Solid solution pigment nanoparticles and method for producing solid solution pigment nanoparticles having controlled solid solution ratio

Patent metadata

Field	Value
Publication number	US-9481694-B2
Application number	US-201113883692-A
Country	US
Kind code	B2
Filing date	May 20, 2011
Priority date	Nov 24, 2010
Publication date	Nov 1, 2016
Grant date	Nov 1, 2016

Abstract

The problem addressed by the present invention is to provide; solid solution pigment nanoparticles having a homogeneous solid solution ratio; a method for producing solid solution pigment nanoparticles having a homogeneous solid solution ratio in each primary particle; and a method for controlling the solid solution ratio of solid solution pigment nanoparticles. The solid solution pigment nanoparticles are prepared by precipitating at least two types of pigment by mixing a pigment precipitation solvent and; at least one type of pigment solution wherein at least two types of pigment are dissolved in a solvent: or at least two types of pigment solution wherein at least one type of pigment is dissolved in a solvent. The solid solution pigment nanoparticles are wherein the solid solution ratio of the at least two types of pigment in the primary particles of the precipitated solid solution pigment nanoparticles with respect to the ratio of the at least two types of pigment in the pigment solution mixed with the pigment precipitation solvent having a precision within 25%.

First claim

The invention claimed is:

1. A method for producing a solid solution pigment nanoparticle, comprising the steps of:
introducing a pigment separation solvent, as a first fluid, with at least one pigment solution having at least two types of pigment dissolved in a solvent, as a second fluid, into a processing device, the processing device comprising at least two processing surfaces facing each other, the at least two processing surfaces being operable to approach to and separate from each other, at least one of the at least two processing surfaces rotating relative to the other;
mixing the first fluid and the second fluid to form a thin film fluid between the at least two processing surfaces; and
separating the solid solution pigment nanoparticle having a controlled solid solution ratio,
wherein the solid solution pigment nanoparticle is produced by separating at least two types of pigment,
wherein the controlled solid solution ratio of at least two types of pigment in a primary particle of the separated solid solution pigment nanoparticle relative to a ratio of at least two types of pigment in the pigment solution mixed with the pigment separation solvent is within 25% as a degree of precision.

2. The method for producing a solid solution pigment nanoparticle according to claim 1 , wherein the degree of precision of the solid solution ratio of at least two types of pigment in a primary particle of the separated solid solution pigment nanoparticle relative to the ratio of at least two types of pigment in the pigment solution mixed with the pigment separation solvent is obtained by a TEM-EDS measurement with the observation condition of 250,000 or more magnification.

3. The method for producing a solid solution pigment nanoparticle according to claim 1 , wherein the degree of precision of the solid solution ratio obtained by the TEM-EDS measurement relative to the solid solution ratio obtained by an ICP emission spectrometric analysis of the solid solution pigment nanoparticle is within 20%.

4. The method for producing a solid solution pigment nanoparticle according to claim 1 , wherein the solid solution ratio of at least two different types of pigment in the solid solution pigment nanoparticle is controlled by controlling a ratio of the at least two different types of pigment in the second fluid to be mixed.

5. The method for producing a solid solution pigment nanoparticle according to claim 4 , wherein the ratio of the pigments is a mixture dissolution ratio (mol ratio).

6. The method for producing a solid solution pigment nanoparticle according to claim 1 , wherein the controlled solid solution ratio of at least two types of pigment in a primary particle of the separated solid solution pigment nanoparticle relative to a ratio of at least two types of pigment in the pigment solution mixed with the pigment separation solvent is within 10% as a degree of precision.

7. The method for producing a solid solution pigment nanoparticle according to claim 6 , wherein the degree of precision of the solid solution ratio of at least two types of pigment in a primary particle of the separated solid solution pigment nanoparticle relative to the ratio of at least two types of pigment in the pigment solution mixed with the pigment separation solvent is obtained by a TEM-EDS measurement with the observation condition of 250,000 or more magnification.

8. The method for producing a solid solution pigment nanoparticle according to claim 6 , wherein the degree of precision of the solid solution ratio obtained by the TEM-EDS measurement relative to the solid solution ratio obtained by an ICP emission spectrometric analysis of the solid solution pigment nanoparticle is within 20%.

9. The method for producing a solid solution pigment nanoparticle according to claim 1 , wherein the controlled solid solution ratio of at least two types of pigment in a primary particle of the separated solid solution pigment nanoparticle relative to a ratio of at least two types of pigment in the pigment solution mixed with the pigment separation solvent is within 5% as a degree of precision.

10. The method for producing a solid solution pigment nanoparticle according to claim 9 , wherein the degree of precision of the solid solution ratio of at least two types of pigment in a primary particle of the separated solid solution pigment nanoparticle relative to the ratio of at least two types of pigment in the pigment solution mixed with the pigment separation solvent is obtained by a TEM-EDS measurement with the observation condition of 250,000 or more magnification.

11. The method for producing a solid solution pigment nanoparticle according to claim 9 , wherein the degree of precision of the solid solution ratio obtained by the TEM-EDS measurement relative to the solid solution ratio obtained by an ICP emission spectrometric analysis of the solid solution pigment nanoparticle is within 20%.

12. A method for producing a solid solution pigment nanoparticle, comprising the steps of:
introducing at least two pigment solutions each having at least one type of pigment dissolved in a solvent, as a first fluid and a second fluid, and a pigment separation solvent, as a third fluid, into a processing device, the processing device comprising at least two processing surfaces facing each other, the at least two processing surfaces being operable to approach to and separate from each other, at least one of the at least two processing surfaces rotating relative to the other, wherein the at least one type of pigment dissolved in the first fluid is different from the at least one type of pigment dissolved in the second fluid;
mixing the first fluid, the second fluid and the third fluid to form a thin film fluid between the at least two processing surfaces; and
separating the solid solution pigment nanoparticle having a controlled solid solution ratio,
wherein the solid solution pigment nanoparticle is produced by separating at least two types of pigment,
wherein the controlled solid solution ratio of at least two types of pigment in a primary, particle of the separated solid solution pigment nanoparticle relative to a ratio of at least two types of pigment in the pigment solutions mixed with the pigment separation solvent is within 25% as a degree of precision.

13. The method for producing a solid solution pigment nanoparticle according to claim 12 , wherein the solid solution ratio of the at least one type of pigment dissolved in the first fluid and the at least one type of pigment dissolved in the second fluid in the solid solution pigment nanoparticle is controlled by controlling a ratio of the at least one type of pigment dissolved in the first fluid and the at least one type of pigment dissolved in the second fluid to be mixed.

14. The method for producing a solid solution pigment nanoparticle according to claim 12 , wherein the controlled solid solution ratio of at least two types of pigment in a primary particle of the separated solid solution pigment nanoparticle relative to a ratio of at least two types of pigment in the pigment solutions mixed with the pigment separation solvent is within 10% as a degree of precision.

15. The method for producing a solid solution pigment nanoparticle according to claim 14 , wherein the degree of precision of the solid solution ratio of at least two types of pigment in a primary particle of the separated solid solution pigment nanoparticle relative to the ratio of at least two types of pigment in the pigment solutions mixed with the pigment separation solvent is obtained by a TEM-EDS measurement with the observation condition of 250,000 or more

Assignees

• Maekawa Masaki
• Araki Kaeko
• Oka Hideyuki
• Honda Daisuke
• Enomura Masakazu
• M Technique Co Ltd

Inventors

• Maekawa Masaki
• Araki Kaeko
• Oka Hideyuki
• Honda Daisuke
• Enomura Masakazu

Classifications

• B01F3/0861

  Operations & Transport · mapped topic

• C09C1/04

  Compounds of zinc {(C09C1/0003, C09C1/0009, C09C1/0015, C09C1/0078 take precedence)} · CPC title

• C09B67/0017

  Influencing the physical properties by treatment with an acid, H2SO4 · CPC title

• C09C1/627

  Copper · CPC title

• C07F1/08

  Copper compounds · CPC title