Polypropylene-based resin composition and foam sheet

Patent metadata

Field	Value
Publication number	US-9505894-B2
Application number	US-201314373040-A
Country	US
Kind code	B2
Filing date	Feb 22, 2013
Priority date	Feb 23, 2012
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

Provided is a polypropylene-based resin composition which gives uniform and fine cells and from which a foamed sheet and thermoform excellent in appearance, thermoformability, impact resistance, lightness, stiffness, heat resistance, heat insulating properties, oil resistance and the like can be produced and includes (X) 5 to 99% by weight of a polypropylene resin having a structure with long chain branches, and (Y) 1 to 95% by weight of a propylene-based block copolymer produced by sequential polymerization, which block copolymer comprises (Y-1) a propylene (co)polymer and (Y-2) a propylene-ethylene copolymer.

First claim

The invention claimed is:

1. A polypropylene-based resin foamed sheet obtained by extruding a foam molding resin comprising:
(X) 5 to 99% by weight of a polypropylene resin comprising a structure with long chain branches,
0.05 to 6.0 parts by weight of a blowing agent, based on 100 parts by weight of said foam molding resin; and
(Y) 1 to 95% by weight of a sequentially polymerized propylene-based block copolymer wherein said resin (Y) comprises:
(Y-1) a propylene (co)polymer, and
(Y-2) a propylene-ethylene copolymer, and wherein

said resin (X) has:
(X-i): a melt flow rate (MFR) of 0.1 to 30.0 g/10 minutes,
(X-ii): a molecular weight distribution Mw/Mn of 3.0 to 10.0 measured by GPC and Mz/Mw of 2.5 to 10.0,
(X-iii): a melt tension (MT) (unit: g) where
log(MT)≧−0.9×log(MFR)+0.7, or

MT≧15

(X-iv): a content of p-xylene soluble components (CXS) at 25° C. of less than 5% by weight based on the total amount of said resin (X), and wherein
said block copolymer (Y) has:
(Y-i): a weight ratio of 50 to 99% of (Y-1) and 1 to 50% of (Y-2) where said ratio is calculated based on the total weight of said block copolymer (Y) regarded as 100% by weight, and
(Y-ii): an MFR of said block copolymer (Y) of 0.1 to 200.0 g/10 minutes,
(Y-iii): a melting point of said block copolymer (Y) of more than 155° C.,
(Y-iv): an ethylene content of said (Y-2) of 11.0% or more and less than 60.0% by weight, wherein said ethylene content is calculated based on the total weight of monomers comprising (Y-2) regarded as 100% by weight, and
(Y-v): the intrinsic viscosity [η] of said (Y-2) measured at 135° C. in decalin is
greater than or equal to 5.3 dl/g when said ethylene content of said (Y-2) is 11.0% or more and 38.0% or less by weight, or
greater than or equal to 7.3 dl/g when said ethylene content of said (Y-2) is greater than 38.0% and less than 60.0% by weight.

2. The polypropylene-based resin foamed sheet of claim 1 , wherein said resin (X) has
(X-v): a branching index g′ of 0.30 or more and less than 1.00 at the absolute molecular weight M abs of 1,000,000.

3. The polypropylene-based resin foamed sheet of claim 2 , wherein said resin (X) has
(X-vi): an mm fraction of 95% or more in the propylene unit triads measured by 13 C-NMR.

4. A polypropylene-based resin multi-layer foamed sheet obtained by co-extruding the foamed sheet of claim 1 and a non-foamed layer comprising a thermoplastic resin composition.

5. The multi-layer foamed sheet according to claim 4 , wherein said thermoplastic resin composition comprises:
100 parts by weight of a thermoplastic resin, and
50 parts by weight or less of an inorganic filler.

6. A molded article obtained by thermoforming the foamed sheet of claim 1 .

7. The polypropylene-based resin foamed sheet of claim 1 , further-comprising
(Z) greater than 0 parts by weight and less than or equal to 1000 parts by weight of another resin (Z) based on 100 parts of the foam molding resin, wherein said resin (Z) does not have properties X-i, X-ii, X-iv, Y-i, Y-ii, Y-iv, and Y-v.

8. The propylene-based resin foamed sheet according to claim 7 , wherein said resin (Z) is a polypropylene-based resin.

9. The polypropylene-based resin foamed sheet according to claim 1 , wherein
(X) is present in an amount greater than or equal to 15% and less than or equal to 80% by weight and
(Y) is present in an amount greater than or equal to 20% and less than or equal to 85% by weight.

10. The propylene-based resin foamed sheet according to claim 7 , wherein said resin (Z) is present in an amount greater than 10 parts by mass and less than or equal to 300 parts by mass.

11. The propylene-based resin foamed sheet according to claim 10 , wherein said resin (Z) is a polypropylene-based resin.

12. A molded article obtained by thermoforming the multi-layer foamed sheet of claim 5 .

Assignees

• Japan Polypropylene Corp

Inventors

• Hotta Sachio
• Asuka Kazuo
• Kitade Shinichi
• Takahashi Kuninori
• Kouzai Iku
• Tayano Takao

Classifications

• B29C49/0006

  for heating or cooling · CPC title

• B29C47/065

  Operations & Transport · mapped topic

• B29C51/002

  characterised by the choice of material · CPC title

• C08L23/16

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• B32B5/18 Primary

  characterised by features of a layer {of} foamed material · CPC title