Three-way catalyst systems including Fe-activated Rh and Ba-Pd material compositions

Patent metadata

Field	Value
Publication number	US-9475005-B2
Application number	US-201514732473-A
Country	US
Kind code	B2
Filing date	Jun 5, 2015
Priority date	Jun 6, 2014
Publication date	Oct 25, 2016
Grant date	Oct 25, 2016

Abstract

Three way catalysts (TWCs) for catalyst systems are disclosed. The disclosed TWC systems include Iron (Fe)-activated Rhodium (Rh) and Barium (Ba)-Palladium (Pd) layers capable of interacting with conventional and/or non-conventional catalyst supports and additives. Variations of TWC system samples are produced including Fe-activated Rh layers deposited onto a washcoat (WC) layer having one or more of an oxygen storage material (OSM). Other TWC system samples are produced including an impregnation (IMPG) layer having loading variations of Ba within a Pd, Ce, and Nd applied onto an OSM WC layer, and a further overcoat layer including Fe-activated Rh is applied onto the IMPG layer. The catalytic performance of disclosed TWC catalysts is evaluated by performing a series of light-off tests, wide pulse perturbation tests, and standard isothermal oxygen storage capacity oscillating tests. Disclosed TWC catalysts exhibit high catalytic performance and significant oxygen storage capacity.

First claim

What is claimed is:

1. A catalyst system, comprising:
a substrate;
a washcoat deposited on the substrate;
at least one impregnation layer; and
an overcoat;
wherein the washcoat comprises at least one of the group consisting of about 10 (w/w) to about 75 (w/w) cerium oxide, about 25 (w/w) to about 90 (w/w) zirconium-hafnium oxide, about 0 (w/w) to about 15 (w/w) lanthanum oxide, about 0 (w/w) to about 15 (w/w) neodymium oxide, about 0 (w/w) to about 15 (w/w) yttrium oxide, and about 0 (w/w) to about 15 (w/w) praseodymium oxide;
wherein the at least one impregnation layer comprises rhodium at about 1 g/ft 3 to about g/ft 3 and iron at about 60 g/ft 3 to about 630 g/ft 3 ; and
wherein the overcoat comprises at least one of the group consisting of an oxygen storage material, support oxides, barium carbonate, doped alumina, strontium carbonate, and combinations thereof.

2. The catalyst system of claim 1 , wherein the overcoat is platinum group metal free.

3. The catalyst system of claim 1 , wherein the washcoat comprises a first oxygen storage material including about 31 (w/w) cerium, about 58 (w/w) zirconium-hafnium, about 5.5 (w/w) neodymium, and about 5 (w/w) yttrium oxide.

4. The catalyst system of claim 1 , wherein the at least one impregnation layer comprises about 3 g/ft 3 rhodium.

5. The catalyst system of claim 1 , wherein the at least one impregnation layer comprises about 140 g/ft 3 iron.

6. The catalyst system of claim 1 , wherein the overcoat comprises the oxygen storage material and wherein the oxygen storage material includes about 30 (w/w) Ce, about 60 (w/w) Zr—Hf, about 5 (w/w) Nd, and about 5 (w/w) Pr oxides.

7. The catalyst system of claim 1 , wherein the overcoat comprises the oxygen storage material and wherein the oxygen storage material includes about 30 (w/w) Ce, about 58 (w/w) Zr—Hf, about 5.5 (w/w) Nd, and about 5 (w/w) yttrium oxides and wherein the oxygen storage material is loaded at about 42 g/L.

8. The catalyst system of claim 1 , wherein the overcoat comprises high surface area alumina stabilized with La 2 O 3 .

9. The catalyst system of claim 8 , wherein the overcoat is loaded with 40 g/L of the high surface area alumina stabilized with La 2 O 3 .

10. A catalyst system, comprising:
a substrate;
a washcoat deposited on the substrate;
at least one impregnation layer impregnated in the washcoat; and
an overcoat;
wherein the at least one impregnation layer comprises Pd nitrate, Ce nitrate, Nd nitrate,
and a Ba salt;
wherein the Ba salt is loaded from about 50 g/ft 3 to about 700 g/ft 3 .

11. The catalyst system of claim 10 , wherein the overcoat comprises an oxygen storage material including Ce, Zr, Nd, and Y; wherein the oxygen storage material is impregnated with Fe nitrate; and wherein the overcoat is further impregnated with Rh nitrate.

12. The catalyst system of claim 11 , wherein the overcoat is loaded with about 9 g/ft 3 Rh.

13. The catalyst system of claim 12 , wherein the overcoat is loaded with about 210 g/ft 3 .

14. The catalyst system of claim 11 , wherein the at least one impregnation layer is loaded with about 22 g/ft 3 Pd, about 115 g/ft 3 Ba, about 105 g/ft 3 Ce, and about 12 g/ft 3 Nd.

15. The catalyst system of claim 10 , wherein the at least one impregnation layer is loaded with about 92 g/ft 3 Pd, about 105 g/ft 3 Ce, and about 12 g/ft 3 Nd.

16. The catalyst system of claim 15 , wherein the at least one impregnation layer is loaded with about 140 g/ft 3 iron.

17. The catalyst system of claim 10 , wherein the at least one impregnation layer is loaded with about 22 g/ft 3 Pd, about 115 g/ft 3 Ba, about 105 g/ft 3 Ce, and about 12 g/ft 3 Nd.

18. The catalyst of claim 10 , wherein the at least one impregnation layer is loaded with about 50 g/ft 3 to about 230 g/ft 3 of the Ba salt.

Assignees

• Clean Diesel Tech Inc

Inventors

• Hatfield Randal L
• Lee Edward J
• Ngo Johnny T
• Golden Stephen J

Classifications

• B01J23/10 Primary

  of rare earths · CPC title

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• B01D53/9454

  characterised by a specific device · CPC title

• B01D2255/40

  Mixed oxides · CPC title

• B01J35/0006

  Operations & Transport · mapped topic