Coated article with low-E coating having multilayer overcoat and method of making same

Patent metadata

Field	Value
Publication number	US-9499437-B2
Application number	US-201514690557-A
Country	US
Kind code	B2
Filing date	Apr 20, 2015
Priority date	Feb 22, 2012
Publication date	Nov 22, 2016
Grant date	Nov 22, 2016

Abstract

A coated article is provided so as to include a low-E (low emissivity) coating having an infrared (IR) reflecting layer(s) of or including a material such as silver (Ag), which is provided between a pair of contact layers. The low-E coating includes an overcoat having at least one layer of or including zirconium oxide and/or a substantially metallic layer. The overcoat has been found to improve the durability of the coating without significantly sacrificing desired optical characteristics. Such coated articles may be used in the context of windows.

First claim

What is claimed is:

1. A coated article including a layer system supported by a glass substrate, the layer system comprising at least the following layers moving outwardly from the glass substrate:
a first dielectric layer;
an IR reflecting layer comprising silver on the glass substrate over at least the first dielectric layer;
a contact layer on the glass substrate over and directly contacting the infrared (IR) reflecting layer;
a dielectric layer comprising silicon nitride;
a first layer comprising ZrO 2 on the glass substrate over and directly contacting the dielectric layer comprising silicon nitride;
a dielectric layer comprising silicon oxynitride on the substrate, the dielectric layer comprising silicon oxynitride being over and directly contacting the first layer comprising ZrO 2 ;
a second layer comprising zirconium oxide on the glass substrate over and directly contacting the dielectric layer comprising silicon oxynitride; and
wherein the dielectric layer comprising silicon nitride is from 20-40 nm thick, and wherein the dielectric layer comprising silicon oxynitride is from 40-160 nm thick and is at least 70 nm thicker than is the dielectric layer comprising silicon nitride.

2. The coated article of claim 1 , wherein no IR reflecting layer is located over the first layer comprising ZrO 2 and the second layer comprising zirconium oxide.

3. The coated article of claim 1 , wherein the second layer comprising zirconium oxide is the uppermost layer of the coating farthest from the glass substrate.

4. The coated article of claim 1 , further comprising a layer comprising zinc oxide located under and directly contacting the IR reflecting layer comprising silver.

5. The coated article of claim 1 , wherein the first layer comprising ZrO 2 and the second layer comprising zirconium oxide each further comprise aluminum.

6. The coated article of claim 1 , wherein the first layer comprising ZrO 2 is from about 2-12 nm thick.

7. The coated article of claim 1 , wherein the first layer comprising ZrO 2 is from about 3-8 nm thick.

8. The coated article of claim 1 , wherein the second layer comprising zirconium oxide is from about 2-12 nm thick.

9. The coated article of claim 1 , wherein the coated article has a visible transmission of from about 40 to 60%.

10. The coated article of claim 1 , wherein the layer system has a sheet resistance (R s ) of less than about 20 ohms/square.

11. The coated article of claim 1 , wherein the layer system contains only one silver-based IR reflecting layer.

12. The coated article of claim 1 , wherein the contact layer comprises Ni and Cr.

13. The coated article of claim 1 , wherein the contact layer comprises Ni and Mo.

Assignees

• Guardian Industries

Inventors

• Imran Muhammad
• Wuillaume Francis
• Boyce Brent

Classifications

• C03C17/3626

  one layer at least containing a nitride, oxynitride, boronitride or carbonitride · CPC title

• C03C17/36

  at least one coating being a metal · CPC title

• C03C17/3618 Primary

  Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic · CPC title

• Y10T428/31678

  Of metal · CPC title

• Y10T428/265

  1 mil or less · CPC title