Polymer compositions for injection stretch blow molded articles

Patent metadata

Field	Value
Publication number	US-9505920-B2
Application number	US-201113075208-A
Country	US
Kind code	B2
Filing date	Mar 30, 2011
Priority date	Mar 30, 2011
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

A polymer composition of polypropylene copolymer and 1 to 50% by weight of hard resin. The polypropylene copolymer is either an impact copolymer or a random copolymer. The polymer composition can be used to make injection stretch blow molded articles having improved top load strength.

First claim

What is claimed is:

1. An injection stretch blow molded (ISBM) article comprising:
a polymeric composition comprising a polypropylene impact copolymer including a matrix phase and a rubbery phase dispersed within the matrix phase; and, from 1 to 50 weight percent of a hard resin, wherein the hard resin has a softening point, as measured according ASTM E-28, of from 60° C. to 180° C. and a melt flow rate (MFR) of from 1 to 50 g/10 min at 230° C. and a load of 2.16 kg, and wherein the ISBM article exhibits a top load strength of from 103 to 160 N, a normalized top load strength of from 5.0 to 10.0 N/g, a haze of from 60 to 80%, and a gloss at 45° of from 5 to 15 , and wherein the ISBM article is opaque or semi-opaque.

2. The article of claim 1 , wherein the hard resin is present in the polymer composition in an amount ranging from 5 to 50 weight percent.

3. The article of claim 1 , wherein the softening point of the hard resin, as measured according ASTM E-28, is from 80° C. to 150° C.

4. The article of claim 1 , wherein the softening point of the hard resin, as measured according ASTM E-28, is from 100° C. to 140° C.

5. The article of claim 1 , wherein the softening point of the hard resin, as measured according ASTM E-28, is from 120° C. to 140° C.

6. The article of claim 1 , wherein the hard resin has a number average molecular weight (Mn) of between 500 and 2500.

7. The article of claim 1 , wherein the hard resin has a weight average molecular weight (Mw) of between 500 and 3000.

8. The article of claim 1 , wherein the hard resin has a melt flow rate (MFR) of from 10 to 40 g/10 min at 230° C. and a load of 2.16 kg.

9. The article of claim 1 , wherein the hard resin has a melt flow rate (MFR) of from 20 to 30 g/10 min at 230° C. and a load of 2.16 kg.

10. The article of claim 1 , wherein the hard resin comprises a hydrocarbon resin.

11. The article of claim 10 , wherein the hydrocarbon resin is a hydrogenated petroleum resin.

12. The article of claim 1 , wherein the hard resin comprises a ketone resin.

13. The article of claim 1 , wherein the hard resin comprises a polyamide resin.

14. The article of claim 1 , wherein the hard resin comprises colophonium.

15. The article of claim 1 , wherein the hard resin comprises a coumarone resin.

16. The article of claim 1 , wherein the hard resin comprises a terpene resin.

17. The article of claim 1 , wherein the hard resin comprises a chlorinated aliphatic hydrocarbon resin.

18. The article of claim 1 , wherein the hard resin comprises a chlorinated aromatic hydrocarbon rein.

19. The article of claim 1 , wherein polypropylene impact copolymer has a density of from 0.88 to 0.93 g/cm 3 as determined in accordance with ASTM D-1505, a polydispersity of from 4 to 12, a xylene solubles of 25% or less, a melting point of from 155 to 170° C., an melt flow rate of from 0.1 to 500 g/10 min. as determined in accordance with ASTM D-1238 condition L, and a weight average molecular weight (Mw) of form 280,000 to 840,000.

20. The article of claim 1 , wherein the hard resin in present in the polymer composition in an amount ranging from 5 to 50 weight percent, and wherein the hard resin comprises a hydrocarbon resin, a ketone resin, a polyamide resin, colophonium, a coumarone resin, a terpene resin, a chlorinated aliphatic hydrocarbon resin, a chlorinated aromatic hydrocarbon rein, or combinations thereof.

Assignees

• Sun Luyi
• Coffy Tim
• Daniels Leland
• Fina Technology

Inventors

• Sun Luyi
• Coffy Tim
• Daniels Leland

Classifications

• C08L23/10 Primary

  Homopolymers or copolymers of propene · CPC title

• B29C49/0005

  characterised by the material · CPC title

• B29K2023/08

  Copolymers of ethylene (B29K2023/16 takes precedence) · CPC title

• B29C49/06

  Injection blow-moulding · CPC title

• B29L2031/7158

  Bottles · CPC title