Method of manufacturing magnetic particles

Patent metadata

Field	Value
Publication number	US-9487411-B2
Application number	US-201414258739-A
Country	US
Kind code	B2
Filing date	Apr 22, 2014
Priority date	Apr 23, 2013
Publication date	Nov 8, 2016
Grant date	Nov 8, 2016

Abstract

The method of manufacturing magnetic particles, wherein the magnetic particles are magnetic particles for magnetic recording, and includes subjecting starting material magnetic particles to glass component-adhering treatment to be adhered with a glass component, and subjecting the magnetic particles after the glass component-adhering treatment to coercive force-reducing treatment with heating, to provide magnetic particles having lower coercive force than the starting material magnetic particles.

First claim

What is claimed is:

1. A method of manufacturing magnetic particles, wherein
the magnetic particles are magnetic particles for magnetic recording, and
the method comprises:
subjecting starting material magnetic particles to a glass component-adhering treatment; and
subjecting the magnetic particles after the glass component-adhering treatment to coercive force-reducing treatment with heating, to provide magnetic particles having lower coercive force than the starting material magnetic particles,
wherein
the starting material magnetic particles are ferrite magnetic particles, and
the coercive force-reducing treatment is conducted by subjecting the magnetic particles after the glass component-adhering treatment to adhering with a transition metal-containing organic compound on the surface of the magnetic particles then thermally decomposing the compound.

2. The method of manufacturing magnetic particles according to claim 1 , wherein in the glass component-adhering treatment, a surface of the starting material magnetic particles is partially coated with the glass component.

3. The method of manufacturing magnetic particles according to claim 1 , wherein the glass component is a hydrolysis product of a silicon compound.

4. The method of manufacturing magnetic particles according to claim 3 , wherein the silicon compound is alkoxysilane.

5. The method of manufacturing magnetic particles according to claim 1 , which comprises admixing a precursor of the glass component to a solution comprising the starting material magnetic particles to subject the starting material magnetic particles to adhering with the glass component in the form of a hydrolysis product of the precursor.

6. The method of manufacturing magnetic particles according to claim 1 , which further comprises a step of removing the glass component from the surface of the magnetic particles after the coercive force-reducing treatment.

7. The method of manufacturing magnetic particles according to claim 6 , wherein the glass component is dissolved and removed with alkali.

8. The method of manufacturing magnetic particles according to claim 1 , wherein the coercive force-reducing treatment is conducted by heat treating the magnetic particles in a reducing atmosphere after the glass component-adhering treatment.

9. The method of manufacturing magnetic particles according to claim 8 , wherein the reducing atmosphere comprises reducing gas selected from the group consisting of hydrogen gas and hydrocarbon gas.

10. The method of manufacturing magnetic particles according to claim 8 , which further comprises, before the heat treatment, subjecting the magnetic particles after the glass component-adhering treatment to adhering with a transition metal salt on the surface of the magnetic particles.

11. The method of manufacturing magnetic particles according to claim 10 , wherein the thermal decomposition is conducted by gas phase thermal decomposition.

12. The method of manufacturing magnetic particles according to claim 10 , wherein the transition metal-containing organic compound is a transition metal complex comprising a ligand in the form of an acetyl acetonate compound.

13. The method of manufacturing magnetic particles according to claim 1 , wherein the starting material magnetic particles are hexagonal ferrite magnetic particles.

14. The method of manufacturing magnetic particles according to claim 1 , wherein the starting material magnetic particles are ε-iron oxide particles.

15. The method of manufacturing magnetic particles according to claim 1 , wherein the starting material magnetic particles have coercive force of equal to or greater than 230 kA/m.

16. The method of manufacturing magnetic particles according to claim 1 , wherein the magnetic particles provided through the coercive force-reducing treatment with heating have a particle size ranging from 8 nm to 30 nm.

Assignees

• Fujifilm Corp

Inventors

• Hattori Yasushi

Classifications

• C01G49/06 Primary

  Ferric oxide [Fe2O3] · CPC title

• C01G49/02

  Oxides; Hydroxides {(C01G49/0018 takes precedence)} · CPC title

• C01G49/0036

  containing one alkaline earth metal, magnesium or lead · CPC title

• C01P2004/84

  one phase coated with the other · CPC title

• C01P2006/42

  Magnetic properties · CPC title