Method for producing high-strength hot-dip galvannealed steel sheet

Patent metadata

Field	Value
Publication number	US-9499894-B2
Application number	US-201314140858-A
Country	US
Kind code	B2
Filing date	Dec 26, 2013
Priority date	Apr 20, 2005
Publication date	Nov 22, 2016
Grant date	Nov 22, 2016

Abstract

Exemplary embodiments of the present invention can provide a method for producing hot dip galvannealed steel sheet which exhibits high strength, high ductility, and a significant degree of alloying. Such exemplary method can be applied to, e.g., a pickled hot rolled steel sheet or an annealed and pickled cold rolled steel sheet containing between about 0.02% and about 0.2% C and between about 0.15% and about 2.5% Mn, and may include one or more procedures for rinsing the sheet, preplating the sheet with Ni, rapidly heating the sheet in a nonoxidizing atmosphere to a sheet temperature of about 430° C. to 500° C., then hot dip plating the sheet in a galvanizing bath containing between about 0.05% and about 0.2% Al, and then immediately heating the sheet rapidly for an alloying treatment. Such exemplary method can provide an improved alloying speed, improved plating appearance and better plating adhesion.

First claim

The invention claimed is:

1. A method for producing a high-strength hot-dip galvannealed steel sheet containing C: 0.02-0.2%, Si: 1.3-3.0%, and Mn: 0.15-2.5%, the method comprising sequentially:
pickling a steel sheet comprising at least one of
(i) a pickled hot rolled steel sheet in an aqueous solution of sulfuric acid or hydrochloric acid, or
(ii) an annealed and pickled cold rolled steel sheet in an aqueous solution of sulfuric acid or hydrochloric acid;

preplating the steel sheet in a sulfuric acid bath or chlorination bath with between about 0.2 g/m2 and about 2.0 g/m2 of Ni without rinsing or drying the steel sheet after the pickling;
heating the steel sheet in at least one of a nonoxidizing atmosphere or a reducing atmosphere to a sheet temperature of 430° C. to 500° C. at a rate of at least about 30° C./sec;
hot-dip plating the steel sheet in a galvanizing bath comprising between about 0.05% and about 0.2% of Al;
wiping the steel sheet;
immediately heating the plated steel sheet for alloying to a temperature between about 470° C. and about 550° C. at a rate of at least about 30° C./sec; and
cooling the plated steel sheet to form the high-strength hot-dip galvannealed steel sheet without soaking.

Assignees

• Nippon Steel & Sumitomo Metal Corp

Inventors

• Ishizuka Kiyokazu
• Nishimura Kazumi
• Kikuchi Ikuo
• Kawasaki Kaoru
• Haji Junji

Classifications

• C23C2/06

  Zinc or cadmium or alloys based thereon · CPC title

• C23C2/28 Primary

  Thermal after-treatment, e.g. treatment in oil bath · CPC title

• C23C2/40

  Plates; Strips · CPC title

• C23C2/02 Primary

  Pretreatment of the material to be coated, e.g. for coating on selected surface areas (C23C2/30 takes precedence) · CPC title

• C23C2/29

  Cooling or quenching · CPC title