Method for determining the concentration of iron ions in hydrocarbon compositions

Patent metadata

Field	Value
Publication number	US-9488633-B2
Application number	US-201414301446-A
Country	US
Kind code	B2
Filing date	Jun 11, 2014
Priority date	Dec 5, 2013
Publication date	Nov 8, 2016
Grant date	Nov 8, 2016

Abstract

The present invention relates to a method for determining the concentration of iron ions in a hydrocarbon composition, as well as reagents and kits for use in such methods. The method utilises a thiocarboxylic acid having formula (I) which reduces the ferric ions and complexes ferrous ions producing a colored solution, which can be analysed to determine the amount of iron ions in the starting sample.

First claim

The invention claimed is:

1. A method for determining the concentration of iron ions in a hydrocarbon composition, said method comprising:
a) providing a hydrocarbon composition;
b) reacting the hydrocarbon composition with a reagent composition and optionally a diluent composition comprising a non-polar solvent to provide a test sample,
wherein
the reagent composition comprises water and a compound according to formula (I):

 wherein
 n denotes an integer from 0 to 3, and
 R denotes H, alkyl or aryl, and
 wherein the reagent composition has a pH of 7.5 or above; and
c) determining the concentration of iron ions in the hydrocarbon sample by determining the amount of complex formed between the compound of formula (I) and iron ions in the test sample.

2. The method of claim 1 , wherein step b) comprises:
i. reacting a first amount of the hydrocarbon composition with said reagent composition and optionally said diluent composition to provide a test sample, and
ii. combining a second amount of the hydrocarbon composition with a blank composition comprising water and optionally said diluent composition to provide a blank sample, wherein the blank composition does not contain a compound of formula (I),
wherein the first amount and the second amounts are the same;
and wherein step c) comprises comparing the test sample and the blank sample.

3. The method according to claim 2 , wherein step b) comprises:
either:
mixing the diluent composition and the hydrocarbon composition,
adding the reagent composition to form the test sample and mixing the resultant sample, and
allowing the test sample to phase separate to form an aqueous phase and a hydrocarbon phase;

or:
mixing the reagent composition, the diluent composition and the hydrocarbon composition to form the test sample, and
allowing the test sample to phase separate to form an aqueous phase and a hydrocarbon phase;
and wherein
the blank sample is prepared in an analogous manner using the blank composition in place of the reagent composition.

4. The method of claim 3 , wherein step c) comprises detecting the complexed iron ions in the aqueous phase of the test sample using colorimetry or UV-Vis spectroscopy, optionally by subtracting the blank sample.

5. The method of claim 3 , wherein step c) comprises comparing a color of the aqueous phase of the test sample with a reference color chart, optionally viewed in combination with the aqueous phase of the blank sample.

6. The method of claim 2 , wherein the reagent composition and the blank composition comprise a salt.

7. The method of claim 2 , wherein the reagent composition and the blank composition comprises a buffer.

8. The method of claim 1 , wherein the hydrocarbon composition is engine oil.

9. The method of claim 1 , wherein, in the compound of formula (I):
n denotes 0; and
R denotes H or methyl.

10. The method of claim 1 , wherein the diluent composition further comprises a phase transfer agent.

11. The method of claim 10 , wherein the phase transfer agent is an alcohol.

12. The method of claim 11 , wherein the phase transfer agent is isopropyl alcohol.

13. The method of claim 1 , wherein the non-polar solvent is a petroleum distillate.

14. The method of claim 1 , wherein the hydrocarbon composition is spent engine oil.

Assignees

• Parker Hannifin Corp
• Kittiwake Dev Ltd

Inventors

• Atkinson David

Classifications

• Y10T436/21

  Hydrocarbon · CPC title

• G01N33/22 Primary

  Fuels; Explosives · CPC title

• G01N33/28

  Oils {, i.e. hydrocarbon liquids} (edible oils or edible fats G01N33/03) · CPC title

• G01N33/2858 Primary

  Metal particles · CPC title

• G01N31/22 Primary

  using chemical indicators (G01N31/02 takes precedence) · CPC title