Method for preventing the contamination by platinum of an SCR catalyst

Patent metadata

Field	Value
Publication number	US-9492787-B2
Application number	US-201314407725-A
Country	US
Kind code	B2
Filing date	Jun 10, 2013
Priority date	Jun 14, 2012
Publication date	Nov 15, 2016
Grant date	Nov 15, 2016

Abstract

The invention relates to a method for preventing the contamination by platinum of an SCR catalyst in an exhaust-gas treatment system, said system comprising an oxidation catalyst containing platinum on the inflow side of the SCR catalyst. The outflow side of the oxidation catalyst comprises a material zone which removes traces of platinum contained in the exhaust-gas stream.

First claim

The invention claimed is:

1. A method for preventing the contamination by platinum of an SCR catalyst in an exhaust gas treatment system, comprising:
passing an exhaust gas stream through the exhaust gas treatment system, the exhaust gas treatment system comprising an oxidation catalyst substrate positioned upstream of the SCR catalyst, wherein
the oxidation catalyst substrate comprises an oxidation-catalytically active coating containing platinum, and
the oxidation catalyst substrate further comprises, on an outflow side of the substrate, a material zone that removes traces of platinum contained in the exhaust gas stream.

2. The method as claimed in claim 1 , wherein
the material zone that removes traces of platinum contained in the exhaust gas stream extends over a length of the oxidation catalyst substrate such that the material zone covers, at least in part, the oxidation-catalytically active coating of the oxidation catalyst substrate.

3. The method as claimed in claim 2 , wherein the material zone that removes the traces of platinum contained in the exhaust gas stream occupies 50 to 100% of the total length of the oxidation catalyst substrate.

4. The method as claimed in claim 1 , wherein the oxidation-catalytically active coating and the material zone that removes the traces of platinum contained in the exhaust gas stream are present in separate zones on the oxidation catalyst substrate.

5. The method as claimed in claim 4 , wherein the material zone that removes the traces of platinum contained in the exhaust gas stream occupies 25 to 67% of the total length of the oxidation catalyst substrate.

6. The method as claimed in claim 1 , wherein the material zone that removes traces of platinum contained in the exhaust gas stream contains, as an active component, palladium, gold, or mixtures thereof.

7. The method as claimed in claim 6 , wherein the palladium, gold, or mixtures thereof are present in quantities of 0.02 to 0.21 g/l (0.5 to 6 g/ft 3 ) relative to the volume occupied by the material zone.

8. The method as claimed in claim 6 , wherein the palladium, gold, or mixtures thereof are present in quantities of 0.04 to 0.11 g/l (1 to 3 g/ft 3 ) relative to the volume occupied by the material zone.

9. The method as claimed in claim 6 , wherein the palladium, gold, or mixtures thereof are supported on a high-surface-area, inert supporting oxide.

10. The method as claimed in claim 9 , wherein the supporting oxide is aluminum oxide, doped aluminum oxides, titanium dioxide, cerium oxide, zirconium oxide, cerium/′zirconium mixed oxide, silicon dioxide, or a mixture of two or more of the stated oxides.

11. A method for preventing the contamination by platinum of an SCR catalyst in an exhaust gas treatment system, comprising:
passing an exhaust gas stream through the exhaust gas treatment system, the exhaust gas treatment system comprising an oxidation catalyst substrate positioned upstream of the SCR catalyst, wherein
the oxidation catalyst substrate comprises an oxidation-catalytically active coating, and
the oxidation catalyst substrate further comprises, on an outflow side of the substrate, a material zone that removes traces of platinum contained in the exhaust gas stream.

12. The method as claimed in claim 11 , wherein
the material zone that removes traces of platinum contained in the exhaust gas stream extends over a length of the oxidation catalyst substrate such that the material zone covers, at least in part, the oxidation-catalytically active coating of the oxidation catalyst substrate.

13. The method as claimed in claim 12 , wherein the material zone that removes the traces of platinum contained in the exhaust gas stream occupies 50 to 100% of the total length of the oxidation catalyst substrate.

14. The method as claimed in claim 11 , wherein the oxidation-catalytically active coating and the material zone that removes the traces of platinum contained in the exhaust gas stream are present in separate zones on the oxidation catalyst substrate.

15. The method as claimed in claim 14 , wherein the material zone that removes the traces of platinum contained in the exhaust gas stream occupies 25 to 67% of the total length of the oxidation catalyst substrate.

16. The method as claimed in claim 11 , wherein the material zone that removes traces of platinum contained in the exhaust gas stream contains, as an active component, palladium, gold, or mixtures thereof.

17. The method as claimed in claim 16 , wherein the palladium, gold, or mixtures thereof are present in quantities of 0.02 to 0.21 g/l (0.5 to 6 g/ft 3 ) relative to the volume occupied by the material zone.

18. The method as claimed in claim 16 , wherein the palladium, gold, or mixtures thereof are present in quantities of 0.04 to 0.11 g/l (1 to 3 g/ft 3 ) relative to the volume occupied by the material zone.

19. The method as claimed in claim 16 , wherein the palladium, gold, or mixtures thereof are supported on a high-surface-area, inert supporting oxide.

20. The method as claimed in claim 19 , wherein the supporting oxide is aluminum oxide, doped aluminum oxides, titanium dioxide, cerium oxide, zirconium oxide, cerium/′zirconium mixed oxide, silicon dioxide, or a mixture of two or more of the stated oxides.

Assignees

• Umicore Ag & Co Kg
• Unicore Ag & Co Kg

Inventors

• Schuetze Frank-Walter
• Pfeifer Marcus
• Schiffer Michael
• Symalla Martin
• Hengst Christoph

Classifications

• B01D2255/106

  Gold · CPC title

• F01N3/2066

  Selective catalytic reduction [SCR] · CPC title

• B01D53/9418 Primary

  for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas · CPC title

• B01J29/072

  Iron group metals or copper · CPC title

• B01D2255/1021

  Platinum · CPC title