Potatolike shaped graphite particles with low impurity rate at the surface, process for preparing same

Patent metadata

Field	Value
Publication number	US-9508983-B2
Application number	US-201514933436-A
Country	US
Kind code	B2
Filing date	Nov 5, 2015
Priority date	Oct 25, 2000
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

A method for modifying graphite particles having a prismatic shape or a cylindrical shape characterized by an edge function fe and a basal function fb, said method providing increase of the edge function and lowering of the basal function, wherein the method includes submitting the graphite particles to at least one physical means selected from attrition, jet mill, ball mill, hammer mill, or atomizer mill, in the presence of at least one chemical compound chosen from the group of compounds of the formula MF z , in which M represents an alkaline or alkaline-earth metal and z represents 1 or 2, NaCl and NH 4 F or a mixture thereof, said compound or compounds being added in solid form, at the beginning of the step using the physical means.

First claim

The invention claimed is:

1. A method for modifying graphite particles comprising:
preparing a composition comprising graphite particles to be modified and at least one chemical compound chosen from the group consisting of compounds of the formula MF z , in which M represents an alkaline or alkaline-earth metal and z represents 1 or 2, NaCl and NH 4 F or a mixture thereof, and
subjecting the composition to at least one of grinding by attrition, jet milling, ball milling, hammer milling, or atomizer milling, to form modified graphite particles.

2. The method according to claim 1 , wherein a percentage of impurities by weight present in the modified graphite particles, expressed with respect to total weight of modified graphite particles is between 1 and 10%.

3. The method according to claim 1 , wherein BET varies between 0.5 g/m 2 and 50 g/m 2 .

4. The method according to claim 1 , wherein MF z represents CaF 2 , BaF 2 , or LiF.

5. The method according to claim 1 , wherein the grinding by attrition is carried out with steel balls, ceramic balls or a mixture of steel and ceramic balls.

6. The method according to claim 1 , wherein the modified graphite particles have surface impurities of less than 10% of the total weight of modified graphite particles.

7. The method according to claim 6 , comprising a further step of: reducing the surface impurities, by chemical purification of the modified graphite particles.

8. The method according to claim 1 , wherein the modified graphite particles have from 5 to 20% of at least one of SiO 2 , MgO, ceramic compounds or a mixture thereof, attached to a surface thereof by physical forces.

9. The method according to claim 1 , wherein the grinding by attrition, jet milling, ball milling, hammer milling, or atomizer milling is carried out in a controlled atmosphere or in air, the controlled atmosphere being based on nitrogen, argon, helium or a mixture thereof.

10. The method according to claim 1 , wherein the at least one chemical compound is added in solid form at a beginning of the grinding by attrition, jet milling, ball milling, hammer milling or atomizer milling.

11. The method according to claim 1 , wherein the graphite particles to be modified have an edge function and a basal function, wherein said method increases the edge function and lowers the basal function.

12. The method according to claim 1 , wherein the graphite particles to be modified are subjected to grinding by attrition carried out with an additive being present, selected from SiO 2 , TiO 2 , ZrO 2 , and with steel balls, ceramic balls or with a mixture of steel and ceramic balls.

13. The method according to claim 1 , wherein the modified graphite particles are devoid of surface impurities.

14. Method for modifying prismatic graphite particles, said method comprising coating the prismatic particles with a metallic deposit, a carbon deposit, or a carbon and metal deposit to form graphite-based particles with a coated graphite core.

15. Method according to claim 14 , wherein the graphite-based particles have a size between 1 and 50 μm.

16. Method according to claim 14 , wherein the graphite-based particles have a sphericity of 80% or more.

17. Method according to claim 14 , in which an average thickness of the metallic and/or carbonated coating is between 50 nm and 2 μm.

18. Method according to claim 14 , said core making up at least 90% by weight of total weight of the graphite-based particle, a remainder being the coating made up of at least one metal selected from the group consisting of Ag, Si, Al and Cu and/or of carbon and/or of carbonated polymer, in prismatic or fiber form.

19. A method for modifying natural graphite particles, the natural graphite particles having an edge function fe and a basal function fb, the method comprising:
adding, to the natural graphite particles to be modified, at least one chemical compound chosen from the group consisting of compounds of the formula MF z , in which M represents an alkaline or alkaline-earth metal and z represents 1 or 2, NaCl and NH 4 F or a mixture thereof, said chemical compound or compounds being added in solid form,
subjecting the natural graphite particles to be modified and the at least one chemical compound to at least one of grinding by attrition, jet milling, ball milling, hammer milling, or atomizer milling to form ground natural graphite particles with an increased edge function and a lowered basal function, and
coating the ground natural graphite particles with a metallic deposit, a carbon deposit, or a carbon and metal deposit to form modified graphite-based particles with a coated natural graphite core.

20. The method according to claim 19 , wherein the natural graphite core comprises at least 90% by weight of total mass of the modified graphite-based particles, said modified graphite-based particles having a sphericity of 80% or more and a size between 1 and 50 μm.

21. The method according to claim 20 , wherein the modified graphite-based particles have a size between 2 and 30 μm.

22. The method according to claim 19 , wherein the modified graphite-based particles have a size between 2 and 30 μm.

23. The method according to claim 19 , wherein an average thickness of the metallic, the carbonic or the metallic and carbonic deposit covering the ground natural graphite particles is between 50 nm and 2 μm.

24. The method according to claim 19 , wherein the modified graphite-based particles have a higher percentage of sphericity than the ground natural graphite particles.

25. A method for modifying graphite particles, the method comprising:
preparing a composition consisting essentially of the graphite particles to be modified and at least one chemical compound chosen from the group consisting of compounds of the formula MF z , in which M represents an alkaline or alkaline-earth metal and z represents 1 or 2, NaCl and NH 4 F or a mixture thereof, and
subjecting the composition to at least one of grinding by attrition, jet milling, ball milling, hammer milling, or atomizer milling, to form modified graphite particles.

Assignees

• Hydro Quebec

Inventors

• Guerfi Abdelbast
• Brochu Fernand
• Kinoshita Kimio
• Zaghib Karim

Classifications

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/583

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• Y10T428/2967

  Synthetic resin or polymer · CPC title

• B01J20/3293

  Coatings on a core, the core being particle or fiber shaped, e.g. encapsulated particles, coated fibers · CPC title

• H01M8/0234

  Carbonaceous material · CPC title