Flexible process for transformation of ethanol into middle distillates

Patent metadata

Field	Value
Publication number	US-9475999-B2
Application number	US-201113102283-A
Country	US
Kind code	B2
Filing date	May 6, 2011
Priority date	May 6, 2010
Publication date	Oct 25, 2016
Grant date	Oct 25, 2016

Abstract

The invention describes a process for the production of middle distillate hydrocarbon bases from an ethanol feedstock that is produced from a renewable source that is obtained from biomass, whereby said process comprises a stage for purification of said feedstock, a stage for transformation of said purified feedstock into a light olefinic effluent that comprises at least 30% by weight of olefins that have between four to six carbon atoms relative to the total mass of the formed hydrocarbon compounds, whereby said stage works in the presence of a catalyst that comprises at least one zeolite that is selected from among the zeolites that have a structural type that appears in the following list: CHA, ERI, MTF, AEI, AEL, FER, EUO, MEL, MFS, TON, MTT and the zeolites ZBM-30, ZSM-48, IM-5 and IZM-2, taken by themselves or in a mixture, a stage for separation of the olefinic effluent that is obtained from stage b) in such a way as to eliminate at least a portion of the water that is formed during stage b) to produce at least one hydrocarbon gaseous effluent that for the most part has three or fewer carbon atoms and at least one olefinic hydrocarbon liquid effluent that for the most part has more than four carbon atoms, and a stage for oligomerization of at least a portion of the hydrocarbon effluents that are obtained from stage c) in the presence of an amorphous or zeolitic catalyst that has at least pore openings that contain 10 or 12 oxygen atoms, producing middle distillate hydrocarbon bases.

First claim

The invention claimed is:

1. A process for the production of middle distillate hydrocarbon bases from an ethanol feedstock that is produced from a renewable source that is obtained from biomass, said process comprising at least:
a) purification of said ethanol feedstock to produce a purified feedstock,
b) transformation of said purified feedstock obtained from a) into an olefinic effluent comprising at least 50% by weight of olefins having between four to six carbon atoms relative to the total mass of the hydrocarbon compounds that are formed, whereby said transformation is conducted in the presence of a catalyst comprising at least one ferrierite zeolite,
c) separation of the olefinic effluent that is obtained from b) by eliminating at least a portion of water that is formed during b) and thereafter producing at least one hydrocarbon gaseous effluent that for the most part has three or fewer carbon atoms and at least one olefinic hydrocarbon liquid effluent that for the most part has more than four carbon atoms,
d) oligomerization of at least a portion of the hydrocarbon gaseous effluent and a portion of the olefinic hydrocarbon liquid effluent obtained from c) in the presence of a zeolitic catalyst comprising ZSM-5, NU-10, or ZBM-30 or a mixture thereof, producing an effluent comprising middle distillate hydrocarbon bases, and
e) fractionation of the effluent that is obtained from d).

2. The process according to claim 1 , in which the transformation b) is conducted at a temperature of between 250 and 600° C., at a pressure of between 0 and 5 MPa, and at an hourly volumetric flow rate of between 0.1 and 50 h −1 .

3. The process according to claim 1 , in which at least a portion of said hydrocarbon gaseous effluent obtained from the separation c) is recycled to the transformation b).

4. The process according to claim 1 , in which all of said hydrocarbon gaseous effluent obtained from the separation c) is sent to the oligomerization d).

5. The process according to claim 4 , in which the effluent that is obtained from said oligomerization d) is separated into an effluent that for the most part contains hydrocarbons having fewer than nine carbon atoms and into another effluent that for the most part contains hydrocarbons having more than nine carbon atoms.

6. The process according to claim 4 , in which the effluent that is obtained from said oligomerization d) is separated into an effluent that for the most part contains hydrocarbons having fewer than 12 carbon atoms and into another effluent that for the most part contains hydrocarbons having more than 12 carbon atoms.

7. The process according to claim 5 , in which said effluent that for the most part contains hydrocarbons having more than 9 carbon atoms is sent into the fractionation e), and the another effluent that for the most part contains hydrocarbons having fewer than 9 carbon atoms is sent into the oligomerization d).

8. The process according to claim 1 , in which all of the olefinic hydrocarbon liquid effluent obtained from the separation c) is sent into the oligomerization d), in a mixture with at least the portion of the hydrocarbon gaseous effluent obtained from the separation c) and that has not been recycled to the transformation b).

9. The process according to claim 1 , in which the zeolitic catalyst that is used in the oligomerization step d) comprises silica alumina.

10. The process according to claim 1 , in which said zeolitic catalyst that is used in the oligomerization d) comprises a zeolite that is ZSM-5, NU-10, and ZBM-30, taken by themselves or in a mixture.

11. The process according to claim 1 , in which a stream comprising C2-C4 compounds and a stream comprising gasoline fraction are obtained from the fractionation e), and thereafter at least a portion of the stream comprising C2-C4 compounds and/or at least a portion of the stream comprising gasoline fraction is recycled to the oligomerization d).

12. The process according to claim 1 , in which a stream comprising middle distillate base is obtained from the fractionation e), and thereafter at least a portion of the stream comprising middle distillate base undergoes hydrogenation in the presence of a catalyst that comprises at least one of palladium or nickel, taken by itself or in a mixture, and a substrate that is alumina, silica or silica-alumina to produce a hydrogenation effluent.

13. The process according to claim 12 , in which a separation is implemented for the hydrogenation effluent to produce a kerosene fraction and/or a gas oil fraction and/or a fraction that has a boiling point that is higher than 360° C.

14. The process according to claim 12 , in which at least a portion of the stream comprising middle distillate base is recycled to the separation c).

15. The process according to claim 6 , in which said effluent that for the most part contains hydrocarbons having more than 12 carbon atoms is sent into the fractionation e), and the another effluent that for the most part contains hydrocarbons having fewer than 12 carbon atoms is sent into the oligomerization d).

Assignees

• Guillon Emmanuelle
• Cadran Nicolas
• Touchais Natacha
• Bournay Laurent
• Ifp Energies Now

Inventors

• Guillon Emmanuelle
• Cadran Nicolas
• Touchais Natacha
• Bournay Laurent

Classifications

• C10G3/49

  containing crystalline aluminosilicates, e.g. molecular sieves · CPC title

• C10G3/62

  Catalyst regeneration · CPC title

• C10G50/00 Primary

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title

• C10G2300/4018

  Spatial velocity, e.g. LHSV, WHSV · CPC title

• C10G2300/4081

  Recycling aspects · CPC title