Coated media substrate

Patent metadata

Field	Value
Publication number	US-9505256-B2
Application number	US-201114366197-A
Country	US
Kind code	B2
Filing date	Dec 20, 2011
Priority date	Dec 20, 2011
Publication date	Nov 29, 2016
Grant date	Nov 29, 2016

Abstract

The present disclosure is drawn to coated media substrates, as well as related systems and methods. In one example, a coated media substrate for inkjet ink printing can comprise an ink-receiving layer coated on at least one side of a substrate, and can be formulated for accepting an inkjet ink composition. The ink-receiving layer can comprise an optical brightening agent, an organic acid salt, a binder, a pigment, and a low-molecular weight polymeric carrier having a weighted average molecular weight less than 50,000 Mw.

First claim

What is claimed is:

1. A coated media substrate, comprising an ink-receiving layer coated on at least one side of a substrate and formulated for accepting an inkjet ink composition, the ink-receiving layer comprising:
an optical brightening agent;
a water soluble organic acid salt;
a water-dispersible organic salt;
a binder;
a pigment; and
a low-molecular weight polymeric carrier having a weight average molecular weight less than 50,000 Mw.

2. The coated media substrate of claim 1 , wherein the water-soluble organic acid salt and the water-dispersible organic salt are present at a weight ratio of water-soluble organic salt to water-dispersible organic salt from 9:1 to 1:1.

3. The coated media substrate of claim 1 , wherein the water-soluble organic acid salt is selected from the group of acetates, propionates, formates, oxalates, and mixtures thereof.

4. The coated media substrate of claim 1 , wherein the water-dispersible organic salt is selected from the group of citrates, oleates, oxalates, and mixtures thereof.

5. The coated media substrate of claim 1 , wherein the ink-receiving layer has an optical brightening agent to polymeric carrier weight ratio from 1:1 to 1:3.

6. The coated media substrate of claim 1 , wherein the ink-receiving layer has a pigment to binder weight ratio from 100:1 to 2:1.

7. The coated media substrate of claim 1 , wherein the optical brightening agent is selected from the group of di-, tetra- or hexa-sulfonated triazinestilbenes; coumarins; imidazo lines; diazo les; triazo les; benzoxazo lines;
biphenylstilbenes; derivatives thereof; and mixtures thereof.

8. The coated media substrate of claim 1 , wherein the pigment is selected from the group of titanium oxide pigments, alumina, silica, magnesium oxide, calcined clay, delaminated clay, calcium carbonate, precipitated calcium carbonate, ground calcium carbonate and mixtures thereof.

9. The coated media substrate of claim 1 , wherein the polymeric carrier is poly hydro-carbon compound with polar functional groups.

10. The coated media substrate of claim 1 , wherein the coated media substrate maintains an a* value of more than −5.0 when the optical brightening agent is present over the range of 1 wt % to 10 wt %.

11. The coated media substrate of claim 1 , wherein the coated media substrate maintains a CIE whiteness of at least 80% when the optical brightening agent is present over the range of 1 wt % to 10 wt %.

12. The coated media substrate of claim 1 , wherein the low-molecular weight polymeric carrier is capable of forming a hydrogen bond with water.

13. A method of making a coated media substrate, comprising:
applying a coating composition on at least one side of a substrate at a coating weight from 1 g/m 2 to 30 g/m 2 , the ink-receiving layer comprising an optical brightening agent, a water soluble organic acid salt, a water-dispersible organic salt, a binder, a pigment, and a low-molecular weight polymeric carrier having a weighted average molecular weight less than 50,000 Mw; and
drying the coating composition on the substrate to form an ink-receiving layer on the substrate.

14. A system for inkjet printing, comprising:
an inkjet printer having an inkjet ink loaded therein; and
a coated media substrate comprising an ink-receiving layer applied to at least one side of a substrate formulated for accepting an inkjet ink composition, the ink-receiving layer comprising an optical brightening agent, a water soluble organic acid salt, a water-dispersible organic salt, a binder, a pigment, and a low-molecular weight polymeric carrier having a weighted average molecular weight less than 50,000 Mw,
wherein the low-molecular weight polymeric carrier is capable of forming a hydrogen bond with water.

15. The system of claim 14 , wherein the coated media substrate provides an optical density within 5% of a comparative coated media substrate when printed with the inkjet ink, the comparative coated media substrate prepared identically to the coated media substrate except that the organic acid salt is replaced with calcium chloride, and wherein the coated media substrate has reduced paper greenness and improved CIE whiteness compared to the comparative coated media substrate.

16. The coated media substrate of claim 1 , wherein the coated media substrate maintains an a* value of more than −5.0 when the optical brightening agent is present over the range of 0 wt % to 5 wt % and when the organic acid salt is present over the range of 0 wt % to 15 wt %.

17. The coated media substrate of claim 1 , wherein the pigment comprises calcined clay and delaminated clay.

Assignees

• Pal Lokendra
• Fu Xulong
• Zhou Xiaoqi
• Selensky Ronald J
• Hewlett Packard Development Co Lp

Inventors

• Pal Lokendra
• Fu Xulong
• Zhou Xiaoqi
• Selensky Ronald J

Classifications

• C04B41/009

  characterised by the material treated · CPC title

• B05D3/0263

  with IR heaters · CPC title

• B41M5/5245

  characterised by the use of polymers containing cationic or anionic groups, e.g. mordants · CPC title

• B05D5/04

  to obtain a surface receptive to ink or other liquid (B05D5/02, {B41M5/52} take precedence) · CPC title

• B01J2523/20

  of Group II (IIA or IIB) of the Periodic Table · CPC title