Handheld laser induced breakdown spectroscopy device

Patent metadata

Field	Value
Publication number	US-9506869-B2
Application number	US-201414514294-A
Country	US
Kind code	B2
Filing date	Oct 14, 2014
Priority date	Oct 16, 2013
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

A novel device, method and systems disclosed managing the thermal challenges of LIBS laser components and a spectrometer in a handheld structure as well the use of simplified light signal collection which includes a bare fiber optic to collect the emitted light in close proximity to (or in contact with) the test material. In one example embodiment of the handheld LIBS device, a burst pulse frequency is 4 kHz is used resulting in a time between pulses of about 250 μs which is a factor of 10 above that of other devices in the prior art. In a related embodiment, an active Q-switched laser module is used along with a compact spectrometer module using a transmission grating to improve LIBS measurement while substantially reducing the size of the handheld analyzer.

First claim

What is claimed is:

1. An apparatus for performing laser-induced breakdown spectroscopy, comprising:
a housing configured as a handheld apparatus having an exit for electromagnetic radiation generated from within the housing;
an intracavity, active Q-switched OPO Nd:YAG diode pumped solid state laser module that operates at an eye-safe wavelength of about 1574 nanometers and provides instantaneous laser emissions upon actuation, with a controller system operatively coupled thereto disposed and within the housing, the intracavity laser module including a reflective mirror and an output coupler mirror that form a first resonant cavity and form a second resonant cavity within the first resonant cavity for directing a laser beam through the exit with an energy level per pulse from about 4 millijoules (mJ) to about 10 millijoules (mJ), wherein the laser module operates at a power mode of about 30 watts or less, and wherein the active Q-switched Nd:YAG OPO diode pumped solid state laser module and the laser beam operate with a numerical aperture as low as about 0.0555;
a fiber optic member disposed substantially in the housing for transferring light collected at a distal end of the fiber member without a collection lens or reflective mirror from a plasma induced of a sample material by the laser beam, the fiber optic member distal end being disposed adjacent the exit;
a spectrometer module disposed substantially in the housing for receiving light from a proximal end of the fiber optic member, the spectrometer module producing a spectral distribution corresponding to the sample material from the received light, wherein the controller system provides timing and control between the laser pulse and a spectrometer shutter of the spectrometer module; and
a sampling point interface member with a proximal opening disposed over the housing exit, the laser beam adapted to be projected through the proximal opening and through a distal opening of the interface member, the fiber optic member being disposed adjacent to the interface member distal opening, wherein the sampling point interface is configured in the shape of a cone member, the cone member having an opening opposite an exit opening disposed over the housing exit, wherein an end of the cone member includes a housing-to-sample material interaction section disposed about the housing exit, the interaction section having an area of less than about 2 cm^2.

2. The apparatus according to claim 1 , wherein the spectrometer module includes a first spectrometer configured to operate in an ultraviolet wavelength range and a second spectrometer configured to operate in a visible wavelength range.

3. The apparatus according to claim 2 , wherein the first and second spectrometer include a transmission grating.

4. The apparatus according to claim 1 , further comprising a power source disposed within said housing and configured to deliver electric power to at least said laser module and said spectrometer module.

5. The apparatus according to claim 1 , further comprising a display configured to display information and to receive commands from a user.

6. The apparatus according to claim 1 , further comprising a sighting member configured to assist a user in directing the laser beam, wherein the sighting member is selected from the group consisting of a heat sink member disposed above the laser module and a targeting LED member adapted to project light at a target on the sampled material.

7. The apparatus according to claim 1 , further comprising at least one proximity sensor near the housing exit, the proximity sensor configured to sense location of sampled material.

8. The apparatus according to claim 1 , further comprising a haptic feedback module for providing feedback that a sample analysis is at an acceptable precision level.

9. The apparatus according to claim 1 , wherein the spectrometer module includes a timing aperture or shutter configurable to delay for a predetermined time the collection of light after an initial plasma is formed.

10. The apparatus according to claim 1 , wherein the OPO diode pumped laser module provides about 5 samples per minute, with about 60 pulses to about 100 pulses per sample, and less than about 3 seconds to about 12 seconds between samples.

Assignees

• Tsi Inc

Inventors

• Quant Frederick
• Farmer Kenneth R
• Tan Phillip V
• Stipe Christopher B
• Buckley Steven G
• Stockinger Erik
• Jensen Daniel

Classifications

• G01J3/0221

  the fibers defining an entry slit · CPC title

• G01J3/443

  Emission spectrometry · CPC title

• G01J2003/1861

  Transmission gratings · CPC title

• G01J3/0291

  Housings; Spectrometer accessories; Spatial arrangement of elements, e.g. folded path arrangements · CPC title

• G01N2201/0697

  Pulsed lasers · CPC title