Powdered thermoplastic polyolefin elastomer composition for slush molding

Patent metadata

Field	Value
Publication number	US-9505868-B2
Application number	US-201414767109-A
Country	US
Kind code	B2
Filing date	Feb 3, 2014
Priority date	Feb 28, 2013
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

The present invention relates to a thermoplastic polyolefin elastomer composition in powder form comprising an olefin block copolymer and optionally a high density polyethylene (HDPE), said composition having a Shore A hardness greater than 75, a Tg less than −45° C., a distinct melting peak greater than 95° C., a zero shear viscosity equal to or less than 1,200 Pa-s and a particle size distribution wherein 85 percent of the particles fall between 150 microns to 420 microns and no particles are greater than 500 microns. Said composition demonstrates good pulverizing and flow characteristics at a temperature of 5° C. or less than the distinct melting peak of the olefin block copolymer. In another aspect, this invention relates to a process for preparing said thermoplastic polyolefin elastomer powder and applications for using said powder. In a further aspect, this invention relates to slush molding or rotational molding said thermoplastic polyolefin elastomer composition into skins, for example skins for automotive interior applications, sporting good applications, housing and building applications, packaging materials, covering materials, toys, hollow parts, and the like.

First claim

What is claimed is:

1. A process for the production of a skin comprising the steps of:
(a) pulverizing, grinding, or milling into a powder a thermoplastic polyolefin composition comprising an olefin block copolymer with a melting peak as determined by DSC,
and
(b) slush molding or rotational molding said powder into a skin,

wherein said thermoplastic polyolefin composition has a Shore A hardness greater than 75, a Tg less than −45° C., a melting peak greater than 95° C. as determined by DSC, a zero shear viscosity at 230° C. equal to or less than 1,200 Pa-s, the powder has a particle size distribution wherein 85 weight percent of the particles fall between 150 microns to 420 microns with no particles greater than 500 microns, and the step of pulverizing, grinding, or milling said composition into a powder is performed at a temperature equal to or greater than 90° C. but 5° C. less than the distinct melting peak of the olefin block copolymer.

2. The process of claim 1 wherein the olefin block copolymer, comprising one or more hard segment and one or more soft segment and characterized by one or more of the aspects described as follows:
(a) has a weight average molecular weight/number average molecular weight ratio (Mw/Mn) from 1.7 to 3.5, at least one melting peak (Tm) in degrees Celsius, and a density (d) in grams/cubic centimeter (g/cc), wherein the numerical values of Tm and d correspond to the relationship:
T m >−2002.9+4538.5(d)−2422.2(d) 2 or T m >−6553.3+13735(d)−7051.7(d) 2 ; or
(b) has a Mw/Mn from 1.7 to 3.5, and is characterized by a heat of fusion (ΔH) J/g and a delta quantity, ΔT, in degrees Celsius defined as the temperature difference between the tallest differential scanning calorimetry (DSC) peak and the tallest crystallization analysis fractionation (CRYSTAF) peak, wherein the numerical values of ΔT and ΔH have the following relationships:
ΔT>−0.1299(ΔH)+62.81 for 4H greater than zero and up to 130 J/g,
ΔT≧48° C. for 4H greater than 130 J/g,
wherein the CRYSTAF peak is determined using at least 5 percent of the cumulative polymer, and if less than 5 percent of the polymer has an identifiable CRYSTAF peak, then the CRYSTAF temperature is 30° C.; or
(c) is characterized by an elastic recovery (Re) in percent at 300 percent strain and 1 cycle measured with a compression-molded film of the ethylene/alpha-olefin interpolymer, and has a density (d) in grams/cubic centimeter (g/cc), wherein the numerical values of Re and d satisfy the following relationship: Re>1481-1629(d); or
(d) has a molecular fraction which elutes between 40° C. and 130° C. when fractionated using TREF, characterized in that the fraction has a molar comonomer content greater than, or equal to, the quantity (−0.2013) T+20.07, where T is the numerical value of the peak elution temperature of the TREF fraction, measured in ° C.; or
(e) has a storage modulus at 25° C. (G′(25° C.)) and a storage modulus at 100° C. (G′(100° C.)) wherein the ratio of G′(25° C.) to G′(100° C.) is in the range of 1:1 to 9:1 or
(f) has a molecular fraction which elutes between 40° C. and 130° C. when fractionated using TREF, characterized in that the fraction has a block index of at least 0.5 and up to 1 and a molecular weight distribution, Mw/Mn, greater than 1.3; or
(g) has an average block index greater than zero and up to 1.0 and a molecular weight distribution, Mw/Mn, greater than 1.3.

3. The process of claim 1 wherein the thermoplastic polyolefin composition further comprises a high density polyethylene (HDPE).

4. The process of claim 1 wherein the skin is for an instrument panel, a console box, an arm rest, a head rest, a door trim, a rear panel, a pillar trim, a sunvisor, a trunk room trim, a trunk lid trim, an air bag cover, a seat buckle, a head liner, a gloves box, or a steering wheel cover.

Assignees

• Dow Global Technologies Llc

Inventors

• Doneva Teodora
• Jones Mary Ann

Classifications

• C08L23/06 Primary

  Polyethylene · CPC title

• C08F299/02 Primary

  from unsaturated polycondensates · CPC title

• C08L23/0815

  with aliphatic 1-olefins containing one carbon-to-carbon double bond · CPC title

• C08L23/0807

  with unsaturated hydrocarbons only containing four or more carbon atoms · CPC title

• C08L2666/06

  Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof · CPC title