Process for the oxidation of SO2 to SO3

Patent metadata

Field	Value
Publication number	US-9487401-B2
Application number	US-201314406155-A
Country	US
Kind code	B2
Filing date	Jun 3, 2013
Priority date	Jun 6, 2012
Publication date	Nov 8, 2016
Grant date	Nov 8, 2016

Abstract

The present invention relates to a process plant for the oxidation of SO 2 to SO 3 in a process gas, said process plant comprising a heat exchanger configured for heating the process gas by heat exchange with an oxidized process gas and/or a further oxidized process gas by providing thermal contact between said process gas and said oxidized process gas and/or said further oxidized process gas, a first zone of material catalytically active in oxidation of SO 2 to SO 3 , and a boiler configured for containing steam being heated by the oxidized process gas and/or the further oxidized process after said oxidized process gas has been cooled in the heat exchanger characterized in the cooled oxidized process gas in the boiler being non-condensing with the benefit of providing the possibility for a smaller heat exchanger which may be made with only moderate corrosion resistant materials, compared to a process plant according to the prior art, as well as a related process.

First claim

The invention claimed is:

1. A process for conversion of SO 2 to SO 3 in a raw process gas comprising the steps of:
a) heating the raw process gas by heat exchange with an oxidized process gas, providing a heated process gas;
b) contacting the heated process gas with a first zone of catalyst active in oxidation of SO 2 to SO 3 , providing an oxidized process gas;
c) withdrawing heat of reaction from one or both of the first zone of catalytically active material and the oxidized process gas to the raw process gas, by one or more heat transfer processes taken from the group consisting of convection, conduction, radiation, gas/gas heat exchange or by heat transfer medium facilitated heat exchange; and
d) further cooling the oxidized process gas by heat exchange in a boiler, receiving a feed of water, providing saturated steam and a cooled oxidized process gas in which the raw process gas, the heated process gas, the oxidized process gas and the cooled oxidized process gas is non-condensing with respect to sulfuric acid.

2. A process according to claim 1 further comprising the steps of:
e) contacting the oxidized process gas with one or more further zones of material catalytically active in oxidation of SO 2 to SO 3 , providing a further oxidized process gas,
f) cooling the oxidized process gas and/or the further oxidized process gas by heat exchange with the a process gas upstream the first zone of catalytically active material, in one or more heat exchangers, configured either as interbed coolers, as heat exchangers external to the reactor or as integrated heat exchangers in contact with catalyst.

3. A process according to claim 1 further comprising the step of pre-heating the raw process gas by heat exchange with a steam flow, prior to heating the process gas by heat exchange with the oxidized process gas, providing a pre-heated process gas.

4. A process according to claim 1 further comprising the step of mixing a process gas upstream the first zone of catalytically active material with a recycled warm process gas.

5. A process according to claim 1 in which the heat exchange between the raw process gas and one or more of the oxidized process gas or the further oxidized process gas is made in part by gas/gas heat exchange.

6. A process according to claim 1 in which the heat exchange between the raw process gas and one or more of the oxidized process gas or the further oxidized process gas is in part made by heat exchange facilitated by a heat transfer medium.

7. A process according to claim 1 , in which the raw process gas fluctuates in one or more of the parameters flow rate, pressure and SO 2 concentration.

8. A process according to claim 1 , in which the temperature of the steam is at least 10° C. above the H 2 SO 4 dew point of the cooled oxidized process gas.

9. A process according to claim 1 , in which the temperature of the steam is at least 200° C.

10. A process according to claim 1 , in which the raw process gas contains at least 2% H 2 O in excess to SO 2 .

11. A process according to claim 1 , in which the pressure of the steam is 30-100 barg.

12. A process according to claim 5 above, in which the heated heat transfer medium is cooled by heat exchange with boiling water or steam.

13. A process for production of sulfuric acid involving conversion of SO 2 to SO 3 according to claim 1 , and subsequent condensation of sulfuric acid in a condenser cooled by heat exchange with a gas.

14. A process plant for conversion of SO 2 to SO 3 in a process gas, said process plant comprising:
a heat transfer medium circuit and a process gas flow line;
a converter having a first zone of material catalytically active in oxidation of SO 2 to SO 3 connected to said flow line for receiving process gas;
a heat exchanger configured for heating the process gas by heat exchange with an oxidized process gas and/or a further oxidized process gas by providing thermal contact between said process gas and said oxidized process gas and/or said further oxidized process gas, wherein a tube section of the heat transfer medium circuit extends within said converter to facilitate indirect heat transfer between the oxidized process gas and/or further oxidized process gas and the tube section of the heat transfer medium circuit; and
a boiler configured for containing water including a water outlet line, a section of the water outlet line arranged downstream of the tube section to indirectly heat water by the oxidized process gas and/or the further oxidized process after said oxidized process gas has been cooled in the heat exchanger characterized in said boiler operating at a pressure defining the boiling temperature of the water as at least 10° C. above the sulphuric acid dew point of the oxidized process gas, wherein a water circuit of said boiler is not in liquid communication with said heat exchanger.

Assignees

• Haldor Topsoe As
• Haldor Topsoe As

Inventors

• Møllerhøj Martin

Classifications

• B01J2208/00256

  in a heat exchanger for the heat exchange medium separate from the reactor · CPC title

• C01B17/765 Primary

  Multi-stage SO3-conversion · CPC title

• C01B17/76

  by contact processes · CPC title

• C01B17/803

  Converters · CPC title

• B01J2208/027

  Beds · CPC title