Dividing wall distillation columns for production of high-purity 2-ethylhexanol and fractionation method using same

Patent metadata

Field	Value
Publication number	US-9511306-B2
Application number	US-201313943536-A
Country	US
Kind code	B2
Filing date	Jul 16, 2013
Priority date	Mar 19, 2009
Publication date	Dec 6, 2016
Grant date	Dec 6, 2016

Abstract

A dividing wall distillation column for producing high-purity 2-ethyl hexanol including a condenser, a reboiler and a main column having a dividing wall. The main column is divided into a column-top zone, an upper feed zone, an upper outflow zone, a lower feed zone, a lower outflow zone and a column-bottom zone. A crude 2-ethyl hexanol raw material (F) flows in a middle inflow plate NR 1 in which the upper feed zone and the lower feed zone come in contact with each other, a low boiling point component (D) flows out from the column-top zone, a high boiling point component (B) flows out from the column-bottom zone, and a middle boiling point component (S) flows out through a middle outflow plate NR 2 in which the upper outflow zone and the lower outflow zone come in contact with each other, where the middle boiling point component is 2-ethyl hexanol.

First claim

What is claimed is:

1. A dividing wall distillation column comprising a condenser, a reboiler and a main column having a dividing wall,
wherein the main column is divided into a column-top zone, an upper feed zone, an upper outflow zone, a lower feed zone, a lower outflow zone and a column-bottom zone,
a crude 2-ethyl hexanol raw material flows in a middle inflow plate in which the upper feed zone and the lower feed zone come in contact with each other, a low boiling point component flows out from the column-top zone, a high boiling point component flows out from the column-bottom zone, and a middle boiling point component flows out through a middle outflow plate in which the upper outflow zone and the lower outflow zone come in contact with each other, and
the middle boiling point component is 2-ethyl hexanol wherein the number of plates provided respectively in the column-top zone, the upper feed zone, the upper outflow zone, the lower feed zone, the lower outflow zone and the column-bottom zone is in a range of 80 to 145% of a theoretical plate number, as calculated from a distillation curve of 2-ethyl hexanol.

2. The dividing wall distillation column according to claim 1 , wherein the raw material has a 2-ethyl hexanol content of 90% by weight or more.

3. The dividing wall distillation column according to claim 1 , wherein a length of the dividing wall is determined according to a total theoretical plate number in the upper feed zone and the lower feed zone, as calculated from the distillation curve.

4. The dividing wall distillation column according to claim 1 , wherein a length of the dividing wall is in a range of 30 to 85% of a total theoretical plate number in the column-top zone, the upper feed zone, the lower outflow zone and the column-bottom zone, as calculated from the distillation curve.

5. The dividing wall distillation column according to claim 1 , wherein a temperature of the column-top zone is in a range of 75 to 85° C. at a pressure of 16.671 kPa.

6. The dividing wall distillation column according to claim 1 , wherein a temperature of the column-bottom zone is in a range of 145 to 160° C. at a pressure of 16.671 kPa.

7. The dividing wall distillation column according to claim 1 , wherein a temperature of the middle outflow plate, which is provided in a position where the upper outflow zone and the lower outflow zone come in contact with each other, and from which the middle boiling point component flows out, is in a range of 130 to 140° C. at a pressure of 16.671 kPa.

8. The dividing wall distillation column according to claim 1 , wherein the temperature of the column-top zone is in a range of a lower temperature limit (T 1α ) to an upper temperature limit (T 2α ), which follows the following Equation 1, when the pressure is out of a pressure of 16.671 kPa:
Lower limit: T 1α =114.5099* P 0.2439
Upper limit: T 2α =123.4949* P 0.2149   Equation 1

(wherein T 1α and T 2α represent temperatures (° C.); P represents a pressure (kgf/cm 2 ), provided that 0.01≦P≦10 and P≠0.17).

9. The dividing wall distillation column according to claim 1 , wherein the temperature of the column-bottom zone is in a range of a lower temperature limit (T 1β ) to an upper temperature limit (T 2β ), which follows the following Equation 2, when the pressure is out of a pressure of 16.671 kPa:
Lower limit: T 1β =192.1386* P 0.1548
Upper limit: T 2β =206.5980* P 0.1405   Equation 2

(wherein T 1β and T 2β represent temperatures (° C.); P represents a pressure (kgf/cm 2 ), provided that 0.01≦P≦10 and P≠0.17).

10. The dividing wall distillation column according to claim 1 , wherein the temperature of the middle outflow plate, which is provided in a position where the upper outflow zone and the lower outflow zone come in contact with each other, and from which the middle boiling point component flows out, is in a range of a lower temperature limit (T 1χ ) to an upper temperature limit (T 2χ ), which follows the following Equation 3, when the pressure is out of a pressure of 16.671 kPa:
Lower limit: T 1χ =157.7845* P 0.1034
Upper limit: T 2χ =167.6350* P 0.096   Equation 3

(wherein T 1χ and T 2χ represent temperatures (° C.); P represents a pressure (kgf/cm 2 ), provided that 0.01≦P≦10 and P≠0.17).

11. A method of fractionally distilling 2-ethyl hexanol comprising:
producing 2-ethyl hexanol using the dividing wall distillation column defined in claim 1 .

Assignees

• Lg Chemical Ltd

Inventors

• Lee Sung Kyu
• Lee Jong Ku
• Shin Joon Ho

Classifications

• C07C31/125

  containing five to twenty-two carbon atoms · CPC title

• B01D3/14

  Fractional distillation {or use of a fractionation or rectification column} · CPC title

• C07C29/80

  by distillation · CPC title

• B01D3/141 Primary

  where at least one distillation column contains at least one dividing wall · CPC title