Fuel compositions

Patent metadata

Field	Value
Publication number	US-9487718-B2
Application number	US-201514708520-A
Country	US
Kind code	B2
Filing date	May 11, 2015
Priority date	Feb 17, 2014
Publication date	Nov 8, 2016
Grant date	Nov 8, 2016

Abstract

Low sulphur marine fuel compositions are provided. Embodiments comprise 10 to 50 wt % of a residual hydrocarbon component, with the remaining 50 to 90 wt % selected from a non-hydroprocessed hydrocarbon component, a hydroprocessed hydrocarbon component, and a combination thereof. Embodiments of the marine fuel composition can have a sulphur content of about 0.1 wt % or less.

First claim

We claim:

1. A marine fuel composition comprising:
greater than 25 wt % to 50 wt % of a residual hydrocarbon component comprising an atmospheric tower bottoms (ATB) residues with a kinematic viscosity at 50 degrees C. of at least 100 cSt; and
wherein the marine fuel composition has a kinematic viscosity at 50 degrees C. of at least 10 cSt.

2. The marine fuel composition of claim 1 wherein the sulphur content is in a range of 400 to 1000 wppm.

3. The marine fuel composition of claim 1 which exhibits at least one of the following:
a hydrogen sulfide content of at most 2.0 mg/kg; an acid number of at most 2.5 mg KOH per gram; a sediment content of at most 0.1 wt %; a water content of at most 0.5 vol %; and an ash content of at most 0.15 wt %.

4. The marine fuel composition of claim 1 which has at least one of the following: a density at 15 degrees C. in a range of 0.870 to 1.010 g/cm 3 , a pour point of −30 to 35 degrees C., and a flash point of at least 60 degrees C.

5. The marine fuel composition of claim 4 wherein the density is in a range of at least 0.890 g/cm 3 to 1.010 g/cm 3 .

6. The marine fuel composition of claim 4 wherein the kinematic viscosity at 50 degrees C. is in a range of less than 12 cSt to at least 10 cSt.

7. The marine fuel composition of claim 1
wherein the amount of residual hydrocarbon component is at least 30 wt % to 50 wt %; and the composition further comprises:
at least 10 wt % of a non-hydroprocessed hydrocarbon component comprising at least one of light cycle oil (LCO), heavy cycle oil (HCO), fluid catalytic cracking (FCC) cycle oil, FCC slurry oil, pyrolysis gas oil, cracked light gas oil (CLGO), cracked heavy gas oil (CHGO), pyrolysis light gas oil (PLGO), pyrolysis heavy gas oil (PHGO), thermally cracked residue, thermally cracked heavy distillate, and coker heavy distillates.

8. The marine fuel composition of claim 1
wherein the amount of residual hydrocarbon component is at least 30 wt % to 50 wt %; and the composition further comprises:
at least 10 wt % of a hydroprocessed hydrocarbon component comprising at least one of low-sulfur diesel (LSD) having a sulphur content of less than 500 wppm, ultra low-sulfur diesel (ULSD) having a sulphur content of less than 15 wppm; hydrotreated light cycle oil (LCO); hydrotreated heavy cycle oil (HCO); hydrotreated pyrolysis gas oil, hydrotreated thermally cracked heavy distillate, hydrotreated thermally cracked gas oil, and hydrocracker diesel.

9. The marine fuel composition of claim 1 wherein the residual hydrocarbon component has a sulfur content of at most 0.4 wt %.

10. The marine fuel composition of claim 1 wherein the residual hydrocarbon component has a sulfur content of at most 0.2 wt %.

11. The marine fuel composition of claim 1 wherein the residual hydrocarbon component exhibits at least one of the following: a density at 15 degrees C. in a range of 0.7 to 1.0 g/cc; a pour point in a range of −19.0 to 64 degrees C., a flash point in a range of 80 to 213 degrees C.; and an acid number of up to 8.00 mgKOH/g.

12. The marine fuel composition of claim 1 wherein the residual hydrocarbon component further comprises short residues (VTB) which exhibit at least one of the following: a density at 15 degrees C. in a range of 0.8 to 1.1 g/cc; a pour point in a range of −15.0 to 95 degrees C., a flash point in a range of 220 to 335 degrees C.; an acid number of up to 8.00 mgKOH/g; and a kinematic viscosity at 50 degrees C. in a range of 3.75 to 15000 cSt.

13. The marine fuel composition of claim 7 wherein the non-hydroprocessed hydrocarbon component further comprises at least one of vacuum gas oil (VGO), coker diesel, coker gas oil, coker VGO, thermally cracked VGO, thermally cracked diesel, thermally cracked gas oil, Group I slack waxes, lube oil aromatic extracts, and deasphalted oil (DAO).

14. The marine fuel composition of claim 7 wherein the non-hydroprocessed hydrocarbon component further comprises at least one of coker kerosene, thermally cracked kerosene, gas-to-liquids (GTL) wax, GTL hydrocarbons, straight-run diesel, straight-run kerosene, and straight run gas oil (SRGO).

15. The marine fuel composition of claim 8 wherein the hydroprocessed hydrocarbon comprises at least one of hydrotreated coker diesel, hydrotreated coker gas oil, hydrotreated thermally cracked diesel, hydrotreated VGO, hydrotreated coker VGO, hydrotreated residues, hydrocracker bottoms, hydrotreated thermally cracked VGO, and hydrotreated DAO.

16. The marine fuel composition of claim 8 wherein the hydroprocessed hydrocarbon comprises at least one of ultra low sulfur kerosene (ULSK), hydrotreated jet fuel, hydrotreated kerosene, hydrotreated coker kerosene, hydrocracker kerosene, and hydrotreated thermally cracked kerosene.

17. A marine fuel composition comprising:
greater than 25 wt % to 50 wt % of a residual hydrocarbon component comprising a vacuum tower bottoms (VTB) residues with a kinematic viscosity at 50 degrees C. of at least 100 cSt; and
wherein the marine fuel composition has a kinematic viscosity at 50 degrees C. of at least 10 cSt.

18. The marine fuel composition of claim 17
wherein the amount of residual hydrocarbon component is at least 30 wt % to 50 wt %; and the composition further comprises:
at least 10 wt % of a non-hydroprocessed hydrocarbon component comprising at least one of light cycle oil (LCO), heavy cycle oil (HCO), fluid catalytic cracking (FCC) cycle oil, FCC slurry oil, pyrolysis gas oil, cracked light gas oil (CLGO), cracked heavy gas oil (CHGO), pyrolysis light gas oil (PLGO), pyrolysis heavy gas oil (PHGO), thermally cracked residue, thermally cracked heavy distillate, and coker heavy distillates.

19. The marine fuel composition of claim 17
wherein the amount of residual hydrocarbon component is at least 30 wt % to 50 wt %; and the composition further comprises:
at least 10 wt % of a hydroprocessed hydrocarbon component comprising at least one of low-sulfur diesel (LSD) having a sulphur content of less than 500 wppm, ultra low-sulfur diesel (ULSD) having a sulphur content of less than 15 wppm; hydrotreated light cycle oil (LCO); hydrotreated heavy cycle oil (HCO); hydrotreated pyrolysis gas oil, hydrotreated thermally cracked heavy distillate, hydrotreated thermally cracked gas oil, and hydrocracker diesel.

20. The marine fuel composition of claim 17 wherein the residual hydrocarbon component has a sulfur content of at most 0.4 wt %.

21. The marine fuel composition of claim 17 wherein the residual hydrocarbon component exhibits at least one of the following: a density at 15 degrees C. in a range of 0.8 to 1.1 g/cc; a pour point in a range of −15.0 to 95 degrees C., a flash point in a range of 220 to 335 degrees C.; an acid number of up to 8.00 mgKOH/g; and a kinematic viscosity at 50 degrees C. in a range of 3.75 to 15000 cSt.

22. The marine fuel composition of claim 17 which exhibits at least one of the following:
a hydrogen sulfide content of at most 2.0 mg/kg; an acid number of at most 2.5 mg KOH per gram; a sediment content of at most 0.1 wt %; a water content of at most 0.5 vol %; and an ash content of at most 0.15 wt %.

Assignees

• Shell Oil Co

Inventors

• Kraus Lawrence Stephen
• Droubi Danny F
• Lipinsky Dana Tatum
• Branch Michael Allen
• Delaney-Kinsella Cynthia
• Steernberg Koen
• Brumfield Tommy Louis
• Bru Ariel

Classifications

• C10L1/04 Primary

  essentially based on blends of hydrocarbons · CPC title

• C10L2270/02

  for internal combustion engines · CPC title

• C10L2200/0438

  Middle or heavy distillates, heating oil, gasoil, marine fuels, residua · CPC title