Process for producing water-absorbing polymer particles

Patent metadata

Field	Value
Publication number	US-9486777-B2
Application number	US-201314011384-A
Country	US
Kind code	B2
Filing date	Aug 27, 2013
Priority date	Aug 29, 2012
Publication date	Nov 8, 2016
Grant date	Nov 8, 2016

Abstract

The invention relates to a process for producing water-absorbing polymer particles, comprising polymerization, drying the resulting polymer gel on a through circulation belt dryer, crushing the dried polymer gel, pre-grinding, separating of incompletely dried particles with a perforated plate, grinding and classifying the resulting polymer particles.

First claim

The invention claimed is:

1. A process for producing water-absorbing polymer particles, comprising polymerization of a monomer solution or suspension, comprising
a) at least one ethylenically unsaturated monomer which bears an acid group and may be at least partly neutralized,
b) at least one crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a), and
e) optionally one or more water-soluble polymer,
drying the resulting polymer gel on a through circulation belt dryer, crushing the dried polymer gel, pre-grinding the crushed and dried polymer gel to provide coarse polymer particles, separating incompletely dried particles from the coarse dried polymer particles with a set of two vibrating screens having perforated plates, grinding the coarse dried polymer particles, and classifying resulting coarse dried polymer particles, wherein the vibrating screen is a perforated plate having a thickness from 0.5 to 5 mm, an opening area from 20 to 80%, and a hole diameter from 5 to 20 mm.

2. The process according to claim 1 , wherein a moisture content of the incompletely dried particles is at least 10% by weight.

3. The process according to claim 1 , wherein the dried polymer gel is crushed by means of a toothed roll.

4. The process according to claim 1 , wherein the crushed particles are pre-grinded by means of a roller mill having a gap width of at least 1 mm.

5. The process according to claim 1 , wherein the resulting coarse dried polymer particles are grinded by a multistage roller mill having a gap width of from 0.1 to 1 mm.

6. The process according to claim 1 , wherein the separated incompletely dried particles are further dried by means of a contact dryer.

7. The process according to claim 1 , wherein the separated incompletely dried particles are cut prior to further drying.

8. The process according to claim 1 , wherein a hole diameter of an upper perforated plate is at least 2 mm larger than a hole diameter of a lower perforated plate.

9. The process according to claim 1 , wherein only the incompletely dried particles that are separated by the upper perforated plate are cut prior to further drying.

10. The process according to claim 1 , wherein a proportion of acrylic acid in the total amount of ethylenically unsaturated monomer a) is at least 95 mol %.

11. The process according to claim 1 , wherein a degree of neutralization of the ethylenically unsaturated monomer a) is from 65 to 80 mol %.

12. The process according to claim 1 , wherein the amount of crosslinker b) based on monomer a) is 0.3 to 0.6% by weight.

13. The process according to claim 1 , wherein the water-absorbing polymer particles have a centrifuge retention capacity of at least 15 g/g.

14. The process according to claim 1 , wherein the water-absorbing polymer particles are further surface postcrosslinked.

Assignees

• Basf Se

Inventors

• Peterson Monte
• Guentzel John Perry
• Boykin Gregory
• Van Miert Leo
• Callot Rene
• Stephan Oskar
• Funk Rüdiger
• Weismantel Matthias

Classifications

• C08F6/008

  Treatment of solid polymer wetted by water or organic solvents, e.g. coagulum, filter cakes · CPC title

• C08J2333/02

  Homopolymers or copolymers of acids; Metal or ammonium salts thereof · CPC title

• A61L15/60

  Liquid-swellable gel-forming materials, e.g. super-absorbents · CPC title

• B01J20/261 Primary

  obtained by reactions only involving carbon to carbon unsaturated bonds (macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds per se C08F) · CPC title

• C08F2/10 Primary

  Aqueous solvent · CPC title