Molecular sieve SSZ-101

Patent metadata

Field	Value
Publication number	US-9505626-B2
Application number	US-201414480818-A
Country	US
Kind code	B2
Filing date	Sep 9, 2014
Priority date	Sep 9, 2014
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

A new crystalline molecular sieve designated SSZ-101 is disclosed. SSZ-101 is synthesized using a N-cyclohexylmethyl-N-ethylpiperidinium cation as a structure directing agent.

First claim

The invention claimed is:

1. A molecular sieve having a mole ratio of at least 5 of (1) at least one oxide of at least one tetravalent element to (2) one or more oxides selected from the group consisting of trivalent elements, pentavalent elements, and mixtures thereof, and having, in its as-synthesized form, an X-ray diffraction pattern substantially as shown in the following Table:

d-Spacing,

2-Theta
nm
Relative Intensity
Peak Broadening
P/N

 6.54 ± 0.20
1.350
W
Sh
L

 7.50 ± 0.20
1.177
S
VB
H

 9.77 ± 0.20
0.904
W
Sh
L

11.56 ± 0.20
0.765
W
Sh
L

12.47 ± 0.20
0.709
W
Sh
H

12.95 ± 0.20
0.683
W
Sh
H

15.00 ± 0.20
0.590
W
B
L

15.90 ± 0.20
0.557
W
Sh
L

17.36 ± 0.20
0.510
W
B
L

17.76 ± 0.20
0.499
M
Sh
H

19.89 ± 0.20
0.446
M
B
H

21.68 ± 0.20
0.410
VS
VB
H

22.50 ± 0.20
0.395
W
Sh
L

23.24 ± 0.20
0.382
W
Sh
L

26.06 ± 0.20
0.342
M
Sh
H

28.18 ± 0.20
0.316
VS
VB
H.

2. The molecular sieve of claim 1 , wherein the molecular sieve has a composition, as-synthesized and in the anhydrous state, in terms of mole ratios, as follows:

TO 2 /X 2 O b
 5 to 50

Q/TO 2
0.02 to 0.10

M/TO 2
0.02 to 0.15

wherein:
(1) T is selected from the group consisting of tetravalent elements from Groups 4-14 of the Periodic Table, and mixtures thereof;
(2) X is selected from the group consisting of trivalent and pentavalent elements from Groups 3-13 of the Periodic Table, and mixtures thereof;
(3) b equals the valence state of X;
(4) Q is a N-cyclohexylmethyl-N-ethylpiperidinium cation; and
(5) M is selected from the group consisting of elements from Groups 1 and 2 of the Periodic Table.

3. The molecular sieve of claim 2 , wherein T is selected from the group consisting of Si, Ge, and mixtures thereof.

4. The molecular sieve of claim 3 , wherein T is Si.

5. The molecular sieve of claim 2 , wherein X is selected from the group consisting of B, Al, Ga, In, Fe, and mixtures thereof.

6. The molecular sieve of claim 5 , wherein X is selected from the group consisting of B, Al, Ga, In, and mixtures thereof.

7. The molecular sieve of claim 2 , wherein T is Si and X is Al.

8. A molecular sieve having a mole ratio of at least 5 of (1) at least one oxide of at least one tetravalent element to (2) one or more oxides selected from the group consisting of trivalent elements, pentavalent elements, and mixtures thereof, and having, in its calcined form, an X-ray diffraction pattern substantially as shown following Table:

d-Spacing,

2-Theta
nm
Relative Intensity
Peak Broadening
P/N

 6.21 ± 0.20
1.422
W
Sh
L

 7.50 ± 0.20
1.178
VS
B
H

 9.76 ± 0.20
0.905
W
Sh
L

11.62 ± 0.20
0.761
W
Sh
L

12.47 ± 0.20
0.709
M
Sh
H

12.88 ± 0.20
0.687
S
B
H

14.92 ± 0.20
0.593
W
Sh
L

15.83 ± 0.20
0.559
W
Sh
L

17.44 ± 0.20
0.508
W
B
L

17.70 ± 0.20
0.501
S
B
H

Assignees

• Davis Tracy Margaret
• Schmidt Joel
• Xie Dan
• Chevron Usa Inc

Inventors

• Davis Tracy Margaret
• Schmidt Joel
• Xie Dan

Classifications

• C01B39/46 Primary

  Other types characterised by their X-ray diffraction pattern and their defined composition {(C01B39/023, C01B39/026, C01B39/06 take precedence)} · CPC title

• C01B39/48 Primary

  using at least one organic template directing agent · CPC title

• C01B39/04

  using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound · CPC title

• B01J20/18

  Synthetic zeolitic molecular sieves · CPC title

• B01J29/70

  of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 · CPC title