Semiconductor device and manufacturing method for the same

Patent metadata

Field	Value
Publication number	US-9496365-B2
Application number	US-201414458611-A
Country	US
Kind code	B2
Filing date	Aug 13, 2014
Priority date	Sep 20, 2013
Publication date	Nov 15, 2016
Grant date	Nov 15, 2016

Abstract

A semiconductor device of an embodiment includes: an SiC layer; a gate insulating film provided on a surface of the SiC layer, the gate insulating film including an oxide film or an oxynitride film in contact with the surface of the SiC layer, the oxide film or the oxynitride film containing at least one element selected from B, Al, Ga (gallium), In, Sc, Y, La, Mg, Ca, Sr, and Ba, a concentration peak of the element in the gate insulating film being on the SiC side of the gate insulating film, the concentration peak of the element being in the oxide film or the oxynitride film, the gate insulating film having a region with a concentration of the element being not higher than 1×10 16 cm −3 on the opposite side to the SiC layer with the concentration peak; and a gate electrode on the gate insulating film.

First claim

What is claimed is:

1. A semiconductor device comprising:
a SiC layer;
a gate insulating film provided on a surface of the SiC layer, the gate insulating film including an oxide film or an oxynitride film in contact with the surface of the SiC layer, the oxide film or the oxynitride film containing at least one element X selected from the group consisting of B (boron), Al (aluminum), Ga (gallium), In (indium), Sc (scandium), Y (yttrium), La (lanthanum), Mg (magnesium), Ca (calcium), Sr (strontium), and Ba (barium), a concentration peak of the element X in the gate insulating film being on the SiC layer side of the gate insulating film, the concentration peak of the element X being in the oxide film or the oxynitride film, the gate insulating film having a region with a concentration of the element X being not higher than 1×10 16 cm −3 on the opposite side to the SiC layer with the concentration peak of the element; and
a gate electrode provided on the gate insulating film,
wherein
a concentration of the element X at a portion of the SiC layer adjacent to the gate insulating film is not higher than 1×10 17 cm −3 ,
a concentration of the element X at the concentration peak of the element is not lower than 5×10 18 cm −3 and not higher than 5×10 20 cm −3,
C (carbon) is contained in the gate insulating film,
a concentration peak of C (carbon) in the gate insulating film is on the SiC side of the gate insulating film and is in the oxide film or the oxynitride film, and
the concentration of the element X at the concentration peak of the element is not less than 80% and not more than 120% of the concentration of the C (carbon) at the concentration peak of the C (carbon).

2. The device according to claim 1 , wherein the concentration peak of the element X is in a range of not more than 5 nm from an interface between the SiC layer and the gate insulating film.

3. The device according to claim 1 , wherein
the oxide film or the oxynitride film comprises a CsOX structure, which consists of C (carbon), the element X, and O(oxygen), and
C (carbon) and the element X are bonded with an intervening O (oxygen) in between in the structure.

4. The device according to claim 1 , wherein the concentration peak of the C (carbon) is in a range of not more than 5 nm from an interface between the SiC layer and the gate insulating film.

5. The device according to claim 1 , wherein the gate insulating film is a stacked film of the oxide film or the oxynitride film and a film with a lower concentration of the element X than in the oxide film or the oxynitride film.

6. The device according to claim 5 , wherein the film with a lower concentration of the element X than in the oxide film or the oxynitride film has a concentration of the element X of not higher than 1×10 16 cm −3 .

7. The device according to claim 1 , wherein a concentration distribution of the element X in a film thickness direction and a concentration distribution of the C (carbon) in the film thickness direction agree with each other in a range of not less than 80% and not more than 120%.

8. The device according to claim 1 , wherein a fixed dipole with a plus on the SiC layer side and a minus on the gate insulating film side exists between the SiC layer and the gate insulating film.

9. The device according to claim 1 , wherein the oxide film or the oxynitride film is a silicon oxide film or a silicon oxynitride film.

10. A semiconductor device comprising:
a SiC substrate having first and second planes;
a first conductive type SiC layer formed on the first plane side of the SiC substrate;
a second conductive type first SiC region provided at a surface of the SiC layer;
a first conductive type second SiC region provided at a surface of the first SiC region;
a gate insulating film provided continuously on the surfaces of the SiC layer and the first SiC region, the gate insulating film including an oxide film or an oxynitride film in contact with the surface of the first SiC region, the oxide film or the oxynitride film containing at least one element X selected from the group consisting of B (boron), Al (aluminum), Ga (gallium), In (indium), Sc (scandium), Y (yttrium), La (lanthanum), Mg (magnesium), Ca (calcium), Sr (strontium), and Ba (barium), a concentration peak of the element X in the gate insulating film being on a side of the first SiC region of the gate insulating film, the concentration peak of the element X being in the oxide film or the oxynitride film, the gate insulating film having a region with a concentration of the element X of not higher than 1×10 16 cm −3 on the opposite side to the SiC layer with the concentration peak of the element;
a gate electrode formed on the gate insulating film;
a first electrode formed on the second SiC region; and
a second electrode formed on the SiC substrate,
wherein
a concentration of the element X in the first SiC region is not higher than 1×10 17 cm −3 ,
a concentration of the element X at the concentration peak of the element is not lower than 5×10 18 cm −3 and not higher than 5×10 20 cm −3 ,
C (carbon) is contained in the gate insulating film,
a concentration peak of C (carbon) in the gate insulating film is on the side of the first SiC region of the gate insulating film and is in the oxide film or the oxynitride film, and
the concentration of the element X at the concentration peak of the element is not less than 80% and not more than 120% of the concentration of the C (carbon) at the concentration peak of the C (carbon).

11. The device according to claim 10 , wherein the concentration peak of the element X is in a range of not more than 5 nm from an interface between the first SiC region and the gate insulating film.

12. The device according to claim 10 , wherein the concentration peak. of the C (carbon) is in a range of not more than 5 nm from an interface between the first SiC region and the gate insulating film.

13. The device according to claim 10 , Wherein the SiC substrate is a first conductive type.

14. The device according to claim 10 , wherein
the oxide film or the oxynitride film comprises a CsOX structure, which consists of C (carbon), the element X, and O (oxygen), and
C (carbon) and the element X are bonded with an intervening O (oxygen) in between in the structure.

Assignees

• Toshiba Kk

Inventors

• Shimizu Tatsuo

Classifications

• H10P14/6308

  of Group IV semiconductors · CPC title

• H10P14/6936

  the material containing two or more metal elements · CPC title

• H10P14/6933

  the material containing at least one rare earth element, e.g. silicate of scandium or silicate of yttrium · CPC title

• H10P14/6929

  the material containing aluminium, e.g. AlSiOx · CPC title

• H10P14/6928

  the material containing silicon and at least one metal element, e.g. metal silicate based insulators or metal silicon oxynitrides · CPC title