Method for manufacturing storage battery electrode, storage battery electrode, storage battery, and electronic device

Patent metadata

Field	Value
Publication number	US-9478807-B2
Application number	US-201514970733-A
Country	US
Kind code	B2
Filing date	Dec 16, 2015
Priority date	Jun 15, 2012
Publication date	Oct 25, 2016
Grant date	Oct 25, 2016

Abstract

To provide a method for forming a storage battery electrode including an active material layer with high density in which the proportion of conductive additive is low and the proportion of the active material is high. To provide a storage battery having a higher capacity per unit volume of an electrode with the use of a storage battery electrode formed by the formation method. A method for forming a storage battery electrode includes the steps of forming a mixture including an active material, graphene oxide, and a binder; providing a mixture over a current collector; and immersing the mixture provided over the current collector in a polar solvent containing a reducer, so that the graphene oxide is reduced.

First claim

What is claimed is:

1. A method for manufacturing a storage battery, comprising the steps of:
forming a mixture comprising an active material, graphene oxide, a binder, and a solvent;
providing the mixture over a surface to form an active material layer;
evaporating the solvent in the active material layer;
reducing the graphene oxide in the active material layer to form a graphene; and
consolidating the active material layer by a compression method,
wherein the step of reducing the graphene oxide is performed in a polar solvent comprising a reducer.

2. The method for manufacturing a storage battery, according to claim 1 , wherein the graphene comprises oxygen after the step of reducing the graphene oxide.

3. The method for manufacturing a storage battery, according to claim 2 , wherein a proportion of the oxygen is higher than or equal to 2 at. % and lower than or equal to 20 at. % in the graphene.

4. The method for manufacturing a storage battery, according to claim 1 , wherein the reducer comprises at least one of ascorbic acid, hydrazine, dimethyl hydrazine, hydroquinone, tetra butyl ammonium bromide, NaBH 4 , LiAlH 4 , ethylene glycol, polyethylene glycol, and N,N-diethylhydroxylamine.

5. The method for manufacturing a storage battery, according to claim 1 ,
wherein the polar solvent comprises at least one of water, methanol, ethanol, acetone, tetrahydrofuran, dimethylformamide, N-methylpyrrolidone, and dimethyl sulfoxide.

6. The method for manufacturing a storage battery, according to claim 1 , wherein the active material layer comprises lithium.

7. The method for manufacturing a storage battery, according to claim 1 , wherein the step of reducing the graphene oxide is performed at higher than or equal to room temperature and lower than or equal to 150° C.

8. The method for manufacturing a storage battery, according to claim 1 , wherein the step of consolidating the active material layer is performed after the step of reducing the graphene oxide.

9. An electronic device comprising the storage battery according to claim 1 .

10. A method for manufacturing a storage battery, comprising the steps of:
forming a mixture comprising an active material, graphene oxide, a binder, and a solvent;
providing the mixture over a surface to form an active material layer;
evaporating the solvent in the active material layer;
reducing the graphene oxide in the active material layer; and
consolidating the active material layer by a compression method,
wherein the step of reducing the graphene oxide is performed by immersing the active material layer in a polar solvent comprising a reducer.

11. The method for manufacturing a storage battery, according to claim 10 , wherein the reduced graphene oxide comprises oxygen after the step of reducing the graphene oxide.

12. The method for manufacturing a storage battery, according to claim 11 wherein a proportion of the oxygen is higher than or equal to 2 at. % and lower than or equal to 20 at. % in the reduced graphene oxide.

13. The method for manufacturing a storage battery, according to claim 10 , wherein the reducer comprises at least one of ascorbic acid, hydrazine, dimethyl hydrazine, hydroquinone, tetra butyl ammonium bromide, NaBH 4 , LiAlH 4 , ethylene glycol, polyethylene glycol, and N,N-diethylhydroxylamine.

14. The method for manufacturing a storage battery, according to claim 10 , wherein the polar solvent comprises at least one of water, methanol, ethanol, acetone, tetrahydrofuran, dimethylformamide, N-methylpyrrolidone, and dimethyl sulfoxide.

15. The method for manufacturing a storage battery, according to claim 10 , wherein the active material layer comprises lithium.

16. The method for manufacturing a storage battery, according to claim 10 , wherein the step of reducing the graphene oxide is performed at higher than or equal to room temperature and lower than or equal to 150° C.

17. The method for manufacturing a storage battery, according to claim 10 , wherein the step of consolidating the active material layer is performed after the step of reducing the graphene oxide.

18. An electronic device comprising the storage battery according to claim 10 .

Assignees

• Semiconductor Energy Lab

Inventors

• Yukawa Mikio

Classifications

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/139

  Processes of manufacture · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/64

  Carriers or collectors · CPC title

• H01M4/0404 Primary

  by coating on electrode collectors · CPC title