Coating agent based on a copper-nanoparticle biohybrid and use thereof as a biocidal agent
US-2024180162-A1 · Jun 6, 2024 · US
US9476017B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9476017-B2 |
| Application number | US-201314406162-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 7, 2013 |
| Priority date | Jun 7, 2012 |
| Publication date | Oct 25, 2016 |
| Grant date | Oct 25, 2016 |
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Methods are provided which include a method of cleaning, sanitizing, or disinfecting, wherein the method comprises: contacting a soiled substrate with a cleaning, sanitizing, or disinfecting composition, such that at least a portion of the soil is removed from the substrate; wherein the cleaning, sanitizing, or disinfecting composition consists essentially of one or more food grade agents or a salt thereof; and wherein the method is effluent neutral.
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What is claimed is: 1. A method of cleaning, sanitizing, or disinfecting, wherein the method comprises: contacting a soiled substrate with a cleaning, sanitizing, or disinfecting composition, such that at least a portion of the soil is removed from the substrate; wherein the cleaning, sanitizing, or disinfecting composition consists essentially of tripolyphosphoric acid or a salt thereof and optionally one or more food grade agents selected from the group consisting of carbonate, peroxyacetic acid or salt thereof, and hydrogen peroxide; and wherein the method does not include contacting the substrate with hydroxide, is effluent neutral, and is a clean-in-place (CIP) or sanitize-in-place (SIP) method. 2. The method of claim 1 comprising recycling the cleaning, sanitizing, or disinfecting composition for further use, wherein the composition comprises solids that are separated before further use of the composition in cleaning, sanitizing, or disinfecting soiled substrates. 3. The method of claim 2 wherein the separated solids are added to an animal feedstock. 4. The method of claim 1 , wherein the cleaning, sanitizing, or disinfecting composition is added to an animal feedstock. 5. The method of claim 4 wherein the cleaning, sanitizing, or disinfecting composition is concentrated before being added to an animal feedstock. 6. The method of claim 1 , wherein the soil on the soiled substrate comprises a residue of a grain, dairy product, alcoholic beverage, non-alcoholic beverage, fruit, vegetable, meat, animal food, soiled dish residue, an industrial fermentation product, algae, biofuel, pharmaceutical, nutritional supplement, cosmetic, or a combination of any two or more thereof. 7. The method of claim 1 , wherein the substrate is selected from the group consisting of a brewing apparatus for an alcoholic beverage, apparatus for producing a non-alcoholic beverage, apparatus for producing a dairy product, food-processing apparatus, industrial fermentation apparatus, apparatus for producing biofuel, pharmaceutical processing apparatus, cosmetic processing apparatus, apparatus for producing a nutritional supplement, and a dish-washing apparatus. 8. A method of cleaning, sanitizing, or disinfecting wherein the method consists of: contacting a soiled substrate with a cleaning, sanitizing, or disinfecting composition, such that at least a portion of the soil is removed from the substrate; and optionally rinsing the substrate one or more times with water; wherein the cleaning, sanitizing, or disinfecting composition consists of tripolyphosphoric acid or salt thereof, water, and optionally one or more food grade agents selected from the group consisting of hydroxide, carbonate, hydrogen peroxide, and peracetic acid or a salt thereof; and wherein the method is effluent neutral, and is a clean-in-place (CIP) or sanitize-in-place (SIP) method. 9. The method of claim 8 wherein carbonate is formed in the cleaning, sanitizing, or disinfecting composition, and the carbonate does not substantially reduce the cleaning, sanitizing, or disinfecting efficacy of the cleaning, sanitizing, or disinfecting composition. 10. The method of claim 8 wherein carbonate is formed in the cleaning, sanitizing, or disinfecting composition, and the carbonate does not substantially reduce activity of an enzyme used during liquefaction or fermentation of sugar-based materials during the production of an alcohol. 11. The method of claim 8 , wherein the cleaning, sanitizing, or disinfecting composition consists of about 0.01-5.0 wt. % potassium tripolyphosphoric acid, 0-2.0 wt. % sodium hydroxide, 0-2.0 wt. % sodium carbonate, 0-2.0 wt. % hydrogen peroxide, 0-2.0 wt. % peracetic acid, and water. 12. A method of cleaning, sanitizing, or disinfecting, wherein the method comprises: contacting a soiled substrate with a cleaning, sanitizing, or disinfecting composition, such that at least a portion of the soil is removed from the substrate; wherein the cleaning, sanitizing, or disinfecting composition consists essentially of a phosphoric acid or a salt thereof, one or more organic acids or a salt thereof, and a hydrotrope agent; and wherein the method does not include contacting the substrate with hydroxide, is effluent neutral, and is a clean-in-place (CIP) or sanitize-in-place (SIP) method. 13. The method of claim 8 , wherein the soiled substrate is a fermentation apparatus for the fermentation of a sugar-based material into a biofuel and the biofuel is selected from the group consisting of ethanol, butanol, biodiesel, biogas, and syngas. 14. The method of claim 12 , wherein the hydrotrope agent is selected from the group consisting of benzene sulfonates, naphthalene sulfonates, alkyl benzene sulfonates, naphthalene sulfonates, alkyl sulfonates, alkyl sulfates, alkyl diphenyloxide disulfonates, and phosphate ester hydrotropes. 15. The method of claim 12 wherein the phosphoric acid is tripolyphosphoric acid or a salt thereof. 16. A method of cleaning, sanitizing, or disinfecting, wherein the method comprises: contacting a soiled substrate with a cleaning, sanitizing, or disinfecting composition, such that at least a portion of the soil is removed from the substrate; wherein the cleaning, sanitizing, or disinfecting composition consists essentially of about 0.01-5.0 wt. % sodium and/or potassium tripolyphosphate, 0-2.0 wt. % sodium carbonate, 0.01-2.0 wt. % hydrogen peroxide, 0.01-2.0 wt. % peracetic acid, and water; and wherein the method does not include contacting the substrate with hydroxide, is effluent neutral, and is a clean-in-place (CIP) or sanitize-in-place (SIP) method.
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