Polymeric film composition for non-enzymatic glucose sensor and non-enzymatic glucose sensor including the same

Patent metadata

Field	Value
Publication number	US-9493652-B2
Application number	US-201414555169-A
Country	US
Kind code	B2
Filing date	Nov 26, 2014
Priority date	Nov 27, 2013
Publication date	Nov 15, 2016
Grant date	Nov 15, 2016

Abstract

A polymeric film composition and a non-enzymatic glucose sensor including the functional polymeric film are provided. The polymeric film composition includes polyurethane and perfluorosulfonic acid polymer.

First claim

What is claimed is:

1. A non-enzymatic glucose sensor comprising:
a reference electrode;
a working electrode electrically connected to the reference electrode; and
a polymeric film provided on a surface of the working electrode,
wherein the polymeric film comprises polyurethane, perfluorosulfonic acid polymer and amino phenyl boronic acid,
wherein an amount of the polyurethane and perfluorosulfonic acid polymer is 3.0 wt % with respect to a total weight of the polymeric film, and
an amount of the amino phenyl boronic acid is 0.05 wt % to 0.3 wt % with respect to a total weight of the polymeric film.

2. The non-enzymatic glucose sensor of claim 1 , wherein the surface of the working electrode comprises a single metal or an alloy of a plurality of metals.

3. The non-enzymatic glucose sensor of claim 2 , wherein the single metal or the alloy of a plurality of metals on the surface of the working electrode comprises any one single metal or an alloy of two or more of the single metals selected from a group consisting of Cu, Au, Zn, Mn, Ni, and Co.

4. The non-enzymatic glucose sensor of claim 3 , wherein the surface of the working electrode comprises a Cu—Co alloy.

5. The non-enzymatic glucose sensor of claim 4 , wherein within the Cu—Co alloy, an atomic percentage of Cu is from 45-65% and an atomic percentage of Co is from 35-55%.

6. The non-enzymatic glucose sensor of claim 1 , wherein the working electrode is a microporous metal electrode.

7. The non-enzymatic glucose sensor of claim 6 , wherein a diameter of micropores in the microporous metal electrode is 100 nm to 5 μm, and a porosity of the microporous metal electrode is 5% to 15%.

8. The non-enzymatic glucose sensor of claim 1 , wherein the working electrode is a dendrite electrode.

9. The non-enzymatic glucose sensor of claim 1 , wherein the working electrode is formed by electrical deposition on a carbon electrode or a copper plate.

10. The non-enzymatic glucose sensor of claim 9 , wherein the working electrode is formed on a glassy carbon electrode or a copper plate by electrical deposition for 75 to 200 seconds with a potential of −0.6 V to −1.2 V.

11. The non-enzymatic glucose sensor of claim 1 , wherein the polymeric film is formed by drying the polymeric film at a temperature of 25° C. to 75° C.

12. The non-enzymatic glucose sensor of claim 5 , wherein the atomic percentages of Cu and Co equal 100 atomic percent of the surface of the working electrode.

Assignees

• Samsung Electronics Co Ltd
• Inst For Res & Ind Coop Pnu

Inventors

• Cho Chulho
• Shim Yoon-Bo
• Kim Jaehong
• Jung Suntae
• Cho Seongje
• Cho Jaegeol

Classifications

• C08L75/04

  Polyurethanes · CPC title

• C08L27/16

  Homopolymers or copolymers or vinylidene fluoride · CPC title

• G01N27/3277

  being a redox reaction, e.g. detection by cyclic voltammetry (voltammetry per se G01N27/42, G01N27/48) · CPC title

• C09D175/04

  Polyurethanes · CPC title

• C08L81/06 Primary

  Polysulfones; Polyethersulfones · CPC title