Rapid thickening of aminosilicones to promote emulsion stability and adhesion of UV-curable quantum dot enhancement film emulsions
US-12122948-B2 · Oct 22, 2024 · US
US9487695B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9487695-B2 |
| Application number | US-201214363133-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 5, 2012 |
| Priority date | Dec 5, 2011 |
| Publication date | Nov 8, 2016 |
| Grant date | Nov 8, 2016 |
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The present invention relates to an optical film and an optical display apparatus including the same. The optical film may include a base film and an optical functional layer formed on the base film, wherein at least one of the base film. The optical functional layer may include a luminescent material, and the luminescent material may include at least one of a fluorescent material and a phosphorescent material.
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The invention claimed is: 1. An optical film, comprising: a base film; and an optical functional layer formed on the base film, wherein at least one of the base film and the optical functional layer comprises a luminescent material, and the luminescent material includes at least one of 2,3,6,7-tetrahydro-1,1,7,7-tetramethyl-1H,5H,11H-10-(2-benzothiazolyl)quinolizino [9,9a,1gh] coumarin, 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran(E), N,N′-dimethyl-quinacridone, 9,10-bis[N,N-di-(p-tolyl)-amino]anthracene, 9,10-bis[phenyl(m-tolyl)-amino]anthracene, 5,6,11,12-tetraphenylnaphthacene, poly(naphthalene vinylene) (PNV), poly peri-naphthalene (PPN), tris[2-(p-tolyl)pyridine]iridium(III), bis[3,5-difluoro-2-(2-pyridyl)phenyl](2-carboxypyridyl)iridium(III), tris(2-phenylpyridine)iridium(III), and a mixture thereof, wherein the optical functional layer comprises at least one optical pattern selected from prisms, lenticular lenses, micro-lenses, and embossed shapes. 2. The optical film according to claim 1 , wherein the luminescent material has an absorption wavelength from about 240 nm to about 380 nm or from about 420 nm to about 480 nm, and a light emission wavelength from about 520 nm to about 580 nm. 3. The optical film according to claim 1 , wherein the luminescent material further includes a UV-curable functional group. 4. The optical film according to claim 1 , wherein the at least one of the base film and the optical functional layer of the optical film comprises a fluorene group. 5. The optical film according to claim 1 , wherein the luminescent material is present in an amount of about 0.001 wt % to about 0.5 wt % in the optical film. 6. The optical film according to claim 1 , wherein the optical film is used as a prism sheet, a diffusive sheet, or a light guide plate. 7. The optical film according to claim 1 , wherein the at least one of the base film and the optical functional layer of the optical film comprises a cured product of a resin composition comprising the luminescent material, a UV-curable unsaturated compound, and an initiator. 8. The optical film according to claim 7 , wherein the UV-curable unsaturated compound comprises a fluorene derivative unsaturated resin; and at least one selected from the group consisting of phenoxybenzyl (meth)acrylate, phenylphenoxy ethyl (meth)acrylate, phenylthioethyl (meth) acrylate, and mixtures thereof. 9. The optical film according to claim 7 , wherein the composition further comprises at least one of an ester reactive additive and a silicone reactive resin. 10. A resin composition for an optical film that includes a base film and an optical functional layer on the base film, the composition comprising: a luminescent material; a UV-curable unsaturated compound that includes a fluorene group; and an initiator, wherein the luminescent material includes at least one of 2,3,6,7-tetrahydro-1,1,7,7-tetramethyl-1H,5H,11H-10-(2-benzothiazolyl)quinolizino [9,9a,1gh] coumarin, 4-(dicyanomethylene)-2-tert-butyl-6-(1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran(E), N,N′-dimethyl-quinacridone, 9,10-bis[N,N-di-(p-tolyl)-amino]anthracene, 9,10-bis[phenyl(m-tolyl)-amino]anthracene, 5,6,11,12-tetraphenylnaphthacene, poly(naphthalene vinylene) (PNV), poly peri-naphthalene (PPN), tris[2-(p-tolyl)pyridine]iridium(III), bis[3,5-difluoro-2-(2-pyridyfiphenyl](2-carboxypyridyl)iridium(III), tris(2-phenylpyridine)iridium(III), and a mixture thereof, and wherein at least one of the base film and the optical functional layer comprises the luminescent material and the UV-curable unsaturated compound in a cured state. 11. The resin composition according to claim 10 , further comprising: at least one of an ester reactive resin and a silicone reactive resin. 12. The resin composition according to claim 10 , wherein the optical functional layer comprises at least one optical pattern selected from prisms, lenticular lenses, micro-lenses, and embossed shapes. 13. A liquid crystal display apparatus comprising the optical film according to claim 1 .
comprising acrylic (co)polymers · CPC title
Resin or rubber layer containing a blend of at least two different polymers · CPC title
with sulfur · CPC title
Scratch resistance · CPC title
containing two nitrogen atoms as heteroatoms · CPC title
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