Metal organic framework-derived carbon aerogel, preparation method thereof and application in lithium ion batteries
US-12183924-B2 · Dec 31, 2024 · US
US9512005B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9512005-B2 |
| Application number | US-201414478999-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 5, 2014 |
| Priority date | Sep 11, 2008 |
| Publication date | Dec 6, 2016 |
| Grant date | Dec 6, 2016 |
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In a method for producing a carbonaceous film in which a polymer film is wrapped around a core and is subjected to a heat treatment, material film surfaces during the carbonization step are prevented from fusion, whereby a long carbonaceous having a large area film is obtained. Fusion can be prevented by subjecting a polymer film to a heat treatment under a reduced pressure, and under a reduced pressure while allowing an inert gas to flow. The range of the pressure reduction is preferably −0.08 MPa to −0.01 kPa. It is preferred to carry out carbonization with the pressure reduced in the range of from −0.08 MPa to −0.01 kPa while allowing an inert gas to flow. In addition, the polymer film wrapped around the core is placed in an outer casing, and provided that a value derived by dividing (internal diameter of the outer casing−diameter of the core) by 2 is designated as “a” (mm), and a thickness of wrapping of the polymer film is designated as “b” (mm), a value (b/a) derived by dividing the “b” by the “a” is set to fall within the range of from 0.2 to 0.9.
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The invention claimed is: 1. A method for producing a carbonaceous film, the method comprising a carbonization step in which a polymer film is subjected to a heat treatment under the condition that the polymer film is wrapped around a core, wherein a vessel comprises the core and an outer casing and at least a part of the outer casing is provided with one or more holes for ventilation. 2. The method for producing a carbonaceous film according to claim 1 , where…
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