Method for operating a steam reforming plant

Patent metadata

Field	Value
Publication number	US-9512004-B2
Application number	US-201514629978-A
Country	US
Kind code	B2
Filing date	Feb 24, 2015
Priority date	Mar 6, 2014
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

A method for operating a steam reforming plant wherein a hydrocarbon-rich feed is reacted with steam to form synthesis gas. The plant includes a steam reforming reactor and processing units to obtain a hydrogen-rich fraction after separation of carbon dioxide and carbon monoxide. The plant also includes a pressure-swing adsorption plant to separate the hydrogen-rich fraction into product and residual gas. A recycle compressor is included and allows the plant to operate is two different modes. In the first mode, carbon dioxide separated from the synthesis gas is compressed and added to the hydrocarbon-rich feed. In the second mode, the recycle compressor is used to recycle residual gas from the pressure-swing adsorption plant to the hydrogen-rich fraction upstream of the pressure-swing adsorption plant.

First claim

What is claimed is:

1. A method for producing synthesis gas having different hydrogen/carbon monoxide quantitative product ratios in a steam reforming plant, the steam reforming plant comprising:
at least one steam reforming reactor;
at least one processing unit;
at least one pressure-swing adsorption plant; and
at least one recycle compressor;

wherein the method comprises:
reacting a hydrocarbon-rich feed with steam in the at least one steam reforming reactor to form synthesis gas;
separating carbon dioxide and carbon monoxide from the synthesis gas in the at least one processing unit to form a hydrogen-rich fraction;
separating a residual gas from the hydrogen-rich fraction in the at least one pressure-swing adsorption plant;
producing synthesis gas having a hydrogen/carbon monoxide quantitative product ratio of less than 4 by recycling at least a part of the carbon dioxide separated from the synthesis gas to the hydrocarbon-rich feed using the at least one recycle compressor; and
producing synthesis gas having a hydrogen/carbon monoxide quantitative product ratio of 4 or higher by recycling at least a part of the residual gas separated from the hydrogen-rich fraction to the hydrogen-rich fraction upstream of the at least one pressure-swing adsorption plant using the at least one recycle compressor.

2. The method according to claim 1 , wherein the hydrogen-rich fraction has a hydrogen content of at least 85 mol %.

3. The method according to claim 2 , wherein the hydrogen-rich fraction has a hydrogen content of at least 95 mol %.

4. The method according to claim 1 , wherein the residual gas has at least 2 to 50 mol % carbon monoxide, 0 to 5 mol % carbon dioxide, 30 to 90 mol % hydrogen and 0 to 20 mol % light hydrocarbons.

5. The method according to claim 1 , wherein the hydrocarbon-rich feed is natural gas.

Assignees

• Lang Martin
• Hirsch Alexander
• Schwarzhuber Josef
• Linde Ag

Inventors

• Lang Martin
• Hirsch Alexander
• Schwarzhuber Josef

Classifications

• C01B2203/16

  Controlling the process · CPC title

• C01B2203/1258

  Pre-treatment of the feed · CPC title

• C01B3/384

  with external heating of the catalyst · CPC title

• C01B2203/047

  the impurity being carbon monoxide · CPC title

• C01B2203/0811

  by combustion of fuel · CPC title