Transition metal/zeolite scr catalysts
US-2016367939-A1 · Dec 22, 2016 · US
US9504958B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9504958-B2 |
| Application number | US-201313959858-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 6, 2013 |
| Priority date | Aug 17, 2012 |
| Publication date | Nov 29, 2016 |
| Grant date | Nov 29, 2016 |
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A catalytic filter module for gaseous fluids is disclosed comprising a block-shaped filter element, a catalytic element and a clean gas collecting and discharge arrangement. The catalytic element is substantially coextensive with the filter element, said filter element has a feed face and on its opposite side a discharge face from which filtrate exits to be received by the upstream face of the catalytic element. The gaseous fluid exits the catalytic element as clean gas at a clean gas face thereof opposite to the upstream face. The clean gas collecting and discharge arrangement comprises one or more channels extending across the whole clean gas face of the catalytic element deflecting and directing the clean gas flow transverse to the vertical of the clean gas face of the catalytic element to a clean gas discharge opening of the filter module at a side face thereof.
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The invention claimed is: 1. A catalytic filter module for gaseous fluids comprising a first set of a block-shaped filter element and a catalytic element having an upstream face and on its opposite side a clean gas face, and a second set of a block-shaped filter element and a catalytic element having an upstream face and on its opposite side a clean gas face, the first and second sets being arranged spaced apart from one another and oriented back-to-back with the clean gas faces of the respective catalytic elements; and a clean gas collecting and discharge arrangement, wherein the first set catalytic element is substantially coextensive with the respective first set filter element, and the second set catalytic element is substantially coextensive with the respective second set filter element; the first set filter element and the second set filter element each having a feed face and on its opposite side a discharge face from which filtrate exits to be received by the upstream face of the respective catalytic element, the gaseous fluid exiting the respective catalytic element as clean gas at the clean gas face thereof opposite to the upstream face, and wherein said clean gas collecting and discharge arrangement comprises a channel extending across all of the clean gas faces of the catalytic elements deflecting and directing clean gas flow transverse to a vertical of the clean gas faces of the catalytic elements to a clean gas discharge opening of the filter module at a side face thereof, said clean gas collecting and discharge arrangement being designed as a common arrangement for the first set and the second set and positioned in between the first and second sets receiving clean gas from the clean gas faces of the catalytic elements of the first and second sets. 2. The catalytic filter module according to claim 1 , wherein said catalytic element is a compartment accommodating a fluidized bed or fixed bed of catalytic particles. 3. The catalytic filter module according to claim 1 , wherein said catalytic element is a porous body of a fibrous and/or foam material comprising a catalyst, the catalyst being optionally applied to the body of the catalytic element by coating or impregnating same. 4. The catalytic filter module according to claim 3 , wherein the catalytic element and the filter element have have a pore size, and the pore size of the catalytic element is larger than the pore size of the filter element. 5. The catalytic filter module according to claim 1 , wherein the catalytic element is a redox catalytic element, a catalytic element for NO reduction and/or a catalytic element for tar removal. 6. The catalytic filter module of claim 1 , wherein the catalytic element comprises on its upstream face a filter layer to provide a safety fuse functionality to the catalytic element. 7. The catalytic filter module of claim 1 , wherein the channel of the clean gas collecting and discharge arrangement has a height, measured as the clearance in the direction of the vertical of the clean gas face of the catalytic element, in the range of from about 0.1 to about 0.7 times a distance of the feed face of the filter element from the clean gas face of the catalytic element. 8. The filter module according to claim 1 , wherein the channel of the clean gas collecting and discharge arrangement is oriented with its longitudinal direction at an angle of about 30° or more to the clean gas face of the catalytic element of the filter module. 9. The catalytic filter module according to claim 1 , wherein said filter element comprises a honey-comb structure, comprising a plurality of raw gas ducts and filtrate ducts, the raw gas ducts being separated from the filtrate ducts by tubular wall parts, the raw gas ducts being open at the feed face of the filter element and closed at the discharge face thereof, said filtrate ducts being closed at the feed face of the filter element and open at the discharge face thereof. 10. The filter module according to claim 9 , wherein the cross section of the tubular wall parts of the filter elements is of a polygonal shape. 11. The filter module according to claim 10 , wherein the tubular wall parts have a cross-sectional area corresponding to the area of a square with an edge length of about 3 to about 20 mm. 12. The filter module according to claim 10 , wherein the length of the tubular wall parts of the filter elements amounts to about 300 mm or less. 13. The catalytic filter module of claim 9 , wherein said raw gas ducts and filtrate ducts are oriented parallel or slanted at an angle of from about 10° to about 60° to the vertical of the feed face of the filter element. 14. The catalytic filter module of claim 1 , wherein the channel of the clean gas collecting and discharge arrangement has a height, measured as the clearance in the direction of the vertical of the clean gas faces of the sets, in the range of from about 0.2 to about 1.4 times the distance of the feed face of the filter element from the clean gas face of the catalytic element of one set. 15. A catalytic filter system comprising a filter housing and two or more catalytic filter modules for gaseous fluids, the two or more filter modules each comprising a first set of a block-shaped filter element and a catalytic element having an upstream face and on its opposite side a clean gas face, and a second set of a block-shaped filter element and a catalytic element having an upstream face and on its opposite side a clean gas face, the first and second sets being arranged spaced apart from one another and oriented back-to-back with the clean gas faces of the respective catalytic elements; and a clean gas collecting and discharge arrangement, wherein the first set catalytic element is substantially coextensive with the respective first set filter element, and the second set catalytic element is substantially coextensive with the respective second set filter filter element; the first set filter element and the second set filter element each having a feed face and on its opposite side a discharge face from which filtrate exits to be received by the upstream face of the respective catalytic element, the gaseous fluid exiting the respective catalytic element as clean gas at the clean gas face thereof opposite to the upstream face, and wherein said clean gas collecting and discharge arrangement comprises a channel extending across all of the clean gas faces of the catalytic elements deflecting and directing clean gas flow transverse to a vertical of the clean gas faces of the catalytic elements to a clean gas discharge opening of the filter module at a side face thereof, said clean gas collecting and discharge arrangement being designed as a common arrangement for the first set and the second set and positioned in between the first and second sets receiving clean gas from the clean gas faces of the catalytic elements of the first and second sets; wherein the two or more filter modules are accommodated in said housing, said housing comprising an interior space separated into a raw gas and a clean gas chamber, said filter module(s) being arranged within said interior space, the feed side(s) of the filter element(s) oriented substantially vertical, said feed side(s) of the filter element(s) being in fluid communication with the raw gas chamber and said clean gas discharge opening(s) of the filter module(s) being in fluid communication with the clean gas chamber of the housing. 16. The catalytic filter system of claim 15 , wherein the housing comprises a tube sheet separating the interior of the housing into the raw gas and clean gas ch
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