Method and apparatus for the production of urea from ammonia and carbon dioxide

Patent metadata

Field	Value
Publication number	US-9505712-B2
Application number	US-201314398425-A
Country	US
Kind code	B2
Filing date	May 2, 2013
Priority date	May 3, 2012
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

Method for the production of urea from ammonia and carbon dioxide in a urea plant containing a high-pressure synthesis section with a horizontal pool condenser, wherein the method comprises exchanging heat from a high pressure process medium received in a shell section of the pool condenser to a medium pressure urea containing solution received in a first heat exchanging section provided in the pool condenser to at least decompose ammonium carbamate into NH 3 and CO 2 , wherein the method further comprises exchanging heat from the high pressure process medium to a low pressure steam condensate received in a second heat exchanging section provided in the pool condenser to produce low pressure steam. The invention also relates to an apparatus for the production of urea from ammonia and carbon dioxide.

First claim

The invention claimed is:

1. A method for the production of urea from ammonia and carbon dioxide in a urea plant containing a high-pressure synthesis section with a horizontal pool condenser comprising a shell section and first and second heat exchanging sections, wherein the method comprises
exchanging heat from a high pressure process medium in which carbamate is formed from NH 3 and CO 2 in an exothermic reaction, which high pressure process medium is received in the shell section of the horizontal pool condenser
with a medium pressure urea-containing solution that comprises ammonium carbamate, that is received in said first heat exchanging section to at least decompose in said first heat exchanging section ammonium carbamate into NH 3 and CO 2 , and
exchanging heat from the high pressure process medium contained in said shell section with a low pressure steam condensate received in said second heat exchanging section to produce low pressure steam.

2. The method of claim 1 , wherein the pool condenser is a shell and tube heat exchanger, wherein the first and second heat exchanging sections each comprise a substantially U-shaped tube bundle.

3. The method of claim 1 , wherein the high pressure process medium received in the shell section of the pool condenser is supplied to an after reactor provided downstream of the pool condenser.

4. The method of claim 3 , wherein fresh CO 2 is fed to the after reactor to provide heat for an endothermic urea reaction inside the after reactor.

5. The method of claim 1 , wherein the method further comprises feeding gas that is at least produced in the first heat exchanging section to a medium pressure condenser evaporator in which said gas is at least partially condensed.

6. The method of claim 5 , wherein in the medium pressure condenser evaporator water from a urea-water mixture is evaporated at a tube side of the medium pressure condenser evaporator so as to occur under vacuum conditions.

7. The method of claim 5 , wherein the medium pressure condenser evaporator comprises a falling film evaporator.

Assignees

• Stamicarbon

Inventors

• Van Den Tillaart Johan Albert Arno
• Meessen Jozef Hubert

Classifications

• C07C273/04 Primary

  from carbon dioxide and ammonia · CPC title

• B01J2219/00051

  Controlling the temperature · CPC title

• B01J19/0013

  Controlling the temperature of the process · CPC title

• B01J10/00

  Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor (B01J19/08 takes precedence; separation, e.g. distillation, also combined with chemical reactions B01D, {e.g. B01D3/009}) · CPC title

• Y02P20/142

  Cross-Sectional Technologies · mapped topic