Method of Reducing Impurities in Pyrolysis Oil
US-2024400918-A1 · Dec 5, 2024 · US
US9475994B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9475994-B2 |
| Application number | US-201214110575-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 9, 2012 |
| Priority date | May 3, 2011 |
| Publication date | Oct 25, 2016 |
| Grant date | Oct 25, 2016 |
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A modified paraffinic froth treatment (PFT) process is described, in which a fine tailings stream obtained from a water extraction process practiced on oil sands is added during the treatment process. This modified process may be useful as a treatment for the fine tailings stream, allowing for the flocculation of the fines, thus reducing the volume of such fine tailings. The modified process may also be useful in that the fine tailings stream can be used as a supplement or a replacement for dilution water, thus eliminating or reducing the need for dilution water in the PFT process.
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The invention claimed is: 1. A paraffinic froth treatment process wherein a fine tailings stream obtained from a water extraction process practiced on oil sands is added during the process, wherein the fine tailings stream excludes tailing solvent recovery unit (TSRU) tailings. 2. The paraffinic froth treatment process according to claim 1 , wherein the fine tailings stream obtained from a water extraction process practiced on oil sands is one of (i) a middlings stream from a primary separation vessel in a water-based bitumen extraction process, (ii) a stream of fine tailings obtained from a secondary separation vessel in a water-based bitumen extraction process, (iii) a combination of a middlings stream from a primary separation vessel and a stream of fine tailings obtained from a secondary separation vessel in a water-based bitumen extraction process, (iv) a hydrocyclone overflow and (v) diluted mature fine tailings (MFT). 3. The paraffinic froth treatment process of claim 1 , wherein the fine tailings stream comprises fine solids with an average size of less than 44 microns. 4. The PFT process according to claim 1 , wherein the fine tailings stream is selected from the group consisting of: middlings stream from a primary separation vessel in a water-based bitumen extraction process, a stream of fine tailings obtained from a secondary separation vessel in a water-based bitumen extraction process, a combination of a middlings stream from a primary separation vessel and a stream of fine tailings obtained from a secondary separation vessel in a water-based bitumen extraction process, a hydrocyclone flow, and diluted mature fine tailings (MFT). 5. A paraffinic froth treatment process, comprising: providing a bitumen froth comprising bitumen, mineral solids, and water; adding a paraffinic solvent to the bitumen froth to form a solvent bitumen froth mixture; and processing the solvent bitumen froth mixture in at least a first settling unit such that at least a portion of asphaltenes are precipitated and at least a portion of the mineral solids settles, forming a diluted bitumen stream and a first setting tailings stream; wherein a fine tailings stream obtained from a water extraction process practiced on oil sands is added during the process, and wherein the fine tailings stream excludes tailing solvent recovery unit (TSRU) tailings. 6. The process according to claim 5 , further comprising processing the first settling tailings stream from first settling unit in at least a second settling unit to form a solvent rich oil stream and a second settling tailings stream; and processing the second settling tailings stream in a tailings solvent recovery unit (TSRU) to obtain a solvent stream and a TSRU tailings stream. 7. The paraffinic froth treatment process according to claim 6 , wherein the fine tailings stream is added to (i) the bitumen froth before adding the paraffinic solvent, (ii) the solvent bitumen froth mixture before the solvent bitumen froth mixture is processed in the first settling unit, (iii) the first settling unit, (iv) the first settling tailings stream before the first settling tailings stream is added to the second settling unit, (v) the second settling unit, (vi) the second settling tailings stream before the second settling tailings stream is added to a tailings solvent recovery unit, (vii) the tailings stream from the tailings solvent recovery unit, (viii) above or below a feed injection point in the first or second settling vessel; (ix) the solvent stream; or (x) a combination thereof. 8. The paraffinic froth treatment process according to claim 6 , wherein the TSRU is comprised of a first TSRU and second TSRU. 9. The paraffinic froth treatment process according to claim 6 , further comprising adding fresh paraffinic solvent to the first settling tailings stream prior to addition of said first settling tailings stream to the second settling unit. 10. The paraffinic froth treatment process according to claim 9 , wherein the fine tailings stream is one of (i) mixed with the fresh paraffinic solvent prior to addition of both to the first settling tailings stream, (ii) added to the first settling tailings stream prior to the addition of the fresh paraffinic solvent thereto, (iii) added to the first settling tailings stream after the addition of the fresh paraffinic solvent thereto (iv) added to the first settling tailings stream in place of the addition of the fresh paraffinic solvent thereto and (v) added to the tailings stream from the tailings solvent recovery unit. 11. The PFT process according to claim 5 , wherein the fine tailings stream is selected from the group consisting of: middlings stream from a primary separation vessel in a water-based bitumen extraction process, a stream of fine tailings obtained from a secondary separation vessel in a water-based bitumen extraction process, a combination of a middlings stream from a primary separation vessel and a stream of fine tailings obtained from a secondary separation vessel in a water-based bitumen extraction process, a hydrocyclone flow, and diluted mature fine tailings (MFT). 12. A method of treating a fine tailing stream comprising directing the fine tailings stream into a paraffinic froth treatment process.
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