Spectrally tunable broadband organic photodetectors

Patent metadata

Field	Value
Publication number	US-9508945-B2
Application number	US-201313929028-A
Country	US
Kind code	B2
Filing date	Jun 27, 2013
Priority date	Jun 27, 2012
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

A photodetector device includes multiple organic photodetector subcells arranged in a stack, each organic photodetector subcell being configured to generate an electrical current in response to absorbing light over a corresponding range of wavelengths, in which each organic photodetector subcell includes at least one electron donor material and at least one electron acceptor material.

First claim

What is claimed is:

1. A photodetector device comprising:
a plurality of organic photodetector subcells arranged in a stack, each organic photodetector subcell being configured to generate an electrical current in response to absorbing light over a corresponding range of wavelengths,
wherein each organic photodetector subcell comprises a photoactive region composed of an intimate mixture of at least one electron donor material and at least one electron acceptor material, and wherein the photoactive region of each organic photodetector subcell in the stack is in direct physical contact with the photoactive region of at least one other organic photodetector subcell in the stack.

2. The photodetector device of claim 1 , wherein an absorption spectrum of a first organic photodetector subcell in the stack overlaps with an absorption spectrum of a second organic photodetector subcell in the stack.

3. The photodetector device of claim 1 , wherein each organic photodetector subcell in the stack has an absorption spectrum that spans a different range of wavelengths.

4. The photodetector device of claim 1 , wherein a concentration of a first electron donor material or a first electron acceptor material in a first organic photodetector subcell is graded from a first end of the first subcell to a second end of the first organic photodetector subcell.

5. The photodetector device of claim 1 , wherein a first organic photodetector subcell in the stack is composed of a first electron donor material and a first electron acceptor material mixed in a first ratio, and a second-organic photodetector subcell in the stack is composed of a second electron donor material and a second electron acceptor material mixed in a second different ratio.

6. The photodetector device of claim 1 , wherein a first organic photodetector subcell is composed of a first electron donor material and a first electron acceptor material, and a ratio of the first electron donor material to the first electron acceptor material in the mixture is 1:1.

7. The photodetector device of claim 1 , further comprising a MoO 3 electron blocking layer.

8. The photodetector device of claim 1 , wherein each organic photodetector subcell is electrically and physically in direct contact with an adjacent organic photodetector subcell in the stack.

9. The photodetector device of claim 1 , wherein each organic photodetector subcell in the stack has a different spectral responsivity, the spectral responsivity of each subcell being a function of the subcell thickness.

10. The photodetector device of claim 1 , wherein each organic photodetector subcell has a different spectral responsivity, the spectral responsivity of each organic photodetector subcell being a function of the subcell donor material concentration.

11. The photodetector device of claim 1 , wherein each organic photodetector subcell has a different spectral responsivity, the spectral responsivity of each organic photodetector subcell being a function of the subcell acceptor material concentration.

12. A photodetector device comprising:
a plurality of organic photodetector subcells arranged in a stack, each organic photodetector subcell being configured to generate an electrical current in response to absorbing light over a corresponding range of wavelengths,
wherein each organic photodetector subcell is composed of an intimate mixture of at least one electron donor material and at least one electron acceptor material, and wherein there is no recombination layer or electrode layer between adjacent organic photodetector subcells in the stack, and
wherein each organic photodetector subcell in the stack is in direct physical contact with at least one other organic photodetector subcell in the stack.

13. A photodetector device comprising:
a plurality of organic photodetector subcells arranged in a stack, each organic photodetector subcell being configured to generate an electrical current in response to absorbing light over a corresponding range of wavelengths,
wherein each organic photodetector subcell is composed of an intimate mixture of at least one electron donor material and at least one electron acceptor material, and wherein each organic photodetector subcell in the stack is in direct physical contact with at least one other organic photodetector subcell in the stack.

Assignees

• Univ Minnesota

Inventors

• Holmes Russell J
• Pandey Richa
• Menke Stephen Matt

Classifications

• H10K30/211

  comprising multiple junctions, e.g. double heterojunctions · CPC title

• H01L2251/308

  Electricity · mapped topic

• H01L51/0046

  Electricity · mapped topic

• Y02E10/549

  Organic PV cells · CPC title

• H01L51/0078

  Electricity · mapped topic