Additive compositions with a friction modifier and a dispersant

Patent metadata

Field	Value
Publication number	US-9499764-B2
Application number	US-201615009764-A
Country	US
Kind code	B2
Filing date	Jan 28, 2016
Priority date	Dec 21, 2012
Publication date	Nov 22, 2016
Grant date	Nov 22, 2016

Abstract

An engine oil comprising a major amount of a base oil and a minor amount of an additive package, wherein the additive package comprises:
(A) a friction modifier compound of the formula IV:

wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl group having about 8 to about 22 carbon atoms;

and
(B) at least one dispersant.

First claim

What is claimed is:

1. An engine oil comprising a major amount of a base oil selected from a Group II, Group III, Group IV and Group V base oil and mixtures thereof, wherein the Group II and Group III base oils have at least 90% saturates, and a minor amount of an additive package, wherein the additive package comprises:
(A) 0.1-2.0 wt.% of a friction modifier compound of the formula IV:

wherein R is a linear or branched, saturated, unsaturated, or partially saturated hydrocarbyl group having about 8 to about 22 carbon atoms; and
(B) at least one dispersant; and
wherein the composition is adapted for use as a crankcase engine oil lubricant suitable for lubrication of at least pistons, rings, cylinders, bearings and crankshafts of an engine crankcase, and the engine oil composition has a phosphorus content of 50-1000 ppm.

2. The engine oil of claim 1 , wherein R has from about 10 to about 20 carbon atoms.

3. The engine oil of claim 1 , wherein R has from about 12 to about 18 carbon atoms.

4. The engine oil of claim 1 , wherein the additive package further comprises at least one additive selected from the group consisting of antioxidants, antifoam agents, molybdenum-containing compounds, titanium-containing compounds, phosphorus-containing compounds, viscosity index improvers, pour point depressants, and diluent oils.

5. The engine oil of claim 1 , wherein the at least one dispersant comprises a polyalkylene succinimide.

6. The engine oil of claim 1 , wherein the at least one dispersant comprises a polyisobutylene succinimide prepared from a polyisobutylene having a number average molecular weight of greater than 900.

7. The engine oil of claim 1 , wherein the at least one dispersant comprises a polyisobutylene succinimide prepared from a polyisobutylene having a number average molecular weight of from about 1200 to about 5000.

8. The engine oil of claim 5 , wherein the at least one polyalkylene succinimide is post-treated with one or more compounds selected from boron compounds, anhydrides, aldehydes, ketones, phosphorus compounds, epoxides, and carboxylic acids.

9. The engine oil of claim 8 , wherein the at least one polyisobutylene succinimide is post-treated with a boron compound and wherein the boron content of the engine oil is from about 200 to 500 ppm boron.

10. The engine oil of claim 1 , wherein the at least one dispersant comprises a polyisobutylene succinimide prepared from a polyisobutylene having greater than 50% terminal vinylidene.

11. The engine oil of claim 1 , wherein the at least one polyisobutylene succinimide dispersant is derived from an amine selected from trialkyleneaminetetramine and tetralkylene pentamine.

12. The engine oil of claim 1 , wherein a total amount of dispersant is less than about 20 wt. % of a total weight of the engine oil.

13. The engine oil of claim 12 , wherein the total amount of dispersant is in a range of from 0.1 wt. % to 15 wt. % of a total weight of the engine oil.

14. A method for improving thin film and/or boundary layer friction in an engine comprising the step of lubricating the engine with the engine oil as claimed in claim 1 , wherein the improved thin film and boundary layer friction is determined relative to a same composition in the absence of the one or more friction modifier components.

15. The method of claim 14 for improving boundary layer friction in the engine.

16. The method of claim 14 for improving thin film friction in the engine.

17. The method of claim 14 for improving both thin film and boundary layer friction in the engine.

Assignees

• Afton Chemical Corp

Inventors

• Loper John T
• Styer Jeremy P

Classifications

• C10N2030/04

  Detergent property or dispersant property · CPC title

• C10N2030/56

  Boundary lubrication or thin film lubrication · CPC title

• C10N2010/02

  Groups 1 or 11 · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2010/04

  Groups 2 or 12 · CPC title