Method for producing water-soluble nonionic cellulose ether excellent in storage stability

Patent metadata

Field	Value
Publication number	US-9487594-B2
Application number	US-201414305174-A
Country	US
Kind code	B2
Filing date	Jun 16, 2014
Priority date	Jun 26, 2013
Publication date	Nov 8, 2016
Grant date	Nov 8, 2016

Abstract

Provided is a water-soluble nonionic cellulose ether excellent in storage stability. More specifically, provided is a method for producing a water-soluble nonionic cellulose ether including an etherification step of reacting an alkali cellulose with an etherifying agent to obtain a crude cellulose ether, a washing step of washing the crude cellulose ether to obtain a washed cellulose ether, a drying step of drying the washed cellulose ether, and a grinding step of grinding the cellulose ether during or after the drying, wherein during the washing step or in any of the steps after the washing step, a pH regulator is mixed so as to allow an aqueous 2% by weight solution of the cellulose ether as an end product to have a pH value of from 7.0 to 10.5.

First claim

The invention claimed is:

1. A method for producing a water-soluble nonionic cellulose ether, comprising:
an etherification step of reacting an alkali cellulose with an etherifying agent to obtain a crude cellulose ether,
a washing step of washing the crude cellulose ether with water to obtain a washed cellulose ether,
a drying step of drying the washed cellulose ether, and
a grinding step of grinding the cellulose ether during or after the drying step,
wherein in the washing step or in any of the steps after the washing step, no acid is mixed but a pH regulator is mixed so as to allow an aqueous 2% by weight solution of the cellulose ether as an end product to have a pH value of from 7.0 to 10.5, and
wherein the pH regulator is at least one selected from the group consisting of sodium hydroxide, potassium hydroxide, sodium bicarbonate, and sodium carbonate.

2. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , wherein the grinding step comprises grinding with a rod mill or a ball mill.

3. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , wherein the grinding step comprises a stage of grinding the cellulose ether and a stage of mixing the cellulose ether thus ground, the stage of mixing comprising an addition of the pH regulator.

4. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , further comprising, after the washing step but before the drying step, a gelation step of gelling the washed cellulose ether, the gelation step comprising an addition of the pH regulator.

5. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , wherein the washing step comprises a dispersing stage of dispersing the crude cellulose ether in the water to obtain a cellulose ether dispersion, and a filtration stage of filtering the dispersion, the dispersing stage comprising incorporation of the pH regulator into the cellulose ether dispersion.

6. The method for producing a water-soluble nonionic cellulose ether according to claim 5 , wherein the dispersing stage comprises dispersing the crude cellulose ether in water, wherein the water is at a temperature of 70 to 100° C.

7. The method for producing a water-soluble nonionic cellulose ether according to claim 5 , wherein the filtration stage comprises rinsing with a liquid at a temperature of 70 to 100° C.

8. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , wherein the washing step comprises a dispersing stage of dispersing the crude cellulose ether in the water to obtain a cellulose ether dispersion, and a filtration stage of filtering the dispersion to obtain a residue and rinsing the residue with a rinsing liquid containing the pH regulator.

9. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , wherein the drying step comprises adding a pH regulator before, during or after drying.

10. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , wherein the drying step and the grinding step are conducted simultaneously, the grinding step comprising grinding of the washed cellulose ether during drying and an addition of the pH regulator.

11. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , wherein the water-soluble nonionic cellulose ether comprises at least one of alkyl cellulose, hydroxyalkyl cellulose, and hydroxyalkyl alkyl cellulose.

12. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , wherein the etherifying agent comprises at least one of methyl chloride, ethylene oxide, and propylene oxide.

13. The method for producing a water-soluble nonionic cellulose ether according to claim 1 , wherein the end product has a viscosity of from 30000 to 200000 mPa·s at 20° C. in an aqueous 2% by weight solution.

Assignees

• Shinetsu Chemical Co

Inventors

• Narita Mitsuo

Classifications

• C08B11/00 Primary

  Preparation of cellulose ethers {(rendering cellulose suitable for etherification C08B1/06)} · CPC title

• C08B11/193

  Mixed ethers, i.e. ethers with two or more different etherifying groups · CPC title

• C08B11/08

  with hydroxylated hydrocarbon radicals; Esters, ethers, or acetals thereof · CPC title

• C08B11/20 Primary

  Post-etherification treatments of chemical or physical type, {e.g. mixed etherification in two steps}, including purification · CPC title