Redox shuttles having an aromatic ring fused to a 1,1,4,4-tetrasubstituted cyclohexane ring
US-9203112-B2 · Dec 1, 2015 · US
US9484585B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9484585-B2 |
| Application number | US-201514613939-A |
| Country | US |
| Kind code | B2 |
| Filing date | Feb 4, 2015 |
| Priority date | Feb 5, 2014 |
| Publication date | Nov 1, 2016 |
| Grant date | Nov 1, 2016 |
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There is provided non-aqueous organic electrolytic solution for a lithium primary battery which can be stored for long period at elevated temperatures or at the end stage of discharge. Non-aqueous organic electrolytic solution 20 for lithium primary battery 1 having a cathode active material which is manganese dioxide and an anode active material which is either of lithium or lithium alloy includes a base electrolytic solution that is composed of organic solvent and supporting electrolyte and to which either one of hydroxyphthalimide or hydroxyphthalimide derivative is added as an additive. An amount of the additive which is added to the base electrolytic solution is 0.1 wt % or more and 5.0 wt % or less. It is more preferable that the amount of the additive which is added to the base electrolytic solution is 0.1 wt % or more and 1.0 wt % or less.
Opening claim text (preview).
What is claimed is: 1. A lithium primary battery, comprising: a positive electrode which contains manganese dioxide as a cathode active material; a negative electrode which is composed of either lithium or lithium alloy, and which has a surface area smaller than that of the positive electrode, the lithium and lithium alloy serving as an anode active material; a base electrolytic solution that is composed of organic solvent and electrolyte; and an additive which contains either one of hydroxyphthalimide and hydroxyphthalimide derivative the additive of 0.1 wt % or more and 5.0 wt % or less is added to the base electrolytic solution. 2. A lithium primary battery according to claim 1 , wherein the additive of 0.1 wt % or more and 1.0 wt % or less is added to the base electrolytic solution.
for non-aqueous cells (H01M4/505 takes precedence) · CPC title
Alloys based on lithium · CPC title
Lithium (H01M4/405 takes precedence) · CPC title
by additives · CPC title
characterised by the additives · CPC title
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