Method for producing a photovoltaic cell having a heterojunction, and resulting photovoltaic cell

Patent metadata

Field	Value
Publication number	US-9478686-B2
Application number	US-201314429654-A
Country	US
Kind code	B2
Filing date	Sep 23, 2013
Priority date	Sep 24, 2012
Publication date	Oct 25, 2016
Grant date	Oct 25, 2016

Abstract

A method for producing a heterojunction solar cell including the following successive steps: providing a substrate made from crystalline semiconductor material, doped with a first type of doping, and provided with a first main face; depositing a first layer of intrinsic amorphous semiconductor material on said first main face of the substrate; and forming a second layer of amorphous semiconductor material on the first layer. The method includes deposition of a barrier layer between the first and second layers, said barrier layer being of different nature from those of the first and second layers and includes doping of the second layer by ion implantation.

First claim

The invention claimed is:

1. A method for producing a heterojunction solar cell comprising the following successive steps:
providing a substrate made from crystalline semiconductor material, doped with a first type of doping, and provided with a first main face,
depositing a first layer of intrinsic amorphous semiconductor material on said first main face of the substrate,
depositing a barrier layer on the first layer,
forming a second layer of amorphous semiconductor material on the barrier layer, and
doping the second layer by ion implantation,
wherein said barrier layer is a different chemical composition from those of the first layer and second layer and acts as a barrier during the ion implantation.

2. The method according to claim 1 , wherein the barrier layer is semiconducting.

3. The method according to claim 1 , wherein the barrier layer is made from silicon oxide, silicon nitride, metal or a transparent conducting oxide.

4. The method according to claim 1 , wherein the barrier layer has a thickness of less than 5 nm.

5. The method according to claim 1 , wherein the barrier layer is transparent.

6. The method according to claim 1 , wherein the barrier layer is deposited at a temperature of less than 200° C.

7. The method according to claim 1 , wherein the first and second layers each have a thickness of less than 15 nm.

8. The method according to claim 1 , wherein the doping step by ion implantation of the second layer locally forms two types of doping in said layer so as to form a first P-type area adjacent to a second N-doped area.

9. A method for producing a heterojunction solar cell comprising the following successive steps:
providing a substrate made from crystalline semiconductor material, doped with a first type of doping, and provided with a first main face,
depositing a first layer of intrinsic amorphous semiconductor material on said first main face of the substrate,
depositing a barrier layer on the first layer, wherein the barrier layer is a semiconducting material or is made from one or more selected from the group consisting of Cr, Al, Ti, silicon oxide, silicon nitride, or silicon carbide,
forming a second layer of amorphous semiconductor material on the barrier layer, and
doping the second layer by ion implantation,
wherein said barrier layer is a different chemical composition from those of the first layer and second layer and acts as a barrier during the ion implantation.

10. The method according to claim 9 , wherein the silicon oxide is a doped silicon oxide and the silicon nitride is a doped silicon nitride.

Assignees

• Commissariat Energie Atomique
• Commissariat à l'Energie Atomique et aux Energies Alternatives

Inventors

• Ozanne Anne-Sophie
• Munoz Maria-Delfina
• Nguyen Nathalie

Classifications

• Y02E10/50

  Photovoltaic [PV] energy · CPC title

• H10F71/10

  the devices comprising amorphous semiconductor material · CPC title

• H10F10/166 Primary

  the Group IV-IV heterojunctions being heterojunctions of crystalline and amorphous materials, e.g. silicon heterojunction [SHJ] photovoltaic cells · CPC title

• H10F10/164

  comprising heterojunctions with Group IV materials, e.g. ITO/Si or GaAs/SiGe photovoltaic cells · CPC title

• H10F77/166 Primary

  Amorphous semiconductors · CPC title