Hydrocarbon conversion to ethylene

Patent metadata

Field	Value
Publication number	US-9499457-B2
Application number	US-201514942287-A
Country	US
Kind code	B2
Filing date	Nov 16, 2015
Priority date	Dec 17, 2014
Publication date	Nov 22, 2016
Grant date	Nov 22, 2016

Abstract

The invention relates to a hydrocarbon conversion process and a reactor configured to carry out the hydrocarbon conversion process. The hydrocarbon conversion process is directed to increasing the overall equilibrium production of ethylene from typical pyrolysis reactions. The hydrocarbon conversion process can be carried out by exposing a hydrocarbon feed to a peak pyrolysis gas temperature in a reaction zone in the range of from 850° C. to 1200° C.

First claim

The invention claimed is:

1. A hydrocarbon conversion process, the process comprising:
(a) providing a pyrolysis feed comprising hydrocarbon, wherein the hydrocarbon comprises ethane and/or C 3+ hydrocarbon;
(b) providing a reactor including at least one thermal mass, and having a first zone, a second zone, and a reaction zone intermediate to the first and second zones;
(c) passing the pyrolysis feed from the first zone to the second zone of the reactor;
(d) transferring heat in the first zone from the thermal mass to the pyrolysis feed as the pyrolysis feed is passed proximate to the thermal mass;
(e) passing the pyrolysis feed proximate to the thermal mass in the reaction zone to expose the pyrolysis feed to a peak pyrolysis temperature in the range of from 850° C. to 1200° C., at a hydrocarbon partial pressure ≧7 psia, to convert ≧10.0 wt. % of the hydrocarbon in the pyrolysis feed into a pyrolysis product comprising C 2 unsaturates, wherein the C 2 unsaturates have an ethylene:acetylene molar ratio ≧1:1; and
(f) transferring heat in the second zone from pyrolysis product to the thermal mass to cool the pyrolysis product to a temperature below the peak pyrolysis temperature.

2. The process of claim 1 , wherein the pyrolysis feed is passed through the thermal mass at a total gas residence time in the thermal mass of ≦1.0 second.

3. The process of claim 1 , wherein the pyrolysis feed has a total gas residence time above 800° C. in the reaction zone of ≦0.100 second.

4. The process of claim 1 , wherein the hydrocarbon of the pyrolysis feed comprises ≧50 wt % ethane, based on total weight of the hydrocarbon in the pyrolysis feed.

5. The process of claim 1 , wherein the pyrolysis product further comprises unreacted hydrocarbon from the pyrolysis feed.

6. The process of claim 1 , wherein the pyrolysis feed further comprises diluent and the pyrolysis product further comprises unreacted diluent.

7. The process of claim 6 , wherein the hydrocarbon of the pyrolysis feed is comprised of ≧90.0 wt. % ethane, the diluent of the pyrolysis feed is comprised of ≧90.0 wt. % methane, and the reaction zone is at a total pressure ≧120 psig.

8. The process of claim 6 , wherein the hydrocarbon of the pyrolysis feed is comprised of ≧90.0 wt. % ethane, the diluent of the pyrolysis feed is comprised of ≧90.0 wt. % water, and the reaction zone is at a total pressure ≧40 psig.

9. The process of claim 1 , further comprising separating C 2 unsaturates from the pyrolysis product, the separating being carried out (i) without increasing total pressure of the pyrolysis product or (ii) increasing total pressure of the pyrolysis product by a factor of ≦5.0.

10. The process of claim 1 , wherein the peak pyrolysis temperature is in the range of from 900° C. to 1100° C., the hydrocarbon partial pressure is ≧20 psia (1.4 bara), the pyrolysis feed's total gas residence time in the reaction zone is ≦0.75 seconds, and ≧50.0 wt. % of the pyrolysis feed's hydrocarbon are converted in the reaction zone to C 2 unsaturates.

11. A hydrocarbon conversion process, the process comprising:
(a) providing a pyrolysis feed comprising hydrocarbon, wherein the hydrocarbon comprises ethane and/or C 3+ hydrocarbon;
(b) providing combustion feed comprising hydrocarbon fuel and oxidant;
(c) providing a reverse-flow reactor including at least one thermal mass, the reverse-flow reactor having a first zone, a second zone, and a reaction zone intermediate to the first and second zones;
(d) during a first time interval,
i. passing the pyrolysis feed from the first zone to the second zone of the reverse-flow reactor,
ii. transferring heat from the thermal mass to the pyrolysis feed as the pyrolysis feed is passed through the first zone,
iii. exposing the pyrolysis feed to a peak pyrolysis temperature in the reaction zone in the range of from 850° C. to 1200° C., at a hydrocarbon partial pressure ≧7 psia (0.48 bara), to convert ≧10.0 wt. % of the hydrocarbon in the pyrolysis feed into a pyrolysis product comprising C 2 unsaturates, wherein the C 2 unsaturates have an ethylene:acetylene molar ratio ≧1:1,
iv. transferring heat from pyrolysis product to the thermal mass to cool the pyrolysis product to a temperature below the peak pyrolysis temperature, and
v. lessening or discontinuing the passing of the pyrolysis feed to the reverse-flow reactor; and

(e) during a second time interval,
i. passing the combustion feed to the reverse-flow reactor,
ii. transferring heat in the second zone from the thermal mass to the combustion feed,
iii. exothermically reacting the combustion feed to produce combustion products and heat,
iv. transferring the heat in the first zone from the exothermic reaction to the thermal mass to cool the combustion products, and
v. lessening or discontinuing the passing of the combustion feed to the reverse-flow reactor.

12. The process of claim 11 , wherein the pyrolysis feed is passed through the reaction zone at a total gas residence time in the thermal mass of ≦1.0 second.

13. The process of claim 11 , wherein the pyrolysis feed is passed through the reaction zone at a total gas residence time above 800° C.≦0.100 second.

14. The process of claim 11 , wherein the hydrocarbon of the pyrolysis feed comprises ≧50 wt % ethane, based on total weight of the hydrocarbon in the pyrolysis feed.

15. The process of claim 11 , wherein the pyrolysis product further comprises unreacted hydrocarbon from the pyrolysis feed.

16. The process of claim 11 , wherein the pyrolysis feed further comprises diluent and the pyrolysis product further comprises unreacted diluent.

17. The process of claim 16 , wherein the hydrocarbon of the pyrolysis feed comprises ≧90.0 wt. % ethane, the diluent of the pyrolysis feed comprises ≧90.0 wt. % methane, and the reaction zone is at a total pressure ≧120 psig (8.2 barg).

18. The process of claim 16 , wherein the hydrocarbon of the pyrolysis feed comprises ≧90.0 wt. % ethane, the diluent of the pyrolysis feed comprises ≧90.0 wt. % water, and the reaction zone is at a total pressure ≧40 psig (2.7 barg).

19. The process of claim 11 , further comprising separating C 2 unsaturates from the pyrolysis product, the separating being carried out (i) without increasing total pressure of the pyrolysis product or (ii) increasing total pressure of the pyrolysis product by a factor of ≦5.0.

20. The process of claim 13 , wherein the peak pyrolysis temperature in the range of from 900° C. to 1100° C., the hydrocarbon partial pressure ≧20 psia (1.4 bara); and the pyrolysis feed is passed through the reaction zone at a total gas residence time ≦0.75 seconds to convert ≧50.0 wt. % of the pyrolysis feed's hydrocarbon to C 2 unsaturates.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Hershkowitz Frank
• Keusenkothen Paul F
• Laurenzi Ian J

Classifications

• B01J8/0496 Primary

  Heating or cooling the reactor · CPC title

• C07C5/327

  Formation of non-aromatic carbon-to-carbon double bonds only · CPC title

• C07C11/04

  Ethene · CPC title

• B01J2208/00548

  Flow · CPC title

• B01J2219/00087

  with heat exchange elements outside the reactor · CPC title