Granules and method for their production, method for producing molten glass, and method for producing glass product
US-9216922-B2 · Dec 22, 2015 · US
US9505931B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9505931-B2 |
| Application number | US-201013517935-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 1, 2010 |
| Priority date | Dec 21, 2009 |
| Publication date | Nov 29, 2016 |
| Grant date | Nov 29, 2016 |
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A process for making a composite pavement structure comprising primed glass aggregate particles and a polymeric binder composition is disclosed. Systems and methods are also disclosed for the priming of glass aggregate particles. In one embodiment, the glass aggregate particles range from about 0.1 to about 0.5 inch in diameter and are exposed to a coupling agent in solution, for example an aqueous aminosilane solution, in an amount of about 1 to about 10 parts by weight of solution based on 100 parts by weight of the glass aggregate particles wherein the aqueous solution contains about 0.01 to about 5.0 parts by weight coupling agent based on 100 parts by weight of solution. After exposure, the primer is allowed to react and bond with the glass aggregate particles for a predetermined time period to provide primed glass particles, for example silylated glass particles, which are then dried. Once the primed glass and polymeric binder composition are mixed, they are allowed react and bond to provide a composite pavement structure.
Opening claim text (preview).
We claim: 1. A process for making a composite pavement structure, the process including the steps of: providing glass aggregate particles ranging from about 1/16 to about ½ inch in diameter; providing a polymeric binder composition; exposing the glass aggregate particles to a coupling agent that increases the bond strength between the glass aggregate particles and the polymeric binder composition; allowing the coupling agent to react and bond with the glass aggregate particles for a predetermined time period to provide primed glass aggregate particles; drying the primed glass aggregate particles; mixing the dried primed glass aggregate particles with the polymeric binder composition to form a mixture; applying the mixture to a compacted surface; allowing the polymeric binder composition to react and bond with the dried primed glass aggregate particles to provide the composite pavement structure; and screeding and/or troweling the composite pavement structure. 2. The process according to claim 1 , wherein: the step of exposing the glass aggregate particles to a coupling agent includes exposing the glass aggregate particles to an aqueous aminosilane solution in an amount of about 1 to about 10 parts by weight of solution based on 100 parts by weight of the glass aggregate particles, the aqueous aminosilane solution containing about 0.01 to about 5.0 parts by weight aminosilane based on 100 parts by weight of solution; and the step of allowing the coupling agent to react and bond with the glass aggregate particles to provide primed glass particles includes allowing the aminosilane to react and bond with the glass aggregate particles to provide silylated glass aggregate particles. 3. The process according to claim 2 , wherein the step of exposing the glass aggregate particles to an aqueous aminosilane solution includes: i) exposing the glass aggregate particles to an aqueous aminosilane solution in an amount of about 5 parts by weight of solution based on 100 parts by weight of the glass aggregate particles; and/or ii) exposing the glass aggregate particles to an aqueous aminosilane solution containing about 0.3 parts by weight aminosilane based on 100 parts by weight of solution. 4. The process according to claim 2 , wherein the step of allowing the aminosilane to react and bond with the glass aggregate particles for a predetermined time period includes allowing the aminosilane to react and bond with the glass aggregate particles for at least about 15 seconds before the step of drying the silylated glass aggregate particles. 5. The process according to claim 1 , wherein the step of providing a polymeric binder composition includes: i) providing the reaction product of a two component polymeric binder composition comprising a first component and a second component reactive with the first component; or ii) providing a first component comprising a polymeric isocyanate and providing a second component comprising an isocyanate-reactive component. 6. The process according to claim 1 , wherein the step of providing glass aggregate particles includes providing recycled glass. 7. The process according to claim 1 , wherein the composite pavement structure has a structural strength of at least 1,300 pounds per square inch. 8. The process according to claim 1 , wherein the composite pavement structure is water permeable. 9. The process according to claim 1 , further comprising providing a transportable mixing system, wherein the mixing occurs in the transportable mixing system operable to be transported to an installation area.
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