Antistatic liquid crystalline polymer composition

Patent metadata

Field	Value
Publication number	US-9512293-B2
Application number	US-201314052790-A
Country	US
Kind code	B2
Filing date	Oct 14, 2013
Priority date	Mar 13, 2013
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

A liquid crystalline polymer composition that contains a conductive filler (e.g., carbon fibers, ionic liquid, etc.) and a plurality of mineral fibers distributed within a liquid crystalline polymer matrix is provided. Through careful selection of the conductive filler and mineral fibers, as well as the manner in which they are dispersed within the polymer matrix, the present inventors have discovered that a composition can be formed that has a reduced tendency to create a static electric charge during a molding operation, but yet also has good surface characteristics and mechanical properties.

First claim

What is claimed is:

1. A polymer composition that comprises an electrically conductive filler and plurality of mineral fibers distributed within a liquid crystalline polymer matrix, wherein the mineral fibers have a median width of from about 1 to about 35 micrometers, and wherein conductive fillers constitute from about 0.1 wt. % to about 25 wt. % of the composition and mineral fibers constitute from about 5 wt. % to about 60 wt. % of the polymer composition, wherein the conductive filler includes metal particles metal fibers, carbon particles, carbon nanotubes, carbon fibers, an ionic liquid, or a combination thereof, wherein the composition has a melt viscosity of from about 0.1 to about 80 Pa-s, as determined in accordance with ISO Test No 11443 at a shear rate of 1000 seconds −1 and temperature that is 15° C. above the melting temperature of the composition.

2. The polymer composition of claim 1 , wherein liquid crystalline polymers constitute from about 25 wt. % to about 95 wt. % of the composition.

3. The polymer composition of claim 1 , wherein the liquid crystalline polymer matrix is formed from a polymer that contains aromatic ester repeating units.

4. The polymer composition of claim 3 , wherein the aromatic ester repeating units are aromatic dicarboxylic acid repeating units, aromatic hydroxycarboxylic acid repeating units, or a combination thereof.

5. The polymer composition of claim 3 , wherein the polymer further contains aromatic diol repeating units.

6. The polymer composition of claim 1 , wherein the liquid crystalline polymer matrix is formed from a polymer that contains repeating units derived from 4-hydroxybenzoic acid, terephthalic acid, hydroquinone, 4,4′-biphenol, acetaminophen, 6-hydroxy-2-naphthoic acid, 2,6-naphthalene dicarboxylic acid, or a combination thereof.

7. The polymer composition of claim 1 , wherein the conductive filler includes carbon particles, carbon fibers, or a combination thereof.

8. The polymer composition of claim 1 , wherein the conductive filler includes an ionic liquid that has a melting temperature of about 400° C. or more and is a salt that contains a cationic species and counterion.

9. The polymer composition of claim 8 , wherein the cationic species is a quaternary onium.

10. The polymer composition of claim 8 , wherein the counterion is a halogen, sulfate, sulfonate, sulfosuccinate, amide, imide, borate, phosphate, phosphinate, antimonate, aluminate, fatty acid carboxylate, cyanate, acetate, or a combination thereof.

11. The polymer composition of claim 1 , wherein at least about 60% by volume of the mineral fibers have a diameter of from about 1 to about 35 micrometers.

12. The polymer composition of claim 1 , wherein the mineral fibers have an aspect ratio of from about 1 to about 50.

13. The polymer composition of claim 1 , wherein the mineral fibers have a median width of from about 3 to about 15 micrometers.

14. The polymer composition of claim 1 , wherein the mineral fibers include fibers derived from a silicate.

15. The polymer composition of claim 14 , wherein the mineral fibers include wollastonite fibers.

16. The polymer composition of claim 1 , further comprising a glass filler, clay mineral, or a combination thereof.

17. The polymer composition of claim 1 , further comprising a functional compound.

18. The polymer composition of claim 17 , wherein the functional compound includes an aromatic compound that is an aromatic dial, aromatic carboxylic acid, or a combination thereof.

19. The polymer composition of claim 17 , wherein the functional compound includes a non-aromatic compound that is a hydrate.

20. A molded part comprising the polymer composition of claim 1 .

21. The molded part of claim 20 , wherein the part exhibits a surface resistivity of about 1×10 15 ohms or less as determined in accordance with IEC 60093.

22. The molded part of claim 20 , wherein the part exhibits a volume resistivity of about 1×10 15 ohm-m or less as determined in accordance with IEC 60093.

23. A compact camera module that comprises a generally planar base on which is mounted a lens barrel, wherein the base, barrel, or both have a thickness of about 500 micrometers or less and are formed from a part that contains the polymer composition of claim 1 .

24. The polymer composition of claim 1 , wherein the liquid crystalline polymer contains a liquid crystalline polymer in which the total amount of repeating units derived from naphthenic hydroxycarboxylic and/or naphthenic dicarboxylic acids is no more than about 15 mol. %.

25. The polymer composition of claim 24 , wherein the liquid crystalline polymer contains repeating units derived from 4-hydroxybenzoic acid in an amount from about 10 mol. % to about 80 mol. %.

26. The polymer composition of claim 25 , wherein the liquid crystalline polymer contains repeating units derived from terephthalic acid and/or isophthalic acid in an amount from about 5 mol. % to about 40 mol. %, as well as repeating units derived from 4,4′-biphenol and/or hydroquinone in an amount from about 1 mol. % to about 30 mol. %.

27. The polymer composition of claim 26 , wherein the liquid crystalline polymer contains repeating units derived from 6-hydroxy-2-naphthoic acid in an amount from about 1 mol. % to about 10 mol. %.

28. The polymer composition of claim 26 , wherein the liquid crystalline polymer contains repeating units derived from acetaminophen.

Assignees

• Ticona Llc

Inventors

• Kim Young Shin

Classifications

• B29C48/40

  using two or more parallel screws {or at least two parallel non-intermeshing screws}, e.g. twin screw extruders · CPC title

• B29C48/919

  using a bath, e.g. extruding into an open bath to coagulate or cool the material · CPC title

• C08K5/092

  Polycarboxylic acids · CPC title

• C09K19/54

  Additives having no specific mesophase {characterised by their chemical composition} · CPC title

• B29C48/767

  through a degassing opening of a barrel · CPC title