Polyether polyamide composition

Patent metadata

Field	Value
Publication number	US-9512314-B2
Application number	US-201314421007-A
Country	US
Kind code	B2
Filing date	Aug 12, 2013
Priority date	Aug 14, 2012
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

Provided is a polyether polyamide composition including 100 parts by mass of a polyether polyamide in which a diamine constituent unit thereof is derived from a specified polyether diamine compound and a xylylenediamine, and a dicarboxylic acid constituent unit thereof is derived from an α,ω-linear aliphatic dicarboxylic acid having from 4 to 20 carbon atoms, having blended therein from 0.01 to 15 parts by mass of at least one molecular chain extender selected from a carbodiimide compound and a compound containing two or more epoxy groups in a molecule thereof.

First claim

The invention claimed is:

1. A polyether polyamide composition comprising 100 parts by mass of a polyether polyamide (A1) in which a diamine constituent unit thereof is derived from a polyether diamine compound (a1-1) represented by the following formula (1) and a xylylenediamine (a-2), and a dicarboxylic acid constituent unit thereof is derived from an α,ω-linear aliphatic dicarboxylic acid having from 4 to 20 carbon atoms, the polyether polyamide (A1) having blended therein from 0.01 to 15 parts by mass of at least one molecular chain extender (B) selected from a carbodiimide compound and a compound containing two or more epoxy groups in a molecule thereof:

wherein (x1+z1) is from 1 to 30; y1 is from 1 to 50; and R 1 represents a propylene group; and
wherein the proportion of the constituent unit derived from the xylylenediamine (a-2) in the diamine constituent unit is from 50 to 99.8% by mole.

2. The polyether polyamide composition according to claim 1 , wherein the xylylenediamine (a-2) is m-xylylenediamine, p-xylylenediamine, or a mixture thereof.

3. The polyether polyamide composition according to claim 1 , wherein the xylylenediamine (a-2) is m-xylylenediamine.

4. The polyether polyamide composition according to claim 1 , wherein the xylylenediamine (a-2) is a mixture of m-xylylenediamine and p-xylylenediamine.

5. The polyether polyamide composition according to claim 4 , wherein the proportion of the p-xylylenediamine relative to a total amount of m-xylylenediamine and p-xylylenediamine is 90% by mole or less.

6. The polyether polyamide composition according to claim 1 , wherein the α, ω-linear aliphatic dicarboxylic acid having from 4 to 20 carbon atoms is at least one member selected from adipic acid and sebacic acid.

7. The polyether polyamide composition according to claim 1 , wherein the molecular chain extender (B) is an aliphatic carbodiimide compound.

8. The polyether polyamide composition according to claim 1 , wherein the molecular chain extender (B) is an epoxy group-containing (meth)acrylic polymer.

9. The polyether polyamide composition according to claim 1 , wherein the relative viscosity of the polyether polyamide composition is from 1.1 to 3.5.

10. The polyether polyamide composition according to claim 1 , wherein the melting point of the polyether polyamide composition is from 170 to 270° C.

11. The polyether polyamide composition according to claim 1 , wherein a rate of tensile elongation at break at a measurement temperature of 23° C. and a humidity of 50% RH is 100% or more.

12. A method for producing the polyether polyamide composition according to claim 1 , which comprises blending 100 parts by mass of the polyether polyamide (A1) with from 0.01 to 15 parts by mass of the molecular chain extender (B) and melt kneading the blend.

13. A molded article comprising the polyether polyamide composition according to claim 1 .

14. The polyether polyamide composition according to claim 1 , wherein the number average molecular weight of the polyether diamine compound (a1-1) is from 500 to 1,800.

15. A polyether polyamide composition comprising 100 parts by mass of a polyether polyamide (A2) in which a diamine constituent unit thereof is derived from a polyether diamine compound (a2-1) represented by the following formula (2) and a xylylenediamine (a-2), and a dicarboxylic acid constituent unit thereof is derived from an α,ω,-linear aliphatic dicarboxylic acid having from 4 to 20 carbon atoms, the polyether polyamide (A2) having blended therein from 0.01 to 15 parts by mass of at least one molecular chain extender (B) selected from a carbodiimide compound and a compound containing two or more epoxy groups in a molecule thereof:

wherein (x2+z2) is from 1 to 60; y2 is from 1 to 50; and R 2 represents a propylene group; and
wherein the proportion of the constituent unit derived from the xylylenediamine (a-2) in the diamine constituent unit is from 50 to 99.8% by mole.

16. The polyether polyamide composition according to claim 15 , wherein the xylylenediamine (a-2) is m-xylylenediamine, p-xylylenediamine, or a mixture thereof.

17. The polyether polyamide composition according to claim 15 , wherein the xylylenediamine (a-2) is m-xylylenediamine.

18. The polyether polyamide composition according to claim 15 , wherein the xylylenediamine (a-2) is a mixture of m-xylylenediamine and p-xylylenediamine.

19. The polyether polyamide composition according to claim 18 , wherein the proportion of the p-xylylenediamine relative to a total amount of m-xylylenediamine and p-xylylenediamine is 90% by mole or less.

20. The polyether polyamide composition according to claim 15 , wherein the α, ω-linear aliphatic dicarboxylic acid having from 4 to 20 carbon atoms is at least one member selected from adipic acid and sebacic acid.

21. The polyether polyamide composition according to claim 15 , wherein the molecular chain extender (B) is an aliphatic carbodiimide compound.

22. The polyether polyamide composition according to claim 15 , wherein the molecular chain extender (B) is an epoxy group-containing (meth)acrylic polymer.

23. The polyether polyamide composition according to claim 15 , wherein the relative viscosity of the polyether polyamide composition is from 1.1 to 3.5.

24. The polyether polyamide composition according to claim 15 , wherein the melting point of the polyether polyamide composition is from 170 to 270° C.

25. The polyether polyamide composition according to claim 15 , wherein a rate of tensile elongation at break at a measurement temperature of 23° C. and a humidity of 50% RH is 100% or more.

26. A method for producing the polyether polyamide composition according to claim 15 , which comprises blending 100 parts by mass of the polyether polyamide (A2) with from 0.01 to 15 parts by mass of the molecular chain extender (B) and melt kneading the blend.

27. A molded article comprising the polyether polyamide composition according to claim 15 .

28. The polyether polyamide composition according to claim 15 , wherein the number average molecular weight of the polyether diamine compound (a2-1) is from 300 to 1,500.

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Satou Kazuya
• Katou Tomonori
• Mitadera Jun
• Takeo Mayumi
• Tsunaka Nobuhide

Classifications

• C08K5/29

  Compounds containing {one or more} carbon-to-nitrogen double bonds · CPC title

• C08L77/06 Primary

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• C08L79/00

  Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00 · CPC title

• B01F2015/062

  Operations & Transport · mapped topic

• C08L63/00

  Compositions of epoxy resins; Compositions of derivatives of epoxy resins · CPC title