Spherical magnesium halide adduct, a catalyst component and a catalyst for olefin polymerization prepared therefrom

Patent metadata

Field	Value
Publication number	US-9499569-B2
Application number	US-200913384419-A
Country	US
Kind code	B2
Filing date	Jul 15, 2009
Priority date	Jul 15, 2009
Publication date	Nov 22, 2016
Grant date	Nov 22, 2016

Abstract

A magnesium halide adduct represented by the formula (I): MgX 2 .mROH.nE.pH 2 O, in which X is chlorine, bromine, a C 1 -C 12 alkoxy, a C 3 -C 10 cycloalkoxy or a C 6 -C 10 aryloxy, with the proviso that at least one X is chlorine or bromine; R is a C 1 -C 12 alkyl, a C 3 -C 10 cycloalkyl or a C 6 -C 10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II): in which R 1 and R 2 groups are independently a C 1 -C 12 linear or branched alkyl, a C 3 -C 10 cycloalkyl, a C 6 -C 10 aryl, a C 7 -C 10 alkaryl or an C 7 -C 10 aralkyl, the R 1 and R 2 groups are identical to or different from the R group; m is in a range of from 1.0 to 5.0; n is in a range of from 0.001 to 0.5; and p is in a range of from 0 to 0.8, is disclosed. A catalyst component useful in olefin polymerization, which comprises a reaction product of (1) the magnesium halide adduct, (2) a titanium compound, and optionally (3) an electron donor compound, is also disclosed.

First claim

What is claimed is:

1. A spherical magnesium halide adduct represented by the following formula (I):
MgX 2 .m ROH. n E. p H 2 O  (I)

wherein X is chlorine or bromine; R is a C 1 -C 12 alkyl, a C 3 -C 10 cycloalkyl or a C 6 -C 10 aryl; E is an o-alkoxybenzoate compound represented by the formula (II):

wherein R 1 and R 2 groups, which are the same or different, are independently a C 1 -C 12 linear or branched alkyl, a C 3 -C 10 cycloalkyl, or a C 7 -C 10 aralkyl, the R 1 and R 2 groups are identical to or different from the R group;
m is in a range of from 1.0 to 5.0;
n is in a range of from 0.001 to 0.5; and
p is in a range of from 0 to 0.8.

2. The magnesium halide adduct of claim 1 , wherein the R group is a C 1 -C 4 alkyl.

3. The magnesium halide adduct of claim 1 , wherein the R 1 and R 2 groups are independently a C 1 -C 6 linear or branched alkyl.

4. The magnesium halide adduct of claim 3 , wherein the R 1 and R 2 groups are independently methyl, ethyl, n-propyl, isopropyl, n-butyl or iso-butyl.

5. The magnesium halide adduct of claim 1 , wherein m is in a range of from 1.5 to 3.5, and n is in a range of from 0.005 to 0.2.

6. The magnesium halide adduct of claim 1 , wherein X is chlorine.

7. The magnesium halide adduct of claim 1 , wherein R 1 and R 2 are independently a C 1 -C 6 linear or branched alkyl or a C 3 -C 5 cycloalkyl.

8. A process for preparing a spherical magnesium halide adduct, comprising
(i) preparing a melt of a magnesium halide adduct by:
mixing at least one magnesium halide, at least one alcohol, at least one o-alkoxybenzoate and/or its precursor and at least one inert liquid medium in a reactor, and heating the resultant mixture to a temperature of from 100° C. to 140° C. while stirring, to form a melt of a magnesium halide adduct,
wherein the at least one magnesium halide is represented by a formula of MgX 2 , in which X is chlorine or bromine, and the at least one magnesium halide is used in an amount of from 0.1 to 1.0 mol/liter of the inert liquid medium;
wherein the alcohol is represented by a formula of ROH, in which R is a C 1 -C 12 alkyl, a C 3 -C 10 cycloalkyl or a C 6 -C 10 aryl, and the alcohol is used in an amount of from 1 to 5 moles per mole of the magnesium halide;
wherein the o-alkoxybenzoate compound is represented by the formula (II):

wherein the R 1 and R 2 groups, which are the same or different, are independently a C 1 -C 12 linear or branched alkyl, a C 3 -C 10 cycloalkyl, or a C 7 -C 10 aralkyl, and the o-alkoxybenzoate and/or its precursor is used in an amount of from 0.001 to 0.5 moles per mole of the magnesium halide; and
wherein the inert liquid medium is an inert aliphatic hydrocarbon solvent chosen from kerosene, paraffin oil, vaseline oil, white oil, hexane, and heptane, and contains optionally at least one organic silicon compound and/or at least one surfactant; and
(ii) forming particles of the magnesium halide adduct by:
applying shearing action on the melt of the magnesium halide adduct and then discharging it into a cooling medium at a temperature of from −40° C. to 10° C., to form particles of the magnesium halide adduct.

Assignees

• Xia Xianzhi
• Liu Yuexiang
• Zhang Jigui
• Wang Xinsheng
• Gao Ping
• Qiao Suzhen
• Yin Maoping
• Li Weili
• Zhang Tianyi
• Peng Renqi
• Chen Ying
• Zhang Zhihui
• China Petroleum & Chem Corp
• Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp

Inventors

• Xia Xianzhi
• Liu Yuexiang
• Zhang Jigui
• Wang Xinsheng
• Gao Ping
• Qiao Suzhen
• Yin Maoping
• Li Weili
• Zhang Tianyi
• Peng Renqi
• Chen Ying
• Zhang Zhihui

Classifications

• C08F110/06 Primary

  Propene · CPC title

• C08F4/651

  Pretreating with non-metals or metal-free compounds · CPC title

• C08F2500/15

  Isotactic · CPC title

• C07F3/003 Primary

  without C-Metal linkages · CPC title

• C08F2500/12

  Melt flow index or melt flow ratio · CPC title