Toner

Patent metadata

Field	Value
Publication number	US-9500972-B2
Application number	US-201414554832-A
Country	US
Kind code	B2
Filing date	Nov 26, 2014
Priority date	Nov 29, 2013
Publication date	Nov 22, 2016
Grant date	Nov 22, 2016

Abstract

A toner that comprises a toner particle that contains a binder resin that contains a styrene-acrylic resin and a block polymer, wherein the block polymer has a polyester segment and a vinyl polymer segment; the polyester segment is obtained by condensation polymerization of: a monomer (a) selected from a group consisting of a prescribed monomer group A; and a monomer (b) selected from a group consisting of a prescribed monomer group B, and the content in the polyester segment of the substructure originating with the monomer (b) as calculated from the following formula is from at least 1.0 mol % to not more than 30.0 mol %: {monomer (b) [mol]/(monomer (a) [mol]+monomer (b) [mol])}×100.

First claim

What is claimed is:

1. A toner comprising
a toner particle that contains a binder resin that contains a styrene-acrylic resin and a block polymer,
wherein
the block polymer has a polyester segment and a vinyl polymer segment;
the polyester segment is obtained by condensation polymerization of a monomer (a) and a monomer (b);
the monomer (a) is one or more selected from the group consisting of the monomer group A described below;
the monomer (b) is one or more selected from the group consisting of the monomer group B described below; and
a content, in the polyester segment, of a substructure originating with the monomer (b) as calculated from the following formula is from at least 1.0 mol % to not more than 30.0 mol %:
{monomer ( b ) [mol]/(monomer ( a ) [mol]+monomer ( b ) [mol])}×100

Monomer group A: straight-chain α,ω-aliphatic diols having from at least 2 to not more than 11 carbons, straight-chain α,ω-aliphatic dicarboxylic acids having from at least 2 to not more than 13 carbons, straight-chain α,ω-aliphatic monohydroxymonocarboxylic acids having from at least 2 to not more than 12 carbons, and compounds provided by converting a carboxyl group in these compounds into an acid anhydride, alkyl ester, or lactone;
Monomer group B: straight-chain α,ω-aliphatic dicarboxylic acids having from at least 14 to not more than 24 carbons, straight-chain α,ω-aliphatic diols having from at least 12 to not more than 22 carbons, straight-chain α,ω-aliphatic monohydroxymonocarboxylic acids having from at least 13 to not more than 23 carbons, straight-chain aliphatic primary monocarboxylic acids having from at least 13 to not more than 23 carbons, straight-chain aliphatic primary monoalcohols having from at least 12 to not more than 22 carbons, and compounds provided by converting a carboxyl group in these compounds into an acid anhydride, alkyl ester, or lactone.

2. The toner according to claim 1 , wherein a content of the block polymer in the binder resin is from at least 2.0 mass % to not more than 50.0 mass %.

3. The toner according to claim 2 , wherein the content of the block polymer in the binder resin is from at least 6.0 mass % to not more than 50.0 mass %.

4. The toner according to claim 1 , wherein a mass ratio (the C/A ratio) between the polyester segment and the vinyl polymer segment in the block polymer is from 40:60 to 80:20.

5. The toner according to claim 1 , wherein a weight-average molecular weight (Mw) of the vinyl polymer segment in the block polymer is from at least 3,000 to not more than 14,000.

6. The toner according to claim 1 , wherein a weight-average molecular weight (Mw) of the block polymer is from at least 15,000 to not more than 45,000.

7. The toner according to claim 6 , wherein the weight-average molecular weight (Mw) of the block polymer is from at least 20,000 to not more than 45,000.

8. The toner according to claim 1 , wherein an absolute value (ΔSP value) of a difference between a solubility parameter (SP) value of the styrene-acrylic resin and a solubility parameter (SP) value of the polyester segment in the block polymer is from at least 0.00 to not more than 0.30.

9. The toner according to claim 1 , wherein a melting point of the block polymer is from at least 55° C. to not more than 80° C.

10. The toner according to claim 1 , wherein the toner particle is a toner particle produced by a suspension polymerization method.

Assignees

• Canon Kk

Inventors

• Tanaka Masatake
• Nakagawa Yoshihiro
• Isono Naoya
• Shimano Tsutomu
• NOJI Shintaro
• Yoshida Yu

Classifications

• G03G9/08788

  Block polymers · CPC title

• G03G9/0804

  whereby the components are brought together in a liquid dispersing medium · CPC title

• G03G9/08755

  Polyesters · CPC title

• G03G9/08797

  characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature · CPC title

• G03G9/08795

  characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants · CPC title