Solvent-based methods for production of graphene nanoribbons

Patent metadata

Field	Value
Publication number	US-9493355-B2
Application number	US-201214345016-A
Country	US
Kind code	B2
Filing date	Sep 14, 2012
Priority date	Sep 14, 2011
Publication date	Nov 15, 2016
Grant date	Nov 15, 2016

Abstract

The present invention provides methods of preparing functionalized graphene nanoribbons. Such methods include: (1) exposing a plurality of carbon nanotubes (CNTs) to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to an electrophile to form functionalized graphene nanoribbons (GNRs). The methods may also include a step of exposing the opened CNTs to a protic solvent to quench any reactive species on them. Additional methods include preparing unfunctionalized GNRs by: (1) exposing a plurality of CNTs to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to a protic solvent to form unfunctionalized GNRs.

First claim

What is claimed is:

1. A method of preparing graphene nanoribbons, wherein the method comprises:
exposing a plurality of carbon nanotubes to an alkali metal source in the presence of an aprotic solvent, wherein the exposing opens the carbon nanotubes parallel to their longitudinal axis; and
exposing the opened carbon nanotubes to a protic solvent to form unfunctionalized graphene nanoribbons.

2. The method of claim 1 , wherein the method takes place at room temperature.

3. The method of claim 1 , wherein the carbon nanotubes are selected from the group consisting of single-walled carbon nanotubes, double-walled carbon nanotubes, triple-walled carbon nanotubes, multi-walled carbon nanotubes, ultra-short carbon nanotubes, and combinations thereof.

4. The method of claim 1 , wherein the alkali metal source is selected from the group consisting of lithium, potassium, sodium, rubidium, cesium, alloys thereof, and combinations thereof.

5. The method of claim 1 , wherein the aprotic solvent is selected from the group consisting of diethyl ether, tetrahydrofuran, 1,4-dioxane, glyme, 1,2-dimethoxyethane, diglyme, tetraglyme, amines, N,N,N′,N′-tetramethylethylenediamine, triethylamine, 1,4-diazabicyclo[2.2.2]octane, trialkylamines, dialkylarylamines, alkyldiarylamines, dimethylformamide, and combinations thereof.

6. The method of claim 1 , wherein the protic solvent is selected from the group consisting of formic acid, n-butanol, isopropanol, n-propanol, ethanol, methanol, acetic acid, water, hydrochloric acid, sulfuric acid, ammonia, diethyl amine, dialkylamines, monoalkylamines, diarylamines, monoarylamines, monoalkymonoarylamines, and combinations thereof.

7. The method of claim 1 , further comprising a step of adding an electrophile to the unfunctionalized graphene nanoribbons, wherein the electrophile functionalizes the graphene nanoribbons.

8. The method of claim 7 , wherein the electrophile is selected from the group consisting of water, alcohols, organic halides, alkenes, alkynes, alkyl halides, acyl halides, allylic halides, benzyl halides, benzylic halide, alkenyl halides, aryl halides, alkynyl halides, fluoralkly halides, perfluoroalkyl halides, aldehydes, ketones, methyl vinyl ketones, esters, sulfonate esters, acids, acid chlorides, carboxylic acids, carboxylic esters, carboxylic acid chlorides, carboxylic acid anhydrides, carbonyl bearing compounds, enones, nitriles, carbon dioxide, halogens, monomers, vinyl monomers, ring-opening monomers, isoprenes, butadienes, styrenes, acrylonitriles, methyl vinyl ketones, methacrylates, 1,4-dimethoxy-2-vinylbenzene, methyl methacrylate, alkyl acrylates, alkyl methacrylates, trimethylsilyl chlorides, tert-butyldimethylsilyl chlorides, triphenylsilyl chlorides, epoxides, carbon dioxide, carbon disulfide, tert-butanol, 2-methylpropene, bromine, chlorine, iodine, fluorine, and combinations thereof.

9. The method of claim 7 , wherein the electrophile is carbon dioxide.

10. The method of claim 7 , wherein the electrophile is a monomer.

11. The method of claim 10 , wherein the monomer is selected from the group consisting of olefins, vinyl monomers, styrenes, isoprenes, butadienes, acrylonitriles, methyl vinyl ketones, alkyl acrylates, alkyl methacrylates, ring opening monomers, epoxides, and combinations thereof.

12. The method of claim 10 , wherein the monomer polymerizes upon addition to the graphene nanoribbons, thereby forming polymer-functionalized graphene nanoribbons.

13. The method of claim 7 , wherein the adding of electrophiles leads to the formation of edge-functionalized graphene nanoribbons.

14. The method of claim 1 , wherein the formed graphene nanoribbons have a conductivity ranging from about 0.1 S/cm to about 9,000 S/cm.

15. The method of claim 7 , further comprising a step of deintercalating functional groups from one or more layers of graphene nanoribbons.

16. The method of claim 15 , wherein the deintercalating occurs by heating the formed graphene nanoribbons.

17. The method of claim 1 , further comprising a step of exfoliating one or more layers of graphene from the formed graphene nanoribbons.

18. The method of claim 17 , wherein the exfoliating comprises exposure of the graphene nanoribbons to a gas, wherein the gas is selected from the group consisting of carbon dioxide, nitrogen gas, hydrogen gas, hydrogen chloride, air, and combinations thereof.

Assignees

• Tour James M
• Lu Wei
• Genorio Bostjan
• Univ Rice William M

Inventors

• Tour James M
• Lu Wei
• Genorio Bostjan

Classifications

• C07C29/32

  increasing the number of carbon atoms by reactions without formation of -OH groups · CPC title

• C01B31/0446

  Chemistry & Metallurgy · mapped topic

• C08F112/08 Primary

  Styrene · CPC title

• C01B31/0273

  Chemistry & Metallurgy · mapped topic

• C01B31/0293 Primary

  Chemistry & Metallurgy · mapped topic