Method for preparing 4-(hydroxymethylphosphinyl)-2-oxobutanoic acid
US-2025084110-A1 · Mar 13, 2025 · US
US9481640B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9481640-B2 |
| Application number | US-201514945843-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 19, 2015 |
| Priority date | Oct 24, 2007 |
| Publication date | Nov 1, 2016 |
| Grant date | Nov 1, 2016 |
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This invention relates to novel electron deficient olefins, such as certain 2-cyanoacrylates and methylidene malonates, prepared using an imine or an iminium salt.
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What is claimed is: 1. One or more compounds selected from the group consisting of 2. A composition comprising: (a) or more compounds of claim 1 ; (b) a stabilizer package comprising at least one of a free radical stabilizer and an anionic stabilizer; and (c) optionally, one or more additives selected from the group consisting of cure accelerators, thickeners, thixotropes, tougheners, thermal resistance-conferring agents, and plasticizers. 3. The composition of claim 2 , further comprising a coreactant. 4. The composition of claim 3 , wherein the coreactant is a member selected from the group consisting of epoxides, episulfides, oxetanes, thioxetanes, dioxolanes, dioxanes, isocyanates, maleimides, oxazolines, (meth)acrylates, acrylamides, cyanoacrylates, methylidene malonates, vinyl ethers and combinations thereof. 5. The composition of claim 4 , wherein the cyanoacrylate is within structure IV: wherein in this connection R 1 is selected from C 1-16 alkyl, alkoxyalkyl, cycloalkyl, alkenyl, alkynyl, arylalkyl, aryl, or haloalkyl groups. 6. The composition of claim 4 , wherein the cyanoacrylate is selected from methyl cyanoacrylate, ethyl-2-cyanoacrylate, propyl cyanoacrylates, butyl cyanoacrylates, octyl cyanoacrylates, allyl cyanoacrylate, β-methoxyethyl cyanoacrylate and combinations thereof.
Nitriles · CPC title
containing cyano groups and singly-bound oxygen atoms bound to the same unsaturated acyclic carbon skeleton · CPC title
containing cyano groups and doubly-bound oxygen atoms bound to the same acyclic carbon skeleton · CPC title
Dicarboxylic acid esters having only one carbon-to-carbon double bond · CPC title
Phenols; Phenolates · CPC title
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