Process for production of acrylic acid or its derivatives
US-9452967-B2 · Sep 27, 2016 · US
US9505697B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9505697-B2 |
| Application number | US-201313839986-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 15, 2013 |
| Priority date | Apr 11, 2012 |
| Publication date | Nov 29, 2016 |
| Grant date | Nov 29, 2016 |
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Methods for catalytically dehydrating hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof to acrylic acid, acrylic acid derivatives, or mixtures thereof with high yield and selectivity and without significant conversion to undesired side products, such as, acetaldehyde, propionic acid, and acetic acid, are provided. The catalysts are mixed monophosphates.
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What is claimed is: 1. A method of making acrylic acid, acrylic acid derivatives, or mixtures thereof comprising contacting a stream comprising hydroxypropionic acid, hydroxypropionic acid derivatives, or mixtures thereof with a catalyst comprising: a. monohydrogen monophosphate anion described by formula (I): [HPO 4 ] 2− (I), b. and dihydrogen monophosphate anions described by formula (II): [H 2 PO 4 ] − (II), and c. at least two different cations, wherein t…
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