Preparation of industrial asphalt

Patent metadata

Field	Value
Publication number	US-9493654-B2
Application number	US-201414554180-A
Country	US
Kind code	B2
Filing date	Nov 26, 2014
Priority date	May 27, 2011
Publication date	Nov 15, 2016
Grant date	Nov 15, 2016

Abstract

The present invention relates to a method for preparing an industrial asphalt comprising sparging an oxygen containing gas through an asphalt flux in the presence of 0.25 weight percent to about 12 weight percent of a highly saturated rubbery polymer at a temperature within the range of about 400° F. to about 550° F. for a period of time which is sufficient to increase the softening point of the asphalt flux to a value which is within the range of 185° F. to 250° F. and a penetration value of at least 15 dmm to produce the industrial asphalt. The highly saturated rubbery polymer can be a styrene-ethylene/butylene-styrene block copolymer rubber or a highly saturated styrene-ethylene/propylene-styrene block copolymer rubber.

First claim

What is claimed is:

1. A method for preparing an industrial asphalt comprising (1) heating an asphalt flux to a temperature of at least 120° F. to produce a hot asphalt flux, (2) adding from about 0.1 weight percent to about 10 weight percent of a highly saturated rubbery polymer to the hot asphalt flux, wherein the highly saturated rubbery polymer contains repeat units of the formula —(CH 2 —C(CH 3 ) 2 )— or is a styrene-ethylene/propylene-styrene rubber, (3) mixing the highly saturated rubbery polymer throughout the hot asphalt flux to prepare a highly saturated rubbery polymer modified asphalt flux, (4) heating the highly saturated rubbery polymer modified asphalt flux to a temperature which is within the range of about 400° F. to about 550° F. to produce a hot highly saturated rubbery polymer modified asphalt flux, (5) sparging an oxygen containing gas through the hot highly saturated rubbery polymer modified asphalt flux for a period of time which is sufficient to increase the softening point of the highly saturated rubbery polymer modified asphalt flux to a value which is within the range of 185° F. to 250° F. and a penetration value which is within the range of 15 dmm to 25 dmm to produce the industrial asphalt.

2. The method as specified in claim 1 wherein the highly saturated rubbery polymer contains repeat units of the formula:
CH 2 —C(CH 3 2 .

3. The method as specified in claim 1 wherein the highly saturated rubbery polymer is a styrene-ethylene/propylene-styrene rubber.

4. The method as specified in claim 1 wherein the highly saturated rubbery polymer is mixed throughout the hot asphalt flux in step (3) over a period of time which is within the range of about 10 minutes to about 10 hours at a temperature which is within the range of about 200° F. to 400° F.

5. The method as specified in claim 4 wherein the oxygen containing gas is sparged through the hot highly saturated rubbery polymer modified asphalt flux in step (5) for a period of time which is within the range of 2 hours to 8 hours.

6. The method as specified in claim 5 wherein the oxygen containing gas is sparged through the hot highly saturated rubbery polymer modified asphalt flux in step (5) at a temperature which is within the range of about 400° F. to 550° F.

7. The method as specified in claim 1 wherein the industrial asphalt has a softening point which is within the range of 190° F. to 220° F.

8. The method as specified in claim 1 wherein the asphalt flux is a hard asphalt flux.

9. The method as specified in claim 1 wherein the highly saturated rubbery polymer is a styrene-ethylene/butylene-styrene rubber.

10. A method for preparing an industrial asphalt comprising (1) heating an asphalt flux to a temperature of at least 120° F. to produce a hot asphalt flux, (2) adding from about 0.1 weight percent to about 10 weight percent of a highly saturated rubbery polymer to the hot asphalt flux, (3) mixing the highly saturated rubbery polymer throughout the hot asphalt flux to prepare a highly saturated rubbery polymer modified asphalt flux, wherein asphalt flux is further comprised of an air blowing catalyst, (4) heating the highly saturated rubbery polymer modified asphalt flux to a temperature which is within the range of about 400° F. to about 550° F. to produce a hot highly saturated rubbery polymer modified asphalt flux, (5) sparging an oxygen containing gas through the hot highly saturated rubbery polymer modified asphalt flux for a period of time which is sufficient to increase the softening point of the highly saturated rubbery polymer modified asphalt flux to a value which is within the range of 185° F. to 250° F. and a penetration value which is within the range of 15 dmm to 25 dmm to produce the industrial asphalt.

11. The method as specified in claim 10 wherein the oxygen containing gas is sparged through the hot highly saturated rubbery polymer modified asphalt flux in step (5) at a temperature which is within the range of about 400° F. to 550° F.

12. The method as specified in claim 1 wherein the oxygen containing gas is sparged through the hot highly saturated rubbery polymer modified asphalt flux in step (5) for a period of time which is sufficient to attain a penetration value which is within the range of 15 dmm to 20 dmm to produce the industrial asphalt.

13. An industrial asphalt composition which is comprised of (1) asphalt and (2) from about 0.1 weight percent to about 12 weight percent of a A-B-A block copolymer rubber having A blocks which are comprised of repeat units which are derived from at least one vinyl aromatic monomer and a B block which is comprised of isobutylene repeat units, butylene-styrene repeat units, or propylene-styrene repeat units, wherein the industrial asphalt composition has a softening point which is within the range of 185° F. to 250° F. and a penetration value of at least 15 dmm.

14. The industrial asphalt composition as specified in claim 13 wherein the B block is further comprised of repeat units which are derived from an α-olefin monomer.

15. The industrial asphalt composition as specified in claim 13 wherein the A-B-A block copolymer rubber is styrene-ethylene/butylene-styrene rubber.

16. The industrial asphalt composition as specified in claim 13 wherein the highly saturated rubbery polymer is a styrene-ethylene/propylene-styrene rubber.

17. The industrial asphalt composition as specified in claim 13 wherein the vinyl aromatic monomer is styrene.

18. The industrial asphalt composition as specified in claim 13 wherein the vinyl aromatic monomer is α-methyl styrene.

19. The industrial asphalt composition as specified in claim 13 wherein the industrial asphalt composition has a flash point which is higher than 550° C.

Assignees

• Building Materials Invest Corp

Inventors

• Stephens Keith Edward
• Soto Nicholas R
• Tibah Denis Muki

Classifications

• C08J2395/00

  Bituminous materials, e.g. asphalt, tar or pitch · CPC title

• C08J3/18

  Plasticising macromolecular compounds (plasticisers C08K) · CPC title

• E04D1/20

  of plastics; {of asphalt;} of fibrous materials · CPC title

• C08L2555/84

  Polymers comprising styrene, e.g. , polystyrene, styrene-diene copolymers or styrene-butadiene-styrene copolymers · CPC title

• C08L95/00 Primary

  Compositions of bituminous materials, e.g. asphalt, tar, pitch · CPC title