Blow molded thermoplastic composition

Patent metadata

Field	Value
Publication number	US-9493646-B2
Application number	US-201313804372-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Apr 13, 2012
Publication date	Nov 15, 2016
Grant date	Nov 15, 2016

Abstract

Components formed of blow molded thermoplastic compositions are described. The blow molded thermoplastic compositions exhibit high strength and flexibility. Methods for forming the thermoplastic compositions are also described. Formation methods include dynamic vulcanization of a composition that includes an impact modifier dispersed throughout a polyarylene sulfide. A crosslinking agent is combined with the other components of the composition following dispersal of the impact modifier. The crosslinking agent reacts with the impact modifier to form crosslinks within and among the polymer chains of the impact modifier. The compositions can exhibit excellent physical characteristics at extreme temperatures and can be used to form, e.g., tubular member such as pipes and hoses and fibers.

First claim

What is claimed is:

1. An automotive component comprising a blow molded thermoplastic composition, the thermoplastic composition being formed by melt processing (i) a linear polyarylene sulfide containing less than about 1 mol. % of cross-linking units based on the total monomer units of the polyarylene sulfide, (ii) from 20 wt. % to 35 wt. % of an epoxy-functionalized impact modifier, and (iii) from 1.0 wt. % to 1.75 wt. % of a polyfunctional crosslinking agent that includes a dicarboxylic acid, wherein the crosslinking agent is supplied following distribution of the impact modifier with the polyarylene sulfide, and wherein the melt processing forms a crosslinked epoxy-functionalized impact modifier that is a reaction product of epoxy-functionalized monomer units and a polyfunctional crosslinking agent, wherein the composition exhibits a tensile elongation at break of about 70% or more as determined in accordance with ISO Test No. 527 at a temperature of 23° C. and at a speed of 50 mm/min.

2. The automotive component of claim 1 , wherein the blow molded thermoplastic composition has a notched Charpy impact strength of greater than about 3 kJ/m 2 as determined according to ISO Test No. 197-1 at 23° C. and a tensile modulus of less than about 3000 MPa as determined according to ISO Test No. 527 at a temperature of 23° C. and a test speed of 5 mm/min.

3. The automotive component of claim 1 , wherein the polyarylene sulfide is polyphenylene sulfide.

4. The automotive component of claim 1 , wherein the thermoplastic composition further comprises a filler, UV stabilizer, heat stabilizer, lubricant, colorant, or a combination thereof.

5. The automotive component of claim 1 , wherein the thermoplastic composition has a halogen content of less than about 1000 ppm.

6. The automotive component of claim 1 , wherein a first section of the component comprises the thermoplastic composition, the first section being adjacent to a second section of the component that does not comprise the thermoplastic composition.

7. The automotive component of claim 1 , wherein the thermoplastic composition is free of plasticizers.

8. The automotive component of claim 1 , wherein the component exhibits a permeation resistance to a fuel or a fuel source of less than about 10 g-mm/m 2 -day as determined according to SAE Testing Method No. J2665.

9. The automotive component of claim 1 , wherein the thermoplastic composition has an elongation at yield of greater than about 4.5% as determined according to ISO Test No. 527 at a temperature of 23° C.

10. The automotive component of claim 1 , wherein the thermoplastic composition has a deflection temperature under load of greater than about 80° C. as measured according to ISO Test No. 75-2 at 1.8 MPa.

11. The automotive component of claim 1 , wherein the thermoplastic composition has a notched Charpy impact strength of greater than about 8 kJ/m 2 at a temperature of −30° C.

12. The automotive component of claim 1 , wherein the thermoplastic composition has a flexural modulus of less than about 2500 MPa as measured according to ISO Test No, 178 at a temperature of 23° C. and a test speed of 2 mm/min.

13. The automotive component of claim 1 , wherein the thermoplastic composition meets the V-0 flammability standard at a thickness of 0.2 millimeters.

14. The automotive component of claim 1 , wherein the thermoplastic composition has a tensile break stress of greater than about 30 MPa and/or a strain at break greater than about 5% , as determined according to ISO Test No. 527 at a temperature of 23° C. and a test speed of 5 mm/min.

15. The automotive component of claim 1 , wherein the epoxy-functionalized impact modifier includes methacrylic monomer units.

16. The automotive component of claim 15 , the epoxy-functionalized impact modifier further includes α-olefin monomer units.

17. The automotive component of claim 1 , wherein the dicarboxylic acid includes terephthalic acid.

18. The automotive component of claim 17 , wherein the epoxy-functionalized monomer units include epoxy-functionalized methacrylic monomer units.

19. The automotive component of claim 1 , wherein polyarylene sulfides constitute from about 20% wt. % to about 78.6 wt. % by weight of the composition.

20. The automotive component of claim 1 , wherein the polyarylene sulfide is functionalized.

21. The automotive component of claim 20 , wherein the functionalized polyarylene sulfide is a reaction product of a polyarylene sulfide and a disulfide compound having a reactive functionality.

Assignees

• Ticona Llc

Inventors

• Luo Rong
• Zhao Xinyu
• Grenci Joseph

Classifications

• Y10T428/1393

  Multilayer [continuous layer] · CPC title

• Y10T428/1352

  Polymer or resin containing [i.e., natural or synthetic] · CPC title

• B60K15/03177

  made of non-metallic material, e.g. plastics, or of a combination of non-metallic and metallic material (B60K15/03006 takes precedence) · CPC title

• Y10T428/139

  Open-ended, self-supporting conduit, cylinder, or tube-type article · CPC title

• B32B1/08

  Tubular products · CPC title