Automotive fuel lines including a polyarylene sulfide

Patent metadata

Field	Value
Publication number	US-9494262-B2
Application number	US-201313804573-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Apr 13, 2012
Publication date	Nov 15, 2016
Grant date	Nov 15, 2016

Abstract

A fuel line comprising a thermoplastic composition is described. The thermoplastic compositions exhibit high strength and flexibility and can be used to form one or more layers of single layer or multi-layer fuel lines. Methods for forming the thermoplastic compositions are also described. Formation methods include dynamic vulcanization of a composition that includes an impact modifier dispersed throughout a polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier. The crosslinking agent reacts with the impact modifier to form crosslinks within and among the polymer chains of the impact modifier. The compositions can exhibit excellent physical characteristics at extreme temperatures.

First claim

What is claimed is:

1. A fuel line comprising a thermoplastic composition, the thermoplastic composition being formed by melt processing (i) a linear polyarylene sulfide containing less than about 1 mol. % of cross-linking units based on the total monomer units of the polyarylene sulfide, ii) from 20 wt. % to 35 wt. % of an epoxy-functionalized impact modifier, and (iii) from 1.0 wt % to 1.75 wt. % of a polyfunctional crosslinking agent that includes a dicarboxylic acid, wherein the crosslinking agent is supplied following distribution of the impact modifier with the polyarylene sulfide, and wherein the melt processing forms a crosslinked epoxy-functionalized impact modifier that is a reaction product of epoxy-functionalized monomer units and a polyfunctional crosslinking agent, the fuel line being a tubular member and including a hollow passage therethrough in the axial direction of the tubular member for passage of a fluid, wherein the composition exhibits a tensile elongation at break of about 70% or more as determined in accordance with ISO Test No. 527 at a temperature of 23° C. and at a speed of 50 mm/min.

2. The fuel line of claim 1 , wherein the polyarylene sulfide is polyphenylene sulfide.

3. The fuel line of claim 1 , the thermoplastic composition further comprising one or more additives.

4. The fuel line of claim 1 , wherein a first section of the fuel line comprises the thermoplastic composition, the first section being adjacent to a second section of the fuel line that does not comprise the thermoplastic composition.

5. The fuel line of claim 1 , wherein the thermoplastic composition is free of plasticizers.

6. The fuel line of claim 1 , wherein the thermoplastic composition has an elongation at yield of greater than about 4.5% as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min and/or a tensile modulus of less than about 3000 MPa as determined according to ISO Test No. 527 at a temperature of 23° C. and a speed of 5 mm/min.

7. The fuel line of claim 1 , wherein the thermoplastic composition has a deflection temperature under load of greater than about 80° C. as measured according to ISO Test No. 75-2 at 1.8 MPa.

8. The fuel line of claim 1 , wherein the thermoplastic composition has a notched Charpy impact strength of greater than about 3 kJ/m 2 as measured according to ISO Test No. 179-1 at a temperature of 23° C. and/or a notched Charpy impact strength of greater than about 8 kJ/m 2 at a temperature of −30° C.

9. The fuel line of claim 1 , wherein the thermoplastic composition has a flexural modulus of less than about 2500 MPa as measured according to ISO Test No. 178 at a temperature of 23° C. and a test speed of 2 mm/min.

10. The fuel line of claim 1 , wherein the thermoplastic composition has a halogen content of less than about 1000 ppm.

11. The fuel line of claim 1 , wherein the thermoplastic composition meets the V-0 flammability standard at a thickness of 0.2 millimeters.

12. The fuel line of claim 1 , wherein the thermoplastic composition exhibits a permeation resistance to a fuel or a fuel source of less than about 3 g-mm/m 2 -day as determined according to SAE Testing Method No. J2665.

13. The fuel line of claim 1 , wherein the epoxy-functionalized impact modifier includes methacrylic monomer units.

14. The fuel line of claim 13 , the epoxy-functionalized impact modifier further includes a-olefin monomer units.

15. The fuel line of claim 1 , wherein the dicarboxylic acid includes terephthalic acid.

16. The fuel line of claim 1 , wherein the epoxy-functionalized monomer units include epoxy-functionalized methacrylic monomer units.

17. The fuel line of claim 1 , wherein polyarylene sulfides constitute from about 20% wt. % to about 78.6 wt. % by weight of the composition.

18. The fuel line of claim 1 , wherein the polyarylene sulfide is functionalized.

19. The fuel line of claim 18 , wherein the functionalized polyarylene sulfide is a reaction product of a polyarylene sulfide and a disulfide compound having a reactive functionality.

20. The fuel line of claim 1 , wherein fuel line contains an inner layer, outer layer, and an optional intermediate layer positioned between the inner layer and the outer layer, at least one of the layers containing the thermoplastic composition.

21. The fuel line of claim 20 , wherein the inner layer contains the thermoplastic composition.

22. The fuel line of claim 20 , wherein the outer layer contains the thermoplastic composition.

23. The fuel line of claim 1 , wherein the flowline contains a single layer.

24. The fuel line of claim 23 , wherein the single layer has a wall thickness of from about 0.5 to about 2.5 millimeters.

25. An automotive body that comprises the fuel line of claim 1 , wherein the fuel line is coupled to a fuel tank.

Assignees

• Ticona Llc

Inventors

• Luo Rong
• Zhao Xinyu
• Grenci Joseph

Classifications

• B32B27/286

  comprising polysulphones; polysulfides · CPC title

• B29C48/0017

  combined with blow-moulding or thermoforming · CPC title

• B32B2307/558

  Impact strength, toughness · CPC title

• B29C2948/92876

  Feeding, melting, plasticising or pumping zones, e.g. the melt itself · CPC title

• B29C48/875

  for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones · CPC title