Tire inner liner

Patent metadata

Field	Value
Publication number	US-9505917-B2
Application number	US-201314435803-A
Country	US
Kind code	B2
Filing date	Oct 10, 2013
Priority date	Oct 15, 2012
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

A tire, the inner liner of which comprises a rubber composition based on at least predominantly a highly unsaturated diene elastomer, a reinforcing organic filler, graphite, chalk, a plasticizing hydrocarbon resin, the glass transition temperature, Tg, of which is greater than 20° C. and the softening point of which is less than 170° C. The use of such a composition in the inner liner of the tire, including graphite and a non-reinforcing filler of chalk type, makes it possible to notably improve the airtightness properties with respect to a control composition which comprises only graphite and which already performs very well in this aspect, but also with respect to a control composition conventionally used in the inner liners of tires, while maintaining a good level of the stiffness and processability properties as the conventional control compositions.

First claim

The invention claimed is:

1. A tire inner liner having a rubber composition based on at least:
predominantly a highly unsaturated diene elastomer;
a reinforcing organic filler;
graphite;
chalk; and
a plasticizing hydrocarbon resin, the glass transition temperature, Tg, of which is greater than 20° C. and the softening point of which is less than 170° C.

2. The inner liner according to claim 1 , wherein the highly unsaturated diene elastomer is selected from the group consisting of polybutadienes (BRs), synthetic polyisoprenes (IRs), natural rubber (NR), butadiene copolymers, isoprene copolymers, and mixtures of these elastomers.

3. The inner liner according to claim 2 , wherein the diene elastomer is selected from the group consisting of butadiene-styrene (SBR) copolymers, isoprene-butadiene (BIR) copolymers, isoprene-styrene (SIR) copolymers and isoprene-butadiene-styrene (SBIR) copolymers and mixtures of these elastomers.

4. The inner liner according to claim 1 , wherein the content of diene elastomer is between 70 and 100 phr.

5. The inner liner according to claim 1 , wherein the rubber composition additionally comprises, in a minority amount, a halogenated or non-halogenated butyl elastomer.

6. The inner liner according to claim 1 , wherein the diene elastomer is an elastomer having a high glass transition temperature which is greater than −40° C.

7. The inner liner according to claim 1 , wherein the reinforcing organic filler comprises carbon black.

8. The inner liner according to claim 7 , wherein the content of carbon black is greater than 30 phr.

9. The inner liner according to claim 7 , wherein the content of carbon black is between 30 and 120 phr.

10. The inner liner according to claim 1 , wherein the plasticizing hydrocarbon resin has a Tg of greater than +30° C.

11. The inner liner according to claim 10 , wherein the content of plasticizing hydrocarbon resin is between 2 and 35 phr.

12. The inner liner according to claim 11 , wherein the content of plasticizing hydrocarbon resin is between 5 and 25 phr.

13. The inner liner according to claim 10 , wherein the plasticizing hydrocarbon resin is selected from the group consisting of cyclopentadiene or dicyclopentadiene homopolymer or copolymer resins, terpene homopolymer or copolymer resins, C 5 fraction homopolymer or copolymer resins and the mixtures of theses resins.

14. The inner liner according to claim 13 , wherein the copolymer resins are selected from the group consisting of, cyclopentadiene/vinylaromatic copolymer resins, dicyclopentadiene/vinylaromatic copolymer resins, cyclopentadiene/terpene copolymer resins, dicyclopentadiene/terpene copolymer resins, cyclopentadiene/C 5 fraction copolymer resins, dicyclopentadiene/C 5 fraction copolymer resins, terpene/vinylaromatic copolymer resins, C 5 fraction/vinylaromatic copolymer resins and the mixtures of these resins.

15. The inner liner according to claim 13 , in which the plasticizing hydrocarbon resin is selected from the group consisting of cyclopentadiene homopolymer resins, dicyclopentadiene homopolymer resins, cyclopentadiene/styrene copolymer resins, dicyclopentadiene/styrene copolymer resins, polylimonene resins, limonene/styrene copolymer resins, limonene/cyclopentadiene copolymer resins, limonene/dicyclopentadiene copolymer resins, C 5 fraction/styrene copolymer resins, C 5 fraction/C 9 fraction copolymer resins and the mixtures of these resins.

16. The inner liner according to claim 1 , wherein the graphite is in a platy form.

17. The inner liner according to claim 16 , wherein the graphite is a natural graphite.

18. The inner liner according to claim 16 , wherein the graphite is an expanded graphite.

19. The inner liner according to claim 16 , wherein the graphite is a synthetic graphite.

20. The inner liner according to claim 16 , wherein the graphite comprises a blend of natural graphite and/or expanded graphite and/or synthetic graphite.

21. The inner liner according to claim 16 , wherein the graphite content is between 3 and 50 phr.

22. The inner liner according to claim 16 , wherein the composition contains a blend of several graphites.

23. The inner liner according to claim 1 , wherein the composition contains one or more inert fillers.

24. The inner liner according to claim 1 , wherein the composition contains a chalk content of between 3 and 50 phr.

25. A tire comprising an inner liner according to claim 1 .

Assignees

• Michelin & Cie
• Michelin Rech Tech
• Michelin Rech Tech

Inventors

• Riou Isabelle
• Riou Aline
• Cabioch Jean-Luc

Classifications

• C08L9/06 Primary

  Copolymers with styrene · CPC title

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title

• C08L21/00 Primary

  Compositions of unspecified rubbers · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C08K3/04

  Carbon · CPC title