Process for producing highly polymerized aromatic polycarbonate resin

Patent metadata

Field	Value
Publication number	US-9499661-B2
Application number	US-201314441939-A
Country	US
Kind code	B2
Filing date	Nov 15, 2013
Priority date	Nov 17, 2012
Publication date	Nov 22, 2016
Grant date	Nov 22, 2016

Abstract

The invention provides a process for producing a highly polymerized aromatic polycarbonate resin including a molecular weight-increasing step of reacting an aromatic polycarbonate prepolymer with an aliphatic diol compound represented by Formula (g2) in the presence of a transesterification catalyst to obtain a highly polymerized aromatic polycarbonate resin. In the formula, Ra and Rb each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group, a cycloalkyl group, an aryl group or an alkoxy group, or Ra and Rb may be bonded to each other to form a ring; R 1 to R 4 each independently represent a hydrogen atom, a halogen atom or an alkyl group; and n represents an integer of 0 to 30.

First claim

The invention claimed is:

1. A process for producing a highly polymerized aromatic polycarbonate resin comprising a highly polymerizing step of reacting an aromatic polycarbonate prepolymer with an aliphatic diol compound represented by the following Formula (g2) in the presence of a transesterification catalyst to obtain a highly polymerized aromatic polycarbonate resin:

wherein, in Formula (g2), Ra and Rb each independently represent a halogen atom, a cycloalkyl group with 3 to 30 carbon atoms optionally having an oxygen atom or a halogen atom, or an alkoxy group with 1 to 15 carbon atoms optionally having an oxygen atom or a halogen atom; R 1 to R 4 each independently represent a hydrogen atom, a halogen atom, or a linear or branched alkyl group with 1 to 5 carbon atoms; and n represents an integer of 0 to 30.

2. The process according to claim 1 , wherein n in Formula (g2) is an integer of 1 to 6.

3. The production process according to claim 1 , wherein the aliphatic diol compound represented by Formula (g2) is an aliphatic diol compound represented by the following Formula (g3):

wherein, in Formula (g3), Ra and Rb each independently represent a halogen atom, a cycloalkyl group with 3 to 30 carbon atoms optionally having an oxygen atom or a halogen atom, or an alkoxy group with 1 to 15 carbon atoms optionally having an oxygen atom or a halogen atom.

4. The process according to claim 1 , further comprising a cyclic carbonate removal step of removing at least part of a cyclic carbonate by-produced in the molecular weight-increasing step to the outside of the reaction system, the cyclic carbonate being represented by the following Formula (h2):

wherein, in Formula (h2), Ra and Rb each independently represent a halogen atom, a cycloalkyl group with 3 to 30 carbon atoms optionally having an oxygen atom or a halogen atom, or an alkoxy group with 1 to 15 carbon atoms optionally having an oxygen atom or a halogen atom; R 1 to R 4 each independently represent a hydrogen atom, a halogen atom, or a linear or branched alkyl group with 1 to 5 carbon atoms; and n represents an integer of 0 to 30.

5. The process according to claim 4 , wherein the cyclic carbonate represented by Formula (h2) is a compound represented by the following Formula (h3):

wherein, in Formula (h3), Ra and Rb each independently represent a halogen atom, a cycloalkyl group with 3 to 30 carbon atoms optionally having an oxygen atom or a halogen atom, or an alkoxy group with 1 to 15 carbon atoms optionally having an oxygen atom or a halogen atom.

6. The process according to claim 1 , wherein the aliphatic diol compound is used in an amount of 0.01 to 1.0 mol per 1 mol of total terminal amount of the unreacted aromatic polycarbonate prepolymer in the highly polymerizing step.

7. A polycarbonate resin composition comprising the highly polymerized aromatic polycarbonate resin obtained by the process according to claim 1 and from 0.0005 to not more than 3000 ppm of a cyclic carbonate represented by the following Formula (h2):

wherein, in Formula (h2), Ra and Rb each independently represent a halogen atom, a cycloalkyl group with 3 to 30 carbon atoms optionally having an oxygen atom or a halogen atom, or an alkoxy group with 1 to 15 carbon atoms optionally having an oxygen atom or a halogen atom; R 1 to R 4 each independently represent a hydrogen atom, a halogen atom, or a linear or branched alkyl group with 1 to 5 carbon atoms; and n represents an integer of 0 to 30.

8. A polycarbonate resin composition comprising the highly polymerized aromatic polycarbonate resin obtained by the process according to claim 1 and from 0.0005 to not more than 3000 ppm of a cyclic carbonate represented by the following Formula (h3):

wherein, in Formula (h3), Ra and Rb each independently represent a halogen atom, a cycloalkyl group with 3 to 30 carbon atoms optionally having an oxygen atom or a halogen atom, or an alkoxy group with 1 to 15 carbon atoms optionally having an oxygen atom or a halogen atom.

9. The polycarbonate resin composition according to claim 7 , further comprising not less than 3 ppm of a catalyst deactivator.

10. The polycarbonate resin composition according to claim 9 , wherein the catalyst deactivator is selected from the group consisting of aromatic sulfonic acids, aromatic sulfonate esters, organic halides, alkyl sulfate salts, phosphoric acids and phosphorous acids.

11. The polycarbonate resin composition according to claim 9 , wherein the catalyst deactivator is selected from the group consisting of paratoluenesulfonic acid, butyl paratoluenesulfonate, tetrabutylphosphonium dodecylbenzenesulfonate salt and tetrabutylammonium paratoluenesulfonate salt.

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Isahaya Yoshinori
• Hirashima Atsushi
• Harada Hidefumi
• Ito Maki
• HAYAKAWA Jun-ya
• Isobe Takehiko
• Tokutake Taichi
• Shinkai Yousuke

Classifications

• C08G64/04 Primary

  Aromatic polycarbonates · CPC title

• C08G64/1608

  saturated · CPC title

• C08G64/06 Primary

  not containing aliphatic unsaturation · CPC title

• C08G64/38

  using other monomers · CPC title

• C08G64/307

  and phenols · CPC title