Method for manufacturing a functional layer for a lithium cell

Patent metadata

Field	Value
Publication number	US-9472808-B2
Application number	US-201414570042-A
Country	US
Kind code	B2
Filing date	Dec 15, 2014
Priority date	Dec 16, 2013
Publication date	Oct 18, 2016
Grant date	Oct 18, 2016

Abstract

In a method for manufacturing a functional layer for a lithium cell, e.g., a protective layer for a lithium metal anode, the functional layer being lithium-ion conductive and including particles of at least one ceramic material, the particles of the at least one ceramic material being applied to a carrier by deposition.

First claim

What is claimed is:

1. A method for manufacturing a lithium-ion conductive functional layer for a lithium cell, comprising:
applying particles of at least one ceramic material to a carrier by depositions;
wherein the functional layer further includes at least one polymeric binder applied to the carrier by deposition,
wherein the particles of the at least one ceramic material and the polymeric binder are deposited one of simultaneously or in alternation,
wherein at least one of (i) the polymeric binder is lithium-ion conductive, (ii) the particles of the at least one ceramic material form uninterrupted lithium-ion conduction paths in the thickness direction of the functional layer, and (iii) the functional layer includes at least one lithium conducting salt,
wherein the lithium conducting salt includes at least one of lithium hexafluorophosphate (LiPF 6 ), lithium bis(trifluoromethanesulfonyl)imide (LiTFSI), lithium tetrafluoroborate (LiBF 4 ), and lithium bis(oxalato)borate,
wherein the lithium conducting salt is introduced into the functional layer after the deposition of the particles of the at least one ceramic material and the polymeric binder, and
wherein the carrier is a carrier substrate which is removed from the functional layer with the aid of a delaminating or etching process, and wherein the functional layer is subsequently applied to a lithium film.

2. The method as recited in claim 1 , wherein an aerosol deposition method is used for the deposition of at least one of the at least one ceramic material and the polymeric binder.

3. The method as recited in claim 1 , wherein (i) the polymeric binder includes at least one of polyethylene oxide, polyethylene oxide derivatives, polyacrylates, and polyacrylate derivatives, and (ii) the ceramic material includes at least one of lithium aluminum titanium phosphate (LATP), lithium aluminum germanium phosphate (LAGP), garnets, sulfide glasses, sulfide electrolytes, argyrodites, Li-rich anti-perovskites, and Li-lanthanum perovskites.

4. The method as recited in claim 3 , wherein the functional layer is formed without an additional tempering step.

5. The method as recited in claim 3 , wherein the functional layer is compacted with the aid of a calendering process.

6. The method as recited in claim 1 , wherein the lithium conducting salt together with the particles of the at least one ceramic material and the polymeric binder are applied to the carrier by deposition.

7. The method as recited in claim 1 , wherein the carrier includes lithium and is formed as a lithium film.

8. The method as recited in claim 1 , wherein an aerosol deposition method is used for the deposition of at least one of the at least one ceramic material and the polymeric binder, and wherein (i) the polymeric binder includes at least one of polyethylene oxide, polyethylene oxide derivatives, polyacrylates, and polyacrylate derivatives, and (ii) the ceramic material includes at least one of lithium aluminum titanium phosphate (LATP), lithium aluminum germanium phosphate (LAGP), garnets, sulfide glasses, sulfide electrolytes, argyrodites, Li-rich anti-perovskites, and Li-lanthanum perovskites.

9. The method as recited in claim 8 , wherein the functional layer is formed without an additional tempering step.

10. The method as recited in claim 8 , wherein the functional layer is compacted with the aid of a calendering process.

11. The method as recited in claim 8 , wherein the lithium conducting salt together with the particles of the at least one ceramic material and the polymeric binder are applied to the carrier by deposition.

12. The method as recited in claim 8 , wherein the carrier includes lithium and is formed as a lithium film.

Assignees

• Bosch Gmbh Robert

Inventors

• Engel Christine
• Butzin Michael
• Tenzer Martin
• Fanous Jean

Classifications

• H01M4/366

  as layered products · CPC title

• H01M4/628 Primary

  Inhibitors, e.g. gassing inhibitors, corrosion inhibitors · CPC title

• H01M4/139

  Processes of manufacture · CPC title

• Y02E60/122

  Cross-Sectional Technologies · mapped topic

• H01M4/0435

  Rolling or calendering · CPC title