Carbonaceous feedstocks for forming carbon allotropes

Patent metadata

Field	Value
Publication number	US-9505620-B2
Application number	US-201314395442-A
Country	US
Kind code	B2
Filing date	Apr 10, 2013
Priority date	Apr 17, 2012
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

Methods and systems are provided for forming carbon allotropes. An exemplary method includes treating a carbonaceous compound to form a feedstock that includes at least about 10 mol % oxygen, at least about 10 mol % carbon, and at least about 20 mol % hydrogen. Carbon allotropes are formed from the feedstock in a reactor in a Bosch reaction at a temperature of at least about 500° C. The carbon allotropes are separated from a reactor effluent stream.

First claim

What is claimed is:

1. A method for forming carbon allotropes, comprising:
treating a carbonaceous compound to form a feedstock comprising at least about 10 mol % oxygen, at least about 10 mol % carbon, and at least about 20 mol % hydrogen;
heating, via a heat exchanger, the feedstock with waste heat from a waste gas stream;
forming carbon allotropes from the feedstock in a reactor in a Bosch reaction at a temperature of at least about 500° C.;
separating, via a separator vessel disposed downstream of the reactor, the carbon allotropes from a reactor effluent stream, forming the waste gas stream having waste heat from the reactor;
passing the waste gas stream through the heat exchanger to an ambient-temperature heat exchanger to condense water in the waste gas stream to give a dry waste gas stream; and
passing the dry waste gas stream to a fractionation system comprising a separation column.

2. The method of claim 1 , comprising condensing and removing, via a second ambient-temperature heat exchanger, residual water in the dry waste gas stream before introducing the dry waste gas stream into the fractionation system, wherein treating the carbonaceous compound comprises flashing a liquid into a gas to form the feedstock.

3. The method of claim 1 , wherein treating the carbonaceous compound comprises cracking the carbonaceous compound.

4. The method of claim 1 , wherein treating the carbonaceous compound comprises steam reforming the carbonaceous compound.

5. The method of claim 1 , comprising introducing the feedstock to a bottom portion of the reactor to fluidize a catalyst in the reactor, wherein the reactor comprises a fluidized bed reactor, and wherein treating the carbonaceous compound comprises shredding a material comprising the carbonaceous compound.

6. The method of claim 1 , wherein treating the carbonaceous compound comprises treating the carbonaceous compound in a gassifier, wherein the reactor comprises a fluidized bed reactor, and wherein the heat exchanger comprises a shell-and-tube heat exchanger.

7. The method of claim 1 , wherein treating the carbonaceous compound to form the feedstock comprises removing compounds from the feedstock, the compounds comprising elements other than carbon, hydrogen, and oxygen.

8. A system for the production of carbon allotropes, comprising:
a feed gas heater to receive a feedstock comprising at least about 10 mol % oxygen, at least about 10 mol % carbon, and at least about 20 mol % hydrogen, the feed gas heater comprising a heat exchanger to heat the feedstock with waste heat from a waste gas stream;
a reactor to form carbon allotropes from the feedstock in a Bosch reaction, the reactor comprising an inlet to receive the feedstock and an outlet to discharge a reactor effluent stream;
a separator to separate the carbon allotropes from the reactor effluent stream, forming the waste gas stream, the separator comprising an inlet to receive the reactor effluent stream, a first outlet to discharge the carbon allotropes, and a second outlet to discharge the waste gas stream; and
a water removal system comprising:
an ambient temperature heat exchanger to condense a bulk of water in the waste gas stream; and
a separation vessel to separate the bulk of the water from the waste gas stream to form a dry waste gas stream.

9. The system of claim 8 , wherein the feedstock comprises an organic liquid, and wherein the heat exchanger comprises a ceramic block heat exchanger.

10. The system of claim 8 , wherein the feedstock comprises syngas.

11. The system of claim 8 , comprising:
a gassifier comprising a pyrolysis reactor to treat a carbonaceous compound to form the feedstock;
an amine contactor to remove sulfur compounds comprising hydrogen sulfide from the feedstock discharged from the gassifier and prior to introduction of the feedstock into the reactor; and
a control valve to regulate flow of the feedstock to the reactor.

12. The system of claim 8 , wherein the heat exchanger comprises a shell-and-tube heat exchanger, and wherein the ambient temperature heat exchanger comprises a water chiller or an air cooled heat exchanger.

13. The system of claim 8 , wherein the feedstock comprises at least about 20 mol % oxygen, at least about 20 mol % carbon, and at least about 40 mol % hydrogen, and wherein the separation vessel comprising an inlet to receive the waste gas stream, a first outlet to discharge the bulk of the water from the waste gas stream, and a second outlet to discharge the dry waste gas stream.

14. The system of claim 8 , wherein the feedstock comprises carbon dioxide and methane, wherein the separation vessel comprises a water-settling vessel having a bottom discharge for the bulk of the water separated from the waste gas stream, and further comprising a second ambient-temperature heat exchanger to condense residual water in the dry waste gas stream.

15. The system of claim 8 , wherein the feedstock comprises carbon monoxide and hydrogen, wherein the separator comprises a cyclonic separator, and wherein the heat exchanger comprises:
a first inlet to receive the waste gas stream;
a first outlet to discharge the waste gas stream;
a second inlet to receive the feedstock; and
a second outlet to discharge the feedstock heated by the waste gas stream via the heat exchanger.

16. The system of claim 8 , comprising an amine adsorbent system comprising an amine contactor to remove sulfur compounds comprising hydrogen sulfide from the feedstock.

17. The system of claim 16 , wherein the reactor comprises a reaction vessel comprising the inlet to receive the feedstock and the outlet for the reactor effluent.

18. The system of claim 16 , comprising a treatment system to receive and treat a carbonaceous material to form the feedstock, wherein the treatment system comprises a pyrolysis reactor comprising heaters, wherein the pyrolysis reactor comprises:
a feed inlet to receive the carbonaceous material as feed material; and
a gas inlet to receive an inert gas to sweep the degradation product out of the pyrolysis reactor through an outlet of the pyrolysis reactor, and wherein the carbonaceous compound comprises used tires, recycled plastics, or recycled paper products.

19. The system of claim 8 , comprising a compressor configured to increase the pressure of the dry waste gas stream to facilitate removal of water from the dry waste gas stream.

20. The system of claim 8 , comprising:
a catalyst separator disposed upstream of the separator to separate catalyst from the reactor effluent and return the catalyst to the reactor; and
a fractionation system comprising a separation column to process the waste gas stream.

21. The system of claim 20 , comprising a static mixer to mix a methane rich stream, or a CO 2 rich stream, or both, from the fractionation system with the feedstock.

22. The system of claim 8 , wherein the reactor is a fluidized bed reactor, and wherein the inlet comprises a bottom inlet to receive a bottom fed flow of feedstock to fluidize a catalyst.

23. The system of claim 8 , comprising a gas fractionation system to separate a methane rich stream and a CO 2 rich stream from the waste gas stream, the gas fractionation system comprising a separation column to discharge the methane rich stream as an overhead stream and discharge the CO 2 rich stream as a bottoms stream, wherein the reactor is a fluidized bed reactor.

24. The system of claim 23 , comprising a static mixe

Assignees

• Exxonmobil Upstream Res Co
• Solid Carbon Prod Llc
• Solid Carbon Prod Llc

Inventors

• Denton Robert D
• Noyes Dallas B
• Koveal Jr Russell J
• Ring Terry A

Classifications

• D01F9/127

  by thermal decomposition of hydrocarbon gases or vapours {or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols} · CPC title

• C01B32/16

  Preparation · CPC title

• B01J2208/00876

  outside the bed, e.g. rotary mixer · CPC title

• B01J8/1836

  Heating and cooling the reactor (B01J8/42 takes precedence) · CPC title

• Y02P20/129

  Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines · CPC title